Structure and Magnetic Property Control of Copper Hydroxide Acetate by Non‐Classical Crystallization

Copper hydroxide acetate (CHA), one layered hydroxide compound with tunable magnetism, attracts great interest because of its potential applications in memory devices. However, ferromagnetism for CHA is only demonstrated by means of GPa pressure. Herein, a new method is reported, involving the combination of different crystallization pathways to control crystallization of amorphous CHA toward the formation of CHA/polymer composites with tunable magnetic properties and even a tunability that can be tested at room temperature. By using poly[(ethylene glycol)₆ methyl ether methacrylate]‐block‐poly[2‐(acetoacetoxy) ethyl methacrylate] (PEGMA‐b‐PAEMA) diblock copolymers as additives in combination with a post‐treatment process by ultracentrifugation, it is demonstrated that CHA and PEGMA‐b‐PAEMA form composites exhibiting different magnetic properties, depending on CHA in‐plane nanostructures. Analytical characterization reveals that crystallization of CHA is induced by ultracentrifugation, during which CHA nanostructures can be well controlled by changing the degrees of polymerization of the PEGMA and PAEMA blocks and their block length ratios. These findings not only present the first example of using crystallization from polymer stabilized amorphous precursors toward the generation of magnetic nanomaterials with tunable magnetism but also pave the way for the future design of functional composite materials.     

Passive Filtration of Airborne Particles from Buildings Ventilated by Natural Convection: Design Procedures and a Case Study at the Buddhist Cave Temples at Yungang,China

Air exchange between interior spaces and the outdoor atmosphere can occur due to a variety of processes, including wind-driven flows and natural convectiondriven flows. As air is exchanged with the outdoors, airborne particles can be brought inside. Depending on the use of the indoor space, the presence of particles in indoor air could be a nuisance to the occupants or could be damaging to materials kept indoors. While one obvious solution to such problems is to install a mechanical air filtration system, that is not always practical. In particular, the character of some historical houses and some archaeological sites would be degraded by the presence of a mechanical air distribution system, and in some parts of the world the reliable electrical power supply needed for such a filtration system may not be available. In the present paper we consider principles for the design of passive filtration systems in which air motion through the filter material is induced by a natural convection flow rather than by a mechanical fan. A fluid mechanical model first is described for predicting the air flow through an interior space that acts as a thermal siphon. The effect of placing filter material in the path of such air flows is examined next. The indoor-outdoor air quality model of Nazaroff and Cass (1989a) is matched to the natural convection air exchange model, and calculations are performed to determine the relationship between the outdoor particle size distribution and indoor particle size distributions and particle deposition rates given a passive filtration system. Example calculations are worked for the case of a passive particle filtration system that could be installed to protect the interior of the Buddhist cave temples at Yungang, China. These are a collection of manmade cave temples dating from the 5th century AD, now situated in the middle of one of China's largest coal-mining regions with its accompanying air pollution problems.     

3D measures exploitation for a monocular semi-supervised fall detection system

Falls have been reported as the leading cause of injury-related visits to emergency departments and the primary etiology of accidental deaths in elderly. Thus, the development of robust home surveillance systems is of great importance. In this article, such a system is presented, which tries to address the fall detection problem through visual cues. The proposed methodology utilizes a fast, real-time background subtraction algorithm, based on motion information in the scene and pixels intensity, capable to operate properly in dynamically changing visual conditions, in order to detect the foreground object. At the same time, it exploits 3D space’s measures, through automatic camera calibration, to increase the robustness of fall detection algorithm which is based on semi-supervised learning approach. The above system uses a single monocular camera and is characterized by minimal computational cost and memory requirements that make it suitable for real-time large scale implementations.     

Design and Testing of a Robotic System for mr Image-guided Interventions

The effective integration of robotics together with magnetic resonance (mr) technology is expected to facilitate the real-time guidance of various diagnostic and therapeutic interventions. Specially designed robotic manipulators are required for this purpose, the development of which is a challenging task given the strong magnetic fields and the space limitations that characterize the mr scanning environment. A prototype mr-compatible manipulator is presented, designed to operate inside cylindrical mr scanners. It was developed for the study of minimally invasive diagnostic and therapeutic interventions in the abdominal and thoracic area with real-time mr image guidance. Initial tests were performed inside a high-field clinical mr scanner and included mr-compatibility tests and phantom studies on image-guided targeting.     

Assessment of an experimental bone wax polymer plus TGF-beta 1 implanted into calvarial defects

The study reported describes an experimental biodegradable polymer ceramic composite with wax-like handling properties that was combined with 2.0 micrograms of recombinant human transforming growth factor beta (rhTGF-beta(1)). The polymer/rhTGF-beta(1) combination was introduced into standard-sized calvarial defects in rabbits to evaluate biodegradability, biocompatibility, hemostasis control, and bone promotion. The experimental wound model was a standard-size circular calvarial defect 8 mm in diameter. The experimental design included 24 skeletally mature New Zealand white rabbits divided evenly between two time periods (6 and 12 weeks) and among three experimental treatments (untreated defects and defects treated with polymer with or without rhTGF-beta(1)). Evaluations consisted of clinical examinations, standarized radiography, radiomorphometry, as well as histology and histomorphometry. Data were analyzed by an Analysis of Variance (ANOVA) and Fisher's Protected Least Significant Difference test at each time period (level of significance p < or = 0.05). Radiomorphometry data indicated that standard-sized defects treated with the wax-like polymer alone and the polymer plus 2.0 micrograms of TGF-beta(1) were significantly more radiopaque than control sites at both 6 and 12 weeks. Histomorphometric data revealed the amount of new bone was significantly greater at 6 weeks in the polymer plus 2.0 micrograms of TGF-beta(1) and in the control group than in the polymer alone. Moreover, at 12 weeks, there was significantly more new bone in the control than in either the polymer alone or the polymer plus 2.0 micrograms of TGF-beta(1). We speculate the incomplete biodegradation of the polymer ceramic composite contributed to the radiopacity and may have retarded osseous regeneration. It is important that the bone wax-like polymer material was biocompatible and acted as a hemostatic agent.     

Concepts of Wildland Fire Protection of Cultural Monuments and National Parks in Greece. Case Study: Digital Telemetry Networks at the Forest of Ancient Olympia

The concepts and particularities of fire protection planning for monuments of cultural heritage that are surrounded by national parks and other public wildlands are outlined, in the context of the general wildland fire problem of Greece. Typical examples of cultural monuments that were threatened by wildland fires in Greece are reported. A conceptual flowchart that combines optimal fire protection objectives with the protected values and functions of the national parks and cultural monuments is analyzed. A case-study presents the development of an electronic forest fire protection support system in the forest around the Ancient Olympia site in Greece, as an example of the potential deployment of innovative technologies in wildland fire protection. The aim of the system is twofold. First, the system supports remote monitoring of an extensive hydraulic network of pipelines, pumps and water-storage tanks build in the vicinity of the site. Second, the system provides means for remote operation of numerous revolving water-jets installed on top of heavy-duty tree-high metal towers, spread at key-locations inside the surrounding forest. All system telemetry data and command signals are transmitted through a single underground wire link requiring no external electric power at sensor/actuator locations inside the forest. Special user interfaces allow immediate system deployment either from a central graphics-based console screen or from purpose-build remote consoles installed at selected locations in the forest, thus achieving a high degree of readiness.     

Particle size distribution and atmospheric metals measurements in a rural area in the South Eastern USA

Atmospheric particle mass concentrations were measured at a site adjacent to Lake Hartwell, GA, during six dry sampling events in February-March 2003. The overall average PM2.5 mass concentration was 9.5 microg/m3 and the overall average total suspended particles mass concentration was 19.1 microg/m3. Particulate matter was collected on a deposition plate mounted onto a specially designed wind vane and was subsequently analyzed to determine the particle size distribution. The average geometric particle diameter was found to be 2.8 microm. Particulate matter collected was found to be closely approximately at log-normal distribution, with a count median diameter of 1.5 mum and a geometric standard deviation of 1.8. Individual metal concentrations present in airborne particulate matter were determined for cadmium, chromium, copper, iron, lead, manganese, nickel, and zinc using inductively coupled plasma-mass spectrometry analysis of samples collected on Teflon filters. Ambient metal concentrations were found to range from 0.8 ng/m3 for cadmium to 512 ng/m3 for iron. The dry deposition flux of metals was estimated to be in the range of 0.17 mg/(m2 year) for cadmium to 102 mg/(m2 year) for iron. More samples need to be collected and analyzed, both temporally and spatially, in order to establish atmospheric metals fluxes onto surfaces.     

Characteristics of W and Cu/W gate MOS diodes fabricated by a process utilizing LPCVD of W and Cu lift-off

MOS diodes having double layer Cu/W, W, or Al gates were fabricated using tungsten chemical vapor deposition, copper evaporation and lift-off and were characterized before and after thermal anneals. The breakdown field statistics were determined for all kinds of devices, while the high field conduction and charge trapping in the oxide were investigated. The W gate devices exhibited high performance and very low degradation even after annealing at 650 °C. In Cu/W gate diodes good barrier action of our LPCVD tungsten films against copper penetration after annealing at 510 °C was observed, while reduced breakdown integrity and degradation due to copper diffusion occurred after annealing at 650 °C.