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1.
Atsushi Narumi Kosei Kawasaki Harumi Kaga Toshifumi Satoh Naoya Sugimoto Toyoji Kakuchi 《Polymer Bulletin》2003,49(6):405-410
Summary
The potato phosphorylase-catalyzed polymerization of α-D-glucose-1-phosphate (G-1-P) onto poly[styrene-block-(4-vinylbenzyl maltohexaoside)] (1) was performed at the molar ratios of [G-l-P]0 and [maltohexaose]0 of 35, 80, and 250. The product was found to be soluble in dimethyl sulfoxide, which was a good solvent for amylose, and
showed the complex-formation with iodine, indicating that the product was assignable to poly[styrene-block-(styrene-graft-amylose)] (2). The quantitative analysis of the liberated phosphoric acid gave the average degree of polymerization o f the glucose unit
(n) as 27, 5 1, and 180 for 2-I, 2-II, and 2-III, respectively.
Received: 29 November 2002/Accepted: 22 December 2002
Correspondence to Toyoji Kakuchi 相似文献
2.
Matano T. Takai Y. Takahashi T. Sakito Y. Fujii I. Takaishi Y. Fujisawa H. Kubouchi S. Narui S. Arai K. Morino M. Nakamura M. Miyatake S. Sekiguchi T. Koyama K. 《Solid-State Circuits, IEEE Journal of》2003,38(5):762-768
A 1-Gb/s/pin 512-Mb DDRII SDRAM has been developed using a digital delay-locked loop (DLL) and a slew-rate-controlled output buffer. The digital DLL has a frequency divider for DLL input, performs at an operating frequency of up to 500 MHz at 1.6 V, and provides internal clocking with 50% duty-cycle correction. The DLL has a current-mirror-type interpolator, which enables a resolution as high as 14 ps, needs no standby current, and can operate at voltages as low as 0.8 V. The slew-rate impedance-controlled output buffer circuit reduces the output skew from 107 to 10 ps. This SDRAM was tested using a 0.13-/spl mu/m 126.5-mm/sup 2/ 512-Mb chip. 相似文献
3.
Harumi Yokokawa Tatsuya Kawada Masayuki Dokiya 《Journal of the American Ceramic Society》1989,72(1):152-153
It has been found that the enthalpy of formation of perovskite compounds, Δf H° (ABO3 , B = transition metais), from binary oxides can be well characterized in terms the tolerance factor, t≡(rA + ro )√2 (rB + ro ), where rA and rB are the radii of A-site ions with 12-coordination and B-site ions with 6-coordination, respectively, and Δf H°=−168 + 270(1 − t) kJ·mol−1 for AI BV O3 , Δf H°=−125 + 1000(1 − t) kJ·mol−1 for AII BIV O3 , and Δf H°=− 90 + 720(1 − t) kJ·mol−1 for AIII BIII O3 . Although the thermodynamic data of K2 NiF4 compounds are not extensive, a similar regularity can be found when use is made of the radii of A-site ions with 9-coordination for the K2 NiF4 compounds. These correlations will be quite useful in predicting. 相似文献
4.
Fate of the chlorine and fluorine in a sub-bituminous coal during pyrolysis and gasification 总被引:1,自引:0,他引:1
The fate of the chlorine and fluorine present in a sub-bituminous coal from Indonesia during pyrolysis and gasification has been studied with fixed and entrained bed reactors. The rate profile for HCl evolved in the temperature programmed pyrolysis exhibits the main and shoulder peaks at 480 and 600 °C, respectively. Model experiments and subsequent Cl 2p XPS measurements show that HCl reacts with metal impurities and carbon active sites at 500 °C to be retained as inorganic and organic chlorine forms, from which HCl evolves again at elevated temperatures. It is suggested that the HCl observed in the coal pyrolysis may originate from the above-mentioned chlorine functionalities formed by secondary reactions involving the nascent char. In the CO2 gasification of the 900 °C char at 1000 °C and 2.5 MPa, any measurable amounts of HCl and HF could not be detected even at a high conversion of 75 wt% (daf), suggesting the accumulation of these halogens in the residual char. When the coal is injected into an O2-blown, entrained bed gasifier at 1200-1400 °C under 2.6 MPa, the partial oxidation proceeds to a larger extent at a higher O2/coal ratio, whereas the chlorine and fluorine are enriched in the remaining char, and the extent of the enrichment at the latter stage of gasification is larger with the fluorine. The XPS measurements of the chars reveal the presence of the broad F 1 s peak, which can cover a wide range of binding energies attributable to inorganic and organic fluorine. The halogen enrichment during gasification is discussed in terms of secondary reactions of HCl and HF with char. 相似文献
5.
