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1.
The syntheses of polyenynes as model compounds for poly(diacetylene)s (PDAs) are described. Variation of properties (UV–VIS, Raman, NMR and bond geometries) as a function of the chain length was investigated. After extrapolation to infinite chain length these data were compared to those for PDAs. From UV–VIS spectra a value of λ = 551 nm (2.25 eV) was calculated corresponding to the electronic transition of a single polyenyne chain. This energy is located at the low energy end of a yellow PDA solution spectrum. From Raman scattering v(C?C) = 2108–2128 cm?1 and v(C?C) = 1505–1532 cm?1 were calculated after extrapolation. Similarly sp-C13C NMR data yielded a shift of δ = 100 ppm. These data are almost identical to data known for yellow PDA solutions. Bond geometries are almost identical to those of poly(diacetylene)s and theoretical data.  相似文献   
2.
Stress measurement methods using neutron and X‐ray diffraction were examined by comparing the surface stresses with internal stresses in the continuous tungsten‐fiber reinforced copper‐matrix composite. Surface stresses were measured by X‐ray stress measurement with the sin2ψ method. Furthermore, the sin2ψ method and the most common triaxal measurement method using Hooke's equation were employed for internal stress measurement by neutron diffraction. On the other hand, microstress distributions developed by the difference in the thermal expansion coefficients between these two phases were calculated by FEM. The weighted average strains and stresses were compared with the experimental results. The FEM results agreed with the experimental results qualitatively and confirmed the importance of the triaxial stress analysis in the neutron stress measurement.  相似文献   
3.
This paper concerns the following problem: given a set of multi-attribute records, a fixed number of buckets and a two-disk system, arrange the records into the buckets and then store the buckets between the disks in such a way that, over all possible orthogonal range queries (ORQs), the disk access concurrency is maximized. We shall adopt the multiple key hashing (MKH) method for arranging records into buckets and use the disk modulo (DM) allocation method for storing buckets onto disks. Since the DM allocation method has been shown to be superior to any other allocation methods for allocating an MKH file onto a two-disk system for answering ORQs, the real issue is knowing how to determine an optimal way for organizing the records into buckets based upon the MKH concept.

A performance formula that can be used to evaluate the average response time, over all possible ORQs, of an MKH file in a two-disk system using the DM allocation method is first presented. Based upon this formula, it is shown that our design problem is related to a notoriously difficult problem, namely the Prime Number Problem. Then a performance lower bound and an efficient algorithm for designing optimal MKH files in certain cases are presented. It is pointed out that in some cases the optimal MKH file for ORQs in a two-disk system using the DM allocation method is identical to the optimal MKH file for ORQs in a single-disk system and the optimal average response time in a two-disk system is slightly greater than one half of that in a single-disk system.  相似文献   

4.
We consider a class of stochastic Nash equilibrium problems (SNEP). Under some mild conditions, we reformulate the SNEP as a stochastic mixed complementarity problem (SMCP). We apply the well-known sample average approximation (SAA) method to solve the SMCP. We further introduce a semismooth Newton method to solve the SAA problems. The comprehensive convergence analysis is given as well. In addition, we demonstrate the proposed approach on a stochastic Nash equilibrium model in the wholesale gas–oil markets.  相似文献   
5.
对水质评价存在诸多方法,而模糊综合评价法具有评价结果合理、更接近客观实际等优点,因而得到越来越广泛的应用。通过模糊评价方法对长江下游贵池河段2005~2009年间水环境综合评价,并采用加权平均原则求取隶属等级,取得较好的效果。  相似文献   
6.
可转债融资与公司股价长期表现实证研究   总被引:1,自引:0,他引:1  
实证检验了我国上市公司可转债融资后的股价长期表现,结果发现,可转债融资后的公司股价并未如配股和增发再融资后的长期表现欠佳,而是有一定的优越表现.以EBIT与Size/BM可比公司进行调整后,一年期的累积超过收益分别为13.52%和17.13%,而以大盘指数调整后的一年期累积超额收益仅为0.41%.对以Size/BM可比公司调整后的累积超额收益给予的多元回归分析发现,可转债发行后的一年期股价市场表现与初始转换概率正相关,与股权稀释因子负相关,而在统计意义上不显著,但制造业公司在可转债发行后股价的一年期市场表现优于非制造业的公司,且在10%的水平下显著.  相似文献   
7.
The calculations of the elastic scattering properties of ultra-cold francium isotopes are reported in detail. A parametric model potential for the triplet molecular states of the Fr2 is represented, and the scattering lengths at and the effective range re are calculated using WKB and Numerov methods for Fr--Fr in the triplet state. The convergence of these scattering properties depending on a K0 parameter and core radius is also investigated using two methods: Quantum Defect Theory and analytical formula of Symskoviski.  相似文献   
8.
A semicircle control chart can be used in detecting both increases and decreases in the mean and/or variance. In this paper, we propose two modified semicircle charts for detecting a reduction in the process variance, a.k.a. process improvement. Each of these modified semicircle charts, namely, SC1 and SC2 has two limits, defined by the inner and outer semicircles. A process improvement is detected by the SC1 scheme if a point is plotted inside the smallest semicircle, or if two successive points are plotted between the inner and outer semicircles and by the SC2 scheme if a point plots inside the smallest semicircle or if two of three successive points plot between the inner and outer semicircles. It will be shown that the two modified semicircle charts have superior average run length (ARL) performances to the basic semicircle chart in the detection of process improvement. The ARL study is conducted by means of a simulation.  相似文献   
9.
This paper introduces a high precision 7m laser measuring instrument developedby the anthors and its operating principle,and systematically analyses the errors havinginfluence on the performance of the measuring instrument.Error analysis and actualverification indicate that all the characteristics reached or exceeded the original designspecifications.  相似文献   
10.
本文提出用有限元方法和按距离加权平均法数值构造地震形变力场,比较了这两种方法的优点和存在的主要问题,并结合计算机口形学的技术描述组成具体实用的系统.  相似文献   
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