Room Temperature Ferromagnetism in Co-doped CuAlO2 Nanofibers Fabricated by Electrospinning

One-dimensional, diluted magnetic semiconductor nanofibers have attracted increasing attention for their unique magnetic properties, large specific surface area, and high porosity. These qualities lead to excellent performance in magneto-optical devices, magnetic resonance imaging, ferrofluids and magnetic separation. The purpose of this study is to fabricate P-type one dimensional CuAlO2-based diluted magnetic semiconductor nanofibers. First, we fabricated Cu Al0.95Co0.05O2 nanofibers with an average diameter of 1 μm with the electrospinning method. The annealed nanofibers were thermally treated at a temperature of 1 100 ℃ and then shrunk to a diameter of about 650 nm. We used X-ray diffraction measurements and Raman spectra to confirm that the Cu Al0.95Co0.05O2 nanofibers had a single impurity free delafossite phase. The X-ray photoelectron spectroscopy analysis indicates that Co was present in the +2 oxidation state, resulting in an room temperature ferromagnetism in the Cu Al0.95Co0.05O2 fiber. This contrasts with nonmagnetism in pristine CuAlO2 fiber. The coercivity(Hc) value of 65.26 Oe and approximate saturation magnetization(Ms) of 0.012 emu/g demonstrate good evidence of ferromagnetism at room temperature for Cu Al0.95Co0.05O2 nanofibers.     

介孔-大孔结构无定形硅-铝催化剂的核磁共振研究

合成了具有介孔-大孔双模型分级结构的无定形硅-铝催化剂,利用硅和铝核的固体魔角核磁共振谱,考察了合成样品中硅和铝结构上的原子特征.     

钻井井喷失控井喷流出口速度预测方法研究

失控井喷流出口速度、喷口内压力、喷层产量都是井喷失控处理方案设计、作业施工中重要的基础数据。由于井喷失控井井口环境条件复杂，井喷失控后无法在井口安装测量仪表及在高速喷流中放入参照物，不能直接获取以上数据。文章利用地质、钻井过程获得的地层物性参数和气体动力学方程，探讨井喷失控井天然气喷流在不同井筒流动尺寸及组合的喷流速度预测模型，可应用薄剪切模型或RNG修正的k-ε模型定量描述速度场、温度场、浓度场颁。为井喷失控井处理方案设计、施工作业提供基础数据。     

自喷井电动清蜡绞车的研制

针对目前石油钻采用清蜡绞车总体结构设计不合理以及实用性不强等技术难题,研制开发了自喷井电动清蜡绞车。该绞车的核心部件包括过载保护安全装置、牙嵌离合器轴套、自动/手动互换装置、计量装置以及密封装置。在清蜡绞车自动工作中,当清蜡刮刀遇到较大阻力时,清蜡绞车将接收到反馈信号,可实现智能停车,自动转换为手动状态,以便操作人员检查和排除故障,从而确保了操作的安全性,延长了设备的使用寿命。1000余台电动清蜡绞车的现场应用表明,该产品可以大大降低原油的开采成本,具有良好的经济效益和社会效益。     

绚丽多彩的楚汉丝织品（之二）──色彩与纹饰

湖南出土的楚汉丝织品，以马王堆一、三号汉墓所出为代表，其色彩反映了我国当时印染工艺技术所达到的高度水平，其纹饰则显示了鲜明的时代特征，表现了运动、气势和古拙的艺术风格，充满着神奇浪漫的色彩。     

汉字环境下FOXPRO FOR DOS图形处理的实现

本文主要讨论通过汇编语言与Foxpro的编程接口,利用显示卡直接编程技术,在Foxpro for Dos中实现图形处理的方法.