Determination of the width of the transition layer between the crystalline and amorphous zones in nylon 1010 by SAXS

The width of the transition layer between the crystalline and amorphous zones in nylon 1010 was determined by SAXS with point collimation and long-slit collimation, respectively. The width of the transition layer, E, was found to be 1.7 nm. The results show that the width of the transition layer is independent of crystallinity.     

Evaporation and Evolution of Suspended Solution Droplets at Atmospheric and Reduced Pressures

Thermal history and solute precipitation behavior of suspended solution droplets of sodium chloride (NaCl), magnesium sulphate (MgSO₄), and zirconium hydroxychloride (ZrO(OH)Cl) evaporating at atmospheric and reduced pressures are studied. Experimental measurements on the variation of droplet diameter, solution concentration, and temperature during the evaporation period are presented and discussed. The results of solute precipitation behavior in solution droplets observed under an optical microscope are displayed and discussed. Results indicate that reducing the pressure (∼ 33 kPa) results in a change in the solution droplet evaporation rate, but the thermal histories of a particular solution droplet are similar at the atmospheric and reduced pressures. At atmospheric and reduced pressures used in this study, the d² law for solution droplets is valid at early stages of the evaporation and before the solute precipitation initiates. Drying of MgSO₄ and ZrO(OH)Cl solution droplets results in the formation of spherical particles, whereas drying of spherical NaCl solution droplets results in the formation of cubic particles.     

Photoresponsive peptide and polypeptide systems: part II. Photochromism of poly(l-ornithine) containing various azo-contents in side chains

Poly(L-ornithine)s having various azo-contents in the side chains were synthesized by the water-soluble carbodiimide procedure. The photochemical properties of the polypeptides poly[N^δ-p-(phenylazo)benzoyl-L-ornithine] (PPABLO) containing 3–77 mol% azobenzene were investigated by absorption and circular dichroism spectroscopy in hexafluoro-2-propanol (HFIP) or water, and in HFIP-water or methanol-water solvent mixtures. The photochromism of the dichroic bands of the PPABLOs containing 20–77 mol% azobenzene in the visible and ultraviolet wavelength regions was found to be mostly reversible as a function of irradiation time at different wavelengths due to the photostationary state (above 80% trans-cis photoisomerization) of the azo aromatic moieties. The PPABLO containing 3.2 mol% azobenzene in water exhibited conformational changes from random coil to helix by the addition of methanol or sodium dodecyl sulphate (SDS). The photo-induced conformational change was observed in HFIP-water-SDS solvent mixtures, while no conformational change was seen in water and HFIP-water solvent mixtures.     

Characterization of Tomato Pulp Stickiness during Spray Drying using a Contact Probe Method

A contact probe test was developed to characterize the surface stickiness of a tomato pulp droplet at various moisture contents and temperatures. To provide tomato pulp samples with different moisture contents, tomato powder produced by a laboratory spray dryer was wetted to seven different moisture levels. The instantaneous tensile force curve was recorded during the probe withdrawal from which the maximum tensile force and other useful information were obtained and cross-examined against images of bonding, debonding, and failure of the material. Generally, at higher moisture contents tomato pulp exhibited cohesive failure followed by semi-adhesive failure, but when moisture content decreased to a certain level, a peak tensile pressure was observed and the failure was adhesive. In addition, higher temperatures shifted the points of adhesive failure toward lower moisture content.     

Influence of Drying Conditions on Ascorbic Acid during Convective Drying of Whole Persimmons

Degradation kinetics of food constituents may be related to the matrix molecular mobility by glass transition temperature. Our objective was to test this approach to describe ascorbic acid degradation during drying of persimmons in an automatically controlled tray dryer with temperatures (40 to 70°C) and air velocities (0.8 to 2.0 m/s) varying according a second order central composite design. The Williams-Landel-Ferry model was satisfactorily adjusted to degradation curves for both control strategies adopted—constant air temperature and temperature fixed inside the fruit. Degradation rates were higher at higher drying temperatures, independent of the necessary time to attain the desired moisture content.     

运动汽车图像静态视点平滑特征优化仿真

由于运动汽车图像在特征采集过程中,汽车处于高速运动状态,采集的过程无法与汽车完全同步,造成汽车的特征像素分量在高速运动中丢失,产生较大的像素运动噪声,使得汽车图像边缘高频特征因为运动干扰而模糊.传统的平滑过渡方法在对运动汽车图像进行平滑处理时,按照图像中像元灰度值计算突变特性,但受到像素丢失与噪声无法抑制的影响,无法解决运动汽车图像高频分量对图像像元灰度值的干扰问题.提出基于替身运动DR算法的运动汽车图像静态视点平滑过渡方法,用替身像素描述汽车在场景中的运动特征,替身像素在场景中运动并同其它汽车的替身进行交互,采用局部化的车辆模型提高运动汽车场景的逼真度,通过依据替身运动的平滑过渡算法完成归一化线性运动汽车图像静态视点的平滑过渡,解决了运动汽车图像的平滑过渡问题.实验结果说明,所提方法可确保运动汽车图像边缘锐化,有效处理平滑噪声和锐化边缘.     

磁场中双量子位Heisenberg模型的纠缠与量子相变

以双量子位Heisenberg模型为例,讨论了磁场方向对纠缠的影响。结果表明：一定温度下,保持磁场的大小不变,仅改变其方向,不仅能获得最大纠缠,还产生了量子相变。     

Stability and synchronization for Markovian jump neural networks with partly unknown transition probabilities

This paper addresses the problems of stability and synchronization for a class of Markovian jump neural networks with partly unknown transition probabilities. We first study the stability analysis problem for a single neural network and present a sufficient condition guaranteeing the mean square asymptotic stability. Then based on the Lyapunov functional method and the Kronecker product technique, the chaos synchronization problem of an array of coupled networks is considered. Both the stability and the synchronization conditions are delay-dependent, which are expressed in terms of linear matrix inequalities. The effectiveness of the developed methods is shown by simulation examples.     

#BIS-hardness for 2-spin systems on bipartite bounded degree graphs in the tree non-uniqueness region

Counting independent sets on bipartite graphs (#BIS) is considered a canonical counting problem of intermediate approximation complexity. It is conjectured that #BIS neither has an FPRAS nor is as hard as #Sat to approximate. We study #BIS in the general framework of two-state spin systems on bipartite graphs. We define two notions, nearly-independent phase-correlated spins and unary symmetry breaking. We prove that it is #BIS-hard to approximate the partition function of any 2-spin system on bipartite graphs supporting these two notions. Consequently, we classify the complexity of approximating the partition function of antiferromagnetic 2-spin systems on bounded-degree bipartite graphs.