Guimes Rodrigues Filho Leandra Cardoso Toledo Daniel Alves Cerqueira Rosana Maria Nascimento de Assunção Carla da Silva Meireles Harumi Otaguro Sizue Ota Rogero Ademar Benévolo Lugão 《Polymer Bulletin》2007,59(1):73-81
Summary In this article, cellulose acetate produced through the homogeneous acetylation of sugar cane bagasse cellulose was used to
produce membranes, using poly(ethyleneglycol) 600 (PEG 600) as an admixture. The membranes were characterized using water
flux measurements (Payne’s cup), differential scanning calorimetry (DSC) and neutral red uptake (cytotoxicity). The results
showed that PEG 600 acts as a crystallinity inductor and/or pore former in the cellulose acetate matrix. The induction of
crystallinity is important for this system since it had not been reported on the literature yet. The results also demonstrated
that the studied membranes present a nontoxic behavior. 相似文献
6.
The contribution of ozone and hydroxyl radical to the formation of bromate ion was investigated in a continuous flow reactor. Experiments were conducted under a wide range of ozone dose (0.7 ~ 3.8 mgL), pH (6.5 ~ 8.5), and t-butanol concentration (0 ~ 0.5 mM). The formation of bromate ion was found to depend on radical reaction pathway, because the amount of bromate ion formed increased with pH and decreased with t-butanol, a radical scavenger, even when dissolved ozone concentrations were almost the same. In fact, the amount of bromate ion formed was reduced by 90% in the presence of t-butanol. Furthermore, the formation of bromate ion occurred even when dissolved ozone was not significantly detected in the presence of organic matter (TOC of 1 mgCL). The second-order reaction rate constant of hydroxyl radical with bromide ion, k HO,Br? of 1.7 × 109 (M?1s?1), was obtained on the assumption that the reactions of bromide ion and t-butanol with hydroxyl radical were competitive with each other in the presence of t-butanol and that the formation of bromate ion depended on the reaction of bromide ion with hydroxyl radical. Therefore, it is concluded that the reaction of bromide ion with hydroxyl radical dominated in the overall reaction from bromide ion to bromate ion in the continuous flow reactor. 相似文献
7.
Tomoyo Okumura Kenya Sonobe Asami Ohashi Harumi Watanabe Katsushi Watanabe Hiroshi Oyamada Masaaki Aramaki Toshiaki Ougizawa 《Polymer Engineering and Science》2020,60(7):1699-1711
Simultaneous one-pot syntheses of PA66 and HAp were carried out by extracting H2O and CO2 from PA66 monomers and HAp raw materials, respectively, resulting in the formation of a polyamide (PA) 66-hydroxyapatite (HAp) nanocomposite. During the process, a spherical nano-sized HAp particle was precipitated following dissolution of micro-sized CaHPO4・2H2O. The PA66 monomers were subsequently adsorbed onto the generated HAp product. Some of the adsorbed PA66 monomers formed a bound polymer on HAp, and an increase in the adhesiveness of the PA66-HAp interface was observed as the polymerization progressed. During this process, the synthesis of a nanocomposite from a micro-sized raw material and creation of an autonomous strong interface between the matrix and filler was achieved. In addition, the shape of the resultant HAp was controllable and could be modified to needle shape by the addition of F− and Mg2+ ions to the raw material. HAp could also be changed to plate shape via octa-calcium phosphate (OCP). Notably, during the synthesis, the filler shape of the nanocomposite could be controlled to 0D (particle), 1D (needle), and 2D (plate). 相似文献
8.
Xiande Shen Yoshikazu Kitajyo Qian Duan Atsushi Narumi Harumi Kaga Noriaki Kaneko Toshifumi Satoh Toyoji Kakuchi 《Polymer Bulletin》2006,56(2-3):137-143
Summary The reaction of the carboxymethyl cellulose