火电机组过热器压力和温度的动态研究

基于过热蒸汽比焓和密度的双线性拟合函数，用机理分析法建立了一段过热器集总参数的压力和温度的动态模型。研究表明：该模型能够反映在机组负荷变化范围大的工况下过热系统的主蒸汽压力和温度的动态特性,以及受到减温喷水量或主汽门调门开度扰动时，主蒸汽压力和温度的耦合动态响应。此外，用辐射能信号的函数替代过热器的有效吸热量并结合火电机组的其他实测数据可以对所建模型进行对比验证。     

Synthesis and optophysical properties of blue-emitting iridium （Ⅲ） complex bearing oxadiazole-based picolinic acid derivative

An iridium (III) bis[(4,6-difluorophenyl)pyridinato-N, C²][6-(6′-(4″-(5‴-phenyl-1‴, 3‴, 4‴-oxadiazole- 2‴-yl) phenoxy) hexyloxy picolinate) was synthesized and characterized by ¹H NMR and elementary analysis in order to study the effect of ancillary ligand of the oxadiazole-based picolinic acid derivative on optophysical properties of its iridium complex, and further to obtain an iridium complex with highly-efficient blue emission. The thermal stability, UV absorption and photoluminescent properties of this iridium complex were investigated. Compared with iridium (III) bis[(4,6-difluorophenyl)pyridinato-N, C²](picolinate) reported as a highly-efficient blue electroluminescent material, this iridium complex bearing an oxadiazole-based picolinic acid derivative presents higher thermal stability, more intense UV absorption at 291 nm and similar photoluminescent spectrum peaked at 469 nm. This indicates that tuning ancillary ligand of picolinic acid with an oxadiazole unit can improve the optophysical properties of its iridium complex. Foundation item: Projects(20772101, 50473046) supported by the National Natural Science Foundation of China; Project(2007FJ3017) supported by the Hunan Provincial Science Foundation, China; Project(07C764) supported by the Science Foundation of the Education Department of Hunan Province, China