Chemische Zusammensetzung und Mikrostruktur polymerabgeleiteter Gläser und Keramiken im System Si–C–O. Teil 2: Charakterisierung der Gefügeausbildung mittels hochauflösender Durchstrahlungselektronenmikroskopie und Feinbereichsbeugung

Chemical Composition and Microstructure of Polymer‐Derived Glasses and Ceramics in the Si–C–O System. Part 2: Characterization of microstructure formation by means of high‐resolution transmission electron microscopy and selected area diffraction Liquid or solid silicone resins represent the economically most interesting class of organic precursors for the pyrolytic production of glass and ceramics materials on silicon basis. As dense, dimensionally stable components can be cost‐effectively achieved by admixing reactive filler powders, chemical composition and microstructure development of the polymer‐derived residues must be exactly known during thermal decomposition. Thus, in the present work, glasses and ceramics produced by pyrolysis of the model precursor polymethylsiloxane at temperatures from 525 to 1550 °C are investigated. In part 1, by means of analytical electron microscopy, the bonding state of silicon was determined on a nanometre scale and the phase separation of the metastable Si–C–O matrix into SiO₂, C and SiC was proved. The in‐situ crystallization could be considerably accelerated by adding fine‐grained powder of inert fillers, such as Al₂O₃ or SiC, which permits effective process control. In part 2, the microstructure is characterized by high‐resolution transmission electron microscopy and selected area diffraction. Turbostratic carbon and cubic β‐SiC precipitate as crystallization products. Theses phases are embedded in an amorphous matrix. Inert fillers reduce the crystallization temperature by several hundred °C. In this case, the polymer‐derived Si–C–O material acts as a binding agent between the powder particles. Reaction layer formation does not occur. On the investigated pyrolysis conditions, no crystallization of SiO₂ was observed.     

Analysis of polarization plane rotation characteristic in 2D photonic crystal waveguide with chiral medium by condensed node spatial network

Using the photonic band gap in photonic crystals, the fundamental waveguide structures for the light wavelength range have been developed. Based on the fine structure of these many functional devices have been proposed by analytical or numerical simulation methods and the experiments of trial manufacture. In this paper, the treatment of chiral dielectric in the Condensed Node Spatial Network for the vector potential is explained, and we show the polarization plane rotation property in air‐hole and pillar type photonic crystal waveguide structures with the chiral medium substrate. Then, we show the fundamental advantage of the air‐hole type photonic crystal waveguide structure in application to a mode converter. © 2005 Wiley Periodicals, Inc. Electr Eng Jpn, 152(1): 7–14, 2005; Published online in Wiley InterScience ( www.interscience. wiley.com ). DOI 10.1002/eej.20098     

反射衰减诊断激光光束的应用分析

介绍了普通光学元件反射诊断激光光束的应用,提出了利用平面平晶的平面反射进行光能衰减,详细论述了采用该方法进行光能衰减的可行性,分析了平面平晶反射衰减中反射光S偏振态和P偏振态能量的差异,对激光束诊断的影响和解决方法,结合半导体绿激光器的光束诊断进行了应用分析。实验证明,该方法结构简单、调整方便、误差小,利用普通平面平晶反射衰减即可满足激光强度的匹配要求,实现了待测激光束无失真取样,达到很好的测试效果。     

实型和虚型结构因子的代数公式

应用晶体正空间和倒易空间等效点的矩阵表示讨论结构因子类型，在得到倒易空间点的一般型结构因子类型和系统消光型结构因子类型的代数公式之后，得到并证明了倒易空间点的实型和虚型结构因子的代数公式．即满足提出的实型结构因子类型或虚型结构因子类型的代数公式的任意一倒易空间点h，其结构因子Fh分别为实型和虚型．     

添加晶种对硅酸盐水泥生料易烧性影响的研究

采用实验室制备不同种类单矿物，纯熟料及白水泥熟料为晶种，利用ＤＴＡ，ＸＲＤ及测定游离石灰等方法，研究了其对硅酸盐水泥生料易烧性的影响。结果表明；铁相的作用在四种单矿物中最为明显，其它三种主要矿物也均有不同程度地促进煅烧过程的熟料矿物形成的作用。     

剪切场下聚合物结晶形态学研究进展

聚合物熔体被引入剪切场后，会发生与静态下不同的结晶现象。微观上可以得到伸直链晶体、片晶及串晶；宏观上除了静态下典型的球晶外，还能观察到球晶的变形和柱晶等。另外，剪切还可以使晶体发生晶型转变。本文对聚合物熔体在剪切场下结晶形态学的研究进展进行了介绍。     

电磁搅拌技术的发展及其在武钢的应用

电磁搅拌技术能够有效地改善铸坯的质量，成为金属凝固过程控制的重要手段之一。论述了电磁搅拌技术的发展、作用及其在武钢的应用。随着技术的进步和发展，电磁搅拌技术不断更新和发展，必将迎来一个辉煌的应用前案。     

氟化钡晶体质子辐照损伤分布的计算

根据经典辐射理论，描述质子辐照BaF2晶体的能量损失，讨论受照晶体的辐照损伤分布，用Monte Carlo方法模拟碰撞过程，具体用TRIM程序分别计算出能量为1．5Mev和2．0Mev质子辐照BaF2晶体所产生的辐照损伤，对计算结果进行讨论，将这两种能量情况下的BaF2晶体辐照损伤分布进行比较。得到的结论与实验结果基本相符。     

Hydrothermal Synthesis and Crystal Structure of a New Dimeric Lanthanum(Ⅲ) Complex

A new dimeric lanthanum(Ⅲ) complex [La2(phen)2(C7H3N2O6)6](phen=1,10-phenanthroline) was synthesized by the hydrothermal method and determined by single crystal X-ray diffraction analysis. The La(Ⅲ) ion is coordinated to seven oxygen atoms from five carboxylate groups and two nitrogen atoms from a phen ligand,forming a monocapped square antiprismatic geometry. Six carboxylate groups coordinate to two La(Ⅲ) ions in three modes which are chelating bidentate,bridging bidentate and bridging tridentate. The crystal is triclinic with space group P-1,a=1.2030(4) nm,b=1.2962(5) nm,c=1.3330(5) nm,α=104.410(5)°,β=114.048(4)°,γ＝100.054(4)°,V=1.7467(10) nm3,Mr=952.46,Z=2,Dc=1.811 g·cm-3,F(000)=944,S=1.017,μ=1.320 mm-1,with R1=0.0298 and wR2=0.0625.     

Uranium Superconductivity Redux

Since the discovery of heavy-fermion superconductivity in uranium compounds in the early 1980s, other uranium compounds have been discovered that are fully as interesting to study. However, as we look forward in the year 2000, we now have higher-purity, single crystals of the element itself. Preliminary resistivity and ac susceptibility measurements show the improved quality of the samples and thus hold the promise of understanding many aspects of its superconductivity, which have remained untouched for almost 25 years.