Mechanistic origins of multi-scale reinforcements in segmented polyurethane-clay nanocomposites

The objective of the present work is to get insights into the mechanistic origin of the reinforcement effects of nanoclay on a segmented polybutadiene polyurethane-urea system. To this end, a convergent analysis of the hard domain morphology and conformational state of soft segment in the nanocomposites was carried out by using a combination of complementary characterization techniques, namely, Fourier transform infrared spectroscopy, small angle neutron scattering, transmission electron microscopy, modulated differential scanning calorimetry and dynamic mechanical analysis. Analysis of small angle neutron scattering data by a combination of Percus–Yevick hard sphere and Zernike-Ornstein model coupled with direct visualization of the dispersed hard domain morphology from transmission electron microscopy provided insight on clay induced changes in the hard domain morphology. A monotonic decrease in the domain size as well as the average interdomain distance was observed with increasing nanoclay content in the polymer matrix. Analysis of the carbonyl stretching region from FTIR showed increased degree of hydrogen bonding for the urethane carbonyl groups of the nanocomposites compared to the neat matrix. A combination of calorimetric and dynamic mechanical analysis revealed the existence of a constrained amorphous region; quantified to be ≈ 16% at the highest clay content experimented. The manifestation of these morphological and conformational changes on the nano-, micro- and macro scale reinforcements in the nanocomposites was investigated by mechanical properties at these length scales using nanoindentation, DMA and tensile testing, respectively.     

Sustainable thermal energy storage technologies for buildings: A review

Energy management in buildings is indispensable which would control the energy use as well as the cost involved while maintaining comfort conditions and requirements in indoor environments. Energy management is intensely coupled with energy efficiency and increasing of which would provide a cost-effective pathway for reducing greenhouse gas emissions. In recent years, the magnitude of energy consumption in buildings seems to crest from the normal demand and that has to be carefully addressed through implementing energy conservative and energy management techniques. In the class of having several energy efficient schemes, thermal energy storage (TES) technologies for buildings are increasingly attractive among architects and engineers. In the scenario of growing energy demand worldwide, the possibility of improving the energy efficiency of TES systems can be achieved from break-through research efforts. The prime intention of this paper is to review the potential research studies pertaining to a variety of latent heat energy storage (LHES) and cool thermal energy storage (CTES) systems solely dedicated for building heating, cooling and air conditioning (A/C) applications. Technical revelations regarding the integration and performance evaluation of heat storage materials in building fabric elements as well as using separate heat storage facility to satisfy the space thermal load demand have been gleaned from numerous research contributions and presented. Emphasis is also given on advanced heat storage materials produced using micro and nanoparticles to realize their improved heat transfer characteristics which would eventually enhance the overall performance of these TES systems. Furthermore, the sustainable aspects of these TES systems to gain the Leadership in Energy and Environmental Design (LEED) credentials for low carbon/high performance buildings are signified.     

Downlink Radio Resource Management Through CoMP and Carrier Aggregation for LTE-Advanced Network

Long Term Evolution-Advanced (LTE-A) offers several new technologies to improve the performance of the user. However, poor received signal and interference from adjacent cells in the cell-edge area can reduce the efficiency of using individual technology. Therefore, the cell-edge users have lower throughput compared to the other users in the cell and LTE-A standard. An efficient downlink radio resource management scheme is proposed in this paper by combining the coordinated multipoint transmission and reception technique along with carrier aggregation technique to achieve higher throughput for the cell-edge user and better overall performance. The proposed method jointly transmits multiple component carriers to the cell-edge user from different cells to increase the bandwidth, strengthen the received signal, and reduce the interference while it satisfies several constraints. Modified largest weighted delay first packet scheduling algorithm is deployed for resource allocation, which takes into account the delay parameters, the probability of packet loss, and data rates of the user. The obtained system-level simulation results show that the proposed method significantly enhances the throughput performances, spectral efficiency, and fairness index, compared with the existing conventional methods.

     

Formation and characterization of polyurethane—vermiculite clay nanocomposite foams

Nanocomposites of rigid polyurethane foam with unmodified vermiculite clay are synthesized. The clay is dispersed either in polyol or isocyanate before blending. The viscosity of the polyol is found to increase slightly on the addition of clay up to 5 pphp (parts per hundred parts of polyol by weight). The gel time and rise time are significantly reduced by the addition of clay, indicating that the clay acts as a heterogeneous catalyst for the foaming and polymerization reactions. X‐ray diffraction and transmission electron microscopy of the polyurethane composite foams indicate that the clay is partially exfoliated in the polymer matrix. The clay is found to induce gas bubble nucleation resulting in smaller cells with a narrower size distribution in the cured foam. The closed cell content of the clay nanocomposite foams increases slightly with clay concentration. The mechanical properties are found to be the best at 2.3 wt% of clay when the clay is dispersed in the isocyanate; the compressive strength and modulus normalized to a density of 40 kg/m³ are 40% and 34% higher than the foam without clay, respectively. The thermal conductivity is found to be 10% lower than the foam without clay. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers     

Mechanisms of Solution Reactions of Cyclo-Penta[cd]Pyrene Oxide and Acenaphthylene Oxide

Rates and products of the acid-catalyzed and spontaneous reactions of cyclopenta[cd]pyrene oxide (2) and acenaphthalene oxide (3) in 1:3 dioxane-water and water, respectively, have been determined. Both 2 and 3 undergo acid-catalyzed hydrolyses to yield cis diol as the major product, and undergo spontaneous reactions to yield predominantly ketone products. The mechanisms of these reactions are discussed.     

A 0.15-V, 44.73% PCE charge pump with CMOS differential ring-VCO for energy harvesting systems

Analog Integrated Circuits and Signal Processing - This paper proposes a dynamic voltage frequency scaling technique (DVFS) for a CMOS differential bootstrapped ring-voltage controlled oscillator...     

Variable-Order Ant System for VLSI multiobjective floorplanning

Floorplanning is crucial in VLSI chip design as it determines the time-to-market and the quality of the product. In this work, Variable-Order Ant System (VOAS) is developed and combined with a floorplan model namely Corner List (CL) to optimize the area and wirelength. CL is used to represent the floorplan layout. Although CL has proven to have the same search space and time complexity as Corner Sequence (CS), comparatively, CL has more corners to be selected. This compensates the sequence weakness, where modules can be placed freely onto the corners, which are not bounded by the floorplan contour. Two groups of ants, namely VOAS and reconnaissance ants, which will collaborate with each other to determine the local information, are introduced. Through this cooperation, VOAS ant can ascertain its local information greedily, based on the local search space information carried out by reconnaissance ants. Subsequently, VOAS ant proposes a new variable-order property to prioritize the global and local explorations. The variable-order property enables the ants in VOAS to weigh a better choice of modules for the floorplanning, based on the local and global information. The update rules of VOAS are modified in order to handle two-dimensional problem, such as VLSI floorplanning. VOAS shows improved results in terms of purely area optimization as well as composite function of area and wirelength, as compared to other state-of-the-art and recent floorplanning/placement algorithms based on Microelectronics Centre of North Carolina (MCNC) and Gigascale Systems Research Center (GSRC) benchmarks.