The radiation crosslinking and scission of ethylene-propylene copolymers studied by solid-state nuclear magnetic resonance

Methyl groups from chain scission and H-crosslinks have been identified by solid-state nuclear magnetic resonance in amorphous ethylene-propylene copolymers containing 23 and 36 mole % propylene after γ-irradiation to 10 MGy at 30°C. G (scission) and G (crosslink) values determined from the n.m.r. spectra and by extraction are in agreement, which suggests that the crosslinks are not clustered. This may differ from the situation in polyethylene where there is a substantial crystalline content. G(S). G(X) and the ratio G(S)/G(X) increase with increasing propylene content of the copolymers.     

铝电解槽热平衡测试计算中的几点问题

由于缺乏正规的标准，铝电解槽能量平衡测试中存在着一些概念混淆、计算方法和公式错误的情况，应引起测试工作者的注意，在测试计算前应认真制订方案，多查一些参考资料，核实所用公式、数据，避免发生失误。同时对于类似计算，由于计算机的应用，应尽可能采取精确算法。没必要采取一些非常粗糙的近似算法和经验值。     

3G网络基站电磁环境影响分析

通过资料收集、理论预测、数据监测与分析,讨论了辽宁某市3G网络基站中典型基站的电磁环境。结果表明,理论预测与实际监测结果差距不大,各典型基站的电磁辐射功率密度均低于国家标准限值8μW/cm2,对该地区的电磁环境影响不大。对保护环境提出了相应的对策措施.     

铁尾矿为原料微波法制备介孔分子筛

以鞍山铁尾矿为硅源,CTAB为模板剂,采用微波辐照法合成出全硅介孔分子筛MCM-41。用N2低温吸附、FT-IR、XRD和TEM等表征手段考察了其比表面积、孔径分布、晶体形貌等特性。结果表明:微波辐射法合成的MCM-41分子筛诱导期极短,晶化速度很快,具有典型的按六方对称性排列的孔道结构,FT-IR证明了分子筛具有硅氧四面体骨架。     

Recombination luminescence from defects in boron-ion implantation-doped diamond using low fluences

 Two identical, high purity, natural type IIa diamonds, which displayed the ubiquitous blue cathodoluminescence (CL) band at ≈ 2.9 eV, as well as an indication of the corresponding green band at ≈ 2.4 eV, have been equivalently doped by using extremely low dose B⁺- and C⁺-ion CIRA-implantations respectively. Comparative CL measurements showed changes in the intensities of the 2.9 and 2.4 eV bands and the generation of bands at ≈ 4 eV, as well as at ≈ 3.5 and ≈ 4.6 eV (the latter two in the B⁺-CIRA diamond). The results are commensurate with the model (proposed previously) in which the 2.9 and 4 eV bands are generated respectively by electron-hole recombinations at negatively charged acceptor- and positively charged donor-like, intrinsic defects. The present results indicate that Coulomb interactions between the latter defects and (at least partially) compensated, negatively charged, boron acceptors, generate the 3.5 and 4.6 eV bands, which may be considered as higher energy (≈ 0.6 eV) replicas of the 2.9 and 4 eV bands. In both cases, two electrons and a hole interact just before the hole combines with an electron. Such a configuration of charges seems related to, and could possibly be described as, a type of ”ionised exciton molecule”, where the ”bonding” of two negative ”nuclei” is facilitated by the presence of the hole. The CL measurements further indicate that the 2.4 eV band forms when a high enough density of, in this case, neutral acceptors are present. These neutral acceptors compete with the valence band to supply holes for recombination at the negatively charged, acceptor-type, intrinsic defects which are, in the absence of the boron, responsible for the generation of the blue, 2.9 eV band. Received: 5 December 1997 / Accepted: 13 December 1997     

一种用于核辐射监测信号的多微处理系统

介绍了4兆伏静电正离子加速器的监测防护系统,该系统由多个微处理器与主控机分布式分布,组成高速多通道辐射信号采集控制系统,可以对多点核辐射的能量、强度、剂量率,剂量及剂量当量进行监测.系统的核电路部分采用最新的芯片产品,合理的硬件安排,优化的软件编程,在仅更换不同的探头后,便可探测分析γ,X及快中子辐射.在参数稍做调整之后,就可以广泛应用于类似条件的其他场所的辐射监测.     

Crystallization and infrared radiation properties of iron ion doped cordierite glass-ceramics

Heterogeneous ion solution is an important method to improve the wanted property of polycrystalline materials. In this paper, for the purpose of infrared radiation property modification, different contents Fe₂O₃ were doped in MgO-Al₂O₃-SiO₂ system glasses. The effects of Fe₂O₃ doping on nucleation mechanism, crystallization behaviors and especially infrared radiation properties of this cordierite-crystalline based glass-ceramics were systematically investigated by means of differential thermal analysis (DTA), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The results show that, the doping of iron ion can promote the phase separation of this magnesium aluminosilicate glass, and therefore change the crystallization mechanism of this glass from surface crystallization to bulk crystallization. The iron ion incorporates into the crystal structure of cordierite by mean of substituting Mg²⁺ in M site. The substitution of Fe³⁺ to Mg²⁺ can form the vacant site of Mg²⁺ cations. For the effects of lattice distortion, impurity and vacancy defects which caused by the incorporation of iron ion, the infrared radiation performance of cordierite based glass-ceramics can be improved effectively.     

Lunar Habitat Micrometeoroid and Radiation Shielding: Options, Applications, and Assessments

Various shielding approaches to protect lunar habitats from micrometeoroid and radiation hazards present major trade-off considerations. Popular scenarios that envision covering modules with in situ regolith will necessitate means to excavate and move large amounts of material; will complicate evolutionary outpost growth; and may require long tunnels between connecting pressurized elements. Strategies that incorporate shielding materials into module structures or internal shelters add very substantial launch mass penalties. Utilization of water bladders can make efficient use of consumable/recyclable supplies, but may impose excess capacity deliveries at early development stages. This paper addresses these different shielding approaches from a top-level application perspective, highlighting pros and cons of each. Examples draw upon research and design investigations undertaken by the Sasakawa International Center for Space Architecture in support of separate National Aeronautics and Space Administration (NASA) contracts awarded to teams headed by Boeing and ILC-Dover for a “Minimum Functionality Habitation Systems Concept Study.” Comprehensive team study results were presented to NASA in February 2009, and have been released as public information.