Synthesis of heterocyclic metal complexes and their evaluation as marine antifoulants

4-Amino-3-thio-1,24-triazolidine (L₁) and 4-amino-5-thio-1,3,4-thiadiazole (L_II) as well as their metal complexes of the general formulae ML_I·2H₂O and ML_IICl (M; Pb(II), Cd(II) and Zn(II)) were prepared. With Sn(II), we obtained Sn(L_I)₂·2H₂O and SnL_IICl, respectively. The structures of the compounds were identified through elemental analysis, and IR and UV spectra measurements, in addition to thermal analysis in case of the metal complexes. The antifouling properties of the compounds were tested by their incorporation into paint formulations which were applied to PVC substrates and tested in water from Alexandria western harbour. When the compounds were added at 17·5% by volume, the coated panels were fouled after 3 months of immersion. The addition of 6·7% by volume of tributyltin oxide to 15·8% of the prepared compounds in one formulation elevated the paint efficiency and prevented fouling for 11 months. Paint containing solely tributyltin oxide at the same concentration was inactive against algae.     

A load dispatch method using fractional programming and semidefinite programming

This paper describes a load dispatch method which minimizes power cost—[fuel cost]/[electric output]—for a power system with thermal plants and energy storage facilities. The proposed method employs fractional programming to convert a minimization problem with fractional objective function to a series of quadratic minimization problems, and semidefinite programming to solve converted problems. The method provides the optimum time‐dependent power output/input and storage level of energy storage facilities as well as time‐dependent power output of thermal plants. The method has been applied to a power system with five thermal plants, two energy storage facilities of various performances, and five load demands. The optimum load scheme of four time mesh points is obtained for the thermal plants and energy storage facilities. The fractional programming successfully converges the optimal scheme through a few iterations. The semidefinite programming deals with a variable matrix of 164 dimensions, and 185 inequality constraints. © 2001 Scripta Technica, Electr Eng Jpn, 138(2): 49–58, 2002     

Effect of crack-growth mechanism on the prediction of fracture load of adhesive joints

This paper presents observations regarding the cracking behavior of tensile-loaded structural adhesive joints. Experiments showed that fracture occurred by the development and propagation of a damage zone, rather than a single, sharp crack, and that the presence of the adhesive spew fillet did not affect the fracture load of the adhesive joints studied. For joints bonded with the mineral-filled epoxy Cybond 4523GB (American Cyanamid), there was approximately 5 mm of subcritical crack propagation prior to final fracture. Fracture-load predictions based on the initial uncracked geometry made in previous papers were unaffected by this small change in geometry. For joints bonded with the rubber-toughened epoxy Permabond ESP 310, approximately 50 mm of subcritical crack propagation was observed. It was again found that predictions made in previous papers on the basis of the initial geometry gave a good estimate of the final fracture load even though this subcritical crack propagation significantly altered the geometry, and thus the applied energy release rates. The effect of shear deformations of the adherends was also investigated, and it was found that shear deformations could be neglected in engineering calculations for joints subject to remote tensile loading.     

Multiobjective dynamic load-dispatching method for optimal operation of power systems

A new practical method is proposed which gives a quasi-optimal solution of the dynamic load-dispatching problem formulated by a multiconstraint multiobjective optimization problem. Here, the multiple constraints are rate reserve constraints and power flow ones, and the multiple objectives are fuel cost and CO₂ emission. The proposed method is an integration of the following three techniques: (1) “Group Dispatch Scheme,” which is developed by the authors, is used to satisfy a violated constraint easily. This scheme consists of three steps. The first step is to classify all generators into two groups. One is the group which should be more loaded to satisfy the violated constraint, and the other is the should-be less loaded group. The second step is to add some load to the former group, and to subtract the same load from the latter. The third step is to dispatch each group load to each groups generators, respectively; (2) the dynamic load-dispatching algorithm is used which provides, in practical time, quasi-optimal generation trajectories; (3) the conventional weighting parametric method is used to obtain a Pareto optimal solution of multiobjective problems. The effectiveness of the method is clarified by a computer simulation on the actual power system of Kansai Electric Power Company.     

Dynamic equivalent method of interconnected power systems with consideration of motor loads

The existing equivalent methods usually only deal with static load models and neglect the dynamic characteristics of loads such as induction motors.This paper presents a dynamic equivalent method which considers motor dynamics.At first,the clustering criterion of motor loads is given.The motors with similar dynamic characteristics are classified into one group.Then,reduction of motors in the same group is carried out.Finally,parameters of the equivalent motor are calculated and the equivalent system is thus...     

Application of structural curvature of coalbed floor on CBM development in the Zaoyuan block of the southern Qinshui Basin

Based on controls of structural style and the position in coalbed methane(CBM)development,we used a method of curvatures to study its relations with CBM development parameters.We calculated structural curvatures of contours of the No.3coal seam floor of the Shanxi Formation in the Zaoyuan block of the Qinshui Basin and analyzed its relations with development parameters of coalbed methane wells.The results show that structural curvature is negatively related to coal reservoir pressure,while positively related to permeability.With an increase in structural curvature,the average production of coalbed methane wells increases at first and then decreases,reaching the highest production at 0.02 m-1 of structural curvature.Therefore,structural curvature can be an important index for potential evaluation of coalbed methane development and provide a basis for siting coalbed methane wells.     

Relation between structural evolution of the Longmenshan orogenic zone and sedimentation of its foreland basin

In order to determine the area for oil and gas exploration in China's north Sichuan basin, we have divided the time during which the Longmenshan foreland basin was formed into five periods, based on the sedimentary response relationship of the fore-land basin to structural evolution: 1) a late Triassic Noric period; 2) an early-Middle Jurassic period; 3) a late Jurassic to early Cre-taceous period; 4) a late Cretaceous to Paleogene-Neogene period and 5) the Quaternary period. As well, we analyzed the sedimen-tary environment and lithologic features of every basin-forming period. The results show that there are several favorable source-reservoir-cap assemblages in our study area, making it a major region for future oil and gas exploration in China's northern Sichuan basin.     

Limit load and shakedown analysis of plastic structures under stochastic uncertainty

Problems from plastic analysis are based on the convex, linear or linearised yield/strength condition and the linear equilibrium equation for the stress (state) vector. In practice one has to take into account stochastic variations of several model parameters. Hence, in order to get robust maximum load factors, the structural analysis problem with random parameters must be replaced by an appropriate deterministic substitute problem. A direct approach is proposed based on the primary costs for missing carrying capacity and the recourse costs (e.g. costs for repair, compensation for weakness within the structure, damage, failure, etc.). Based on the mechanical survival conditions of plasticity theory, a quadratic error/loss criterion is developed. The minimum recourse costs can be determined then by solving an optimisation problem having a quadratic objective function and linear constraints. For each vector a(·) of model parameters and each design vector x, one obtains then an explicit representation of the “best” internal load distribution F^∗. Moreover, also the expected recourse costs can be determined explicitly. Consequently, an explicit stochastic nonlinear program results for finding a robust maximal load factor μ^∗. The analytical properties and possible solution procedures are discussed.     

Models to predict the deformation modulus and the coefficient of subgrade reaction for earth filling structures

Determination of deformation modulus and coefficient of subgrade reaction of soils have major importance, whether the projects are in design, and construction or compaction assessment stage of earth filling structures. Plate load test is one of the frequently used method to directly determine the parameters but the method is both costly and time consuming. For this reason, this paper is concerned with the applications of artificial neural networks (ANN) and simple-multiple regression analysis to predict deformation modulus and coefficient of subgrade reaction of compacted soils from compaction parameters (such as maximum dry density (MDD) and optimum moisture content (OMC), field dry density (FDD), and field moisture content (FMC)). Regression analysis and artificial neural network estimation indicated that there are acceptable correlations between deformation modulus and coefficient of subgrade reaction and these parameters. Artificial neural networks model exhibits higher performance than traditional statistical model for predicting deformation modulus and coefficient of subgrade reaction.