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1.
Poly[2‐methoxy‐5‐(2′‐ethyl‐hexyloxy)‐para‐phenylene vinylene] (MEH‐PPV)/silica nanoparticle hybrid films were prepared and characterised. Three kinds of materials were compared: parent MEH‐PPV, MEH‐PPV/silica (hybrid A films), and MEH‐PPV/coupling agent MSMA/silica (hybrid B films), in which MSMA is 3‐(trimethoxysilyl) propyl methacrylate. It was found that the hybrid B films could significantly prevent macrophase separation, as evidenced by scanning electron and fluorescence microscopy. Furthermore, the thermal characteristics of the hybrid films were largely improved in comparison with the parent MEH‐PPV. The UV‐visible absorption spectra suggested that the incorporation of MSMA‐modified silica into MEH‐PPV could confine the polymer chain between nanoparticles and thus increase the conjugation length. The photoluminescence (PL) studies also indicated enhancement of the PL intensity and quantum efficiency by incorporating just 2 wt% of MSMA‐modified silica into MEH‐PPV. However, hybrid A films did not show such enhancement of optoelectronic properties as the hybrid B films. The present study suggests the importance of the interface between the luminescent organic polymers and the inorganic silica on morphology and optoelectronic properties. Copyright © 2004 Society of Chemical Industry  相似文献   
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3.
α,β‐Unsaturated nitriles have been synthesized by Knoevenagel condensation of a carbonylic compound with malononitrile, assisted by sonochemical irradiation. Two alkaline‐promoted clays (Li+‐ and Cs+‐exchanged saponites) have been employed as catalysts. The influence of the carbonylic compound (benzaldehyde or cyclohexanone) and the use of a solvent on the catalytic activity have been studied. Remarkable increase in the conversion values has been found when the reaction is activated by ultrasound, as compared with the thermal activation. In this green, solvent‐free procedure, α,β‐unsaturated nitriles have been produced in very high yields (97%) when the Cs+‐saponite is used as catalyst. Copyright © 2004 Society of Chemical Industry  相似文献   
4.
A color stimulus may be characterized by three psychophysical dimensions (luminance, dominant wavelength, and purity), whose corresponding color attributes are lightness, hue, and chroma/colorfulness. The 3 × 3 matrix gives nine basic effects of the psychophysical dimensions on the color attributes (e.g. the effect of luminance on hue), but there are 49 possible combinations as more complex effects (e.g. the effect of luminance on hue and chroma, i.e. on chromaticity). Researching and quantifying such effects enables modelling of the underlying neural mechanisms and of color appearance. Using a simple nomenclature to identify the effects (e.g. Ph denotes the effect of Purity on hue), this paper briefly reviews and interrelates 15 of the commonest effects, giving new data or new graphical perspectives to clarify or fill gaps in the literature. Contrast and no‐contrast effects (stimuli viewed simultaneously or singly, respectively) are differentiated. © 2007 Wiley Periodicals, Inc. Col Res Appl, 32, 208–222, 2007  相似文献   
5.
任向红  樊秉安  李瑛 《粘接》2002,23(1):1-2,6
坑道水下堵漏剂的研制包括F-1、F-2和F-3型。其中F-1是一种有机堵漏剂,它可以在水中固化;F-2是一种无机防水堵漏剂,施工方便;F-3是速凝型,它可在瞬间固化,能对坑道的涌水口进行堵漏。  相似文献   
6.
The simultaneous contrast effect is investigated in this article. A total of 174 and 154 test/induction combinations were studied for CRT and surface colours respectively. Each combination was assessed by nine observers using a matching technique. The test and induction colours used for CRT colours were similar to surface colours using fabric samples. The results indicated a strong lightness contrast effect for both CRT and surface media; that is, the lightness of a test colour surrounded by a lighter induction colour was reduced for both CRT and surface colours. However, the effect in CRT medium was more pronounced than in the surface medium. © 2004 Wiley Periodicals, Inc. Col Res Appl, 30, 13–20, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.20074  相似文献   
7.
A modified CIECAM02 colour appearance model, named CIECAM02‐m2, is proposed to enable CIECAM02 to predict the simultaneous contrast effect. The structure of the CIECAM02‐m2 is a development from CIECAM02, and contains two different procedures for modifying the reference white; one is for lightness and the other is for hue. The model was tested using a data set accumulated in this study and the LUTCHI data. The CV values for three colour attributes between predictions and experimental data were used to evaluate the accuracy of the model. The low CV values obtained show the performance of the CIECAM02‐m2 model to predict the simultaneous contrast effect satisfactorily. © 2007 Wiley Periodicals, Inc. Col Res Appl, 32, 121 – 129, 2007  相似文献   
8.
DD—921钢铁常温发黑剂的研制和应用   总被引:4,自引:0,他引:4  
戴龙田 《表面技术》1994,23(5):221-223
研究了钢铁常温发黑过程的成膜机理,各组分之间的作用以及相互之间的影响,着重分析了常温发黑的优缺点,工艺控制参数以及经济性。  相似文献   
9.
介绍了石油烃中砷的存在形式 ,石脑油中砷含量及对催化剂的危害 ,分析了脱砷机理 ,阐述了国产脱砷剂的类型、型号、特点 ,以及选用原则与工业应用情况。  相似文献   
10.
以凹凸棒粘土作为高水速凝固化充填材料的悬浮稳定剂,考察了不同制浆机械对凹凸棒粘土制浆率的影响。采用高剪切混合乳化机预制的1%凹凸棒粘土浆配制高水速凝固化充填材料甲、已料单浆可获得满意的悬浮稳定效果。其充填体结石抗压强度早期发展迅速,后期持续增长。采用此工艺,注浆料的材料成本仅增加2%。  相似文献   
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