Alternating,all-trans polyenynes: Model compounds for poly(diacetylene)s with defined conjugation length

The syntheses of polyenynes as model compounds for poly(diacetylene)s (PDAs) are described. Variation of properties (UV–VIS, Raman, NMR and bond geometries) as a function of the chain length was investigated. After extrapolation to infinite chain length these data were compared to those for PDAs. From UV–VIS spectra a value of λ = 551 nm (2.25 eV) was calculated corresponding to the electronic transition of a single polyenyne chain. This energy is located at the low energy end of a yellow PDA solution spectrum. From Raman scattering v_(C?C) = 2108–2128 cm^?1 and v_(C?C) = 1505–1532 cm^?1 were calculated after extrapolation. Similarly sp-C¹³C NMR data yielded a shift of δ = 100 ppm. These data are almost identical to data known for yellow PDA solutions. Bond geometries are almost identical to those of poly(diacetylene)s and theoretical data.     

Propagation of the Chain Explosive‐Decomposition Reaction in Silver Azide Crystals

The velocity of the chain explosivedecomposition reaction in silver azide whiskes has been measured (1500 m/sec). The measured velocity is identified as the propagation velocity of the diffusion front of holes generated in the course of explosive decomposition.     

Conditional probability Markov chain simulation based reliability analysis method for nonnormal variables

Based on fast Markov chain simulation for generating the samples distributed in failure region and saddlepoint approximation(SA) technique,an efficient reliability analysis method is presented to evaluate the small failure probability of non-linear limit state function(LSF) with non-normal variables.In the presented method,the failure probability of the non-linear LSF is transformed into a product of the failure probability of the introduced linear LSF and a feature ratio factor.The introduced linear LSF wh...     

资源生产供应链履行社会责任的内在动力研究

运用博弈论的基本思想,通过构造一个资源生产供应链,从资源保护这个角度出发,以资源生产供应链中的节点企业——资源开采商开采自然资源为例,对资源生产供应链履行社会责任的内在动力进行了研究。结果表明：对资源开采商合作开采带来的收益增量进行合理分配,既能使资源开采商进行合作,又能实现供应链系统与各资源开采商的帕累托最优。     

风机冷风保安控制系统优化

介绍菜钢型钢AV80风机冷风保安控制系统的优化改造,以增加其控制安全性及可靠性.     

岸吊焊缝裂纹分析与改进措施研究

从材料的焊接性能、焊接结构、焊条、预热与焊后热处理、焊接工艺参数等角度对岸吊胎架焊缝裂纹进行了分析,提出了改进措施,取得了良好的效果。     

一种新型气硬冷芯盒树脂砂工艺试验及其在生产中的应用

原砂加入2．5％水溶性酚醛树脂，固化剂为甲酸甲脂，加入量占树脂的30％～40％。先把甲酸甲脂在气体发生器中气化，然后再与40％的压缩空气混合，吹气硬化制芯，最高抗拉强度1．2MPa，抗压强度0．32MPa，发气量12mL／g。生产浇注试验表明：砂芯表面光洁，轮廓清晰，尺寸精确，铸件缺陷少，无毒或低毒，和一般冷硬树脂砂比较，成本降低30％。     

RAZUMIKHIN-TYPE THEOREMS OF NEUTRAL STOCHASTIC FUNCTIONAL DIFFERENTIAL EQUATIONS

The stability of stochastic functional differential equation with Markovian switching was studied by several authors,but there was almost no work on the stability of the neutral stochastic functional differential equations with Markovian switching.The aim of this article is to close this gap.The authors establish Razumikhin-type theorem of the neutral stochastic functional differential equations with Markovian switching,and those without Markovian switching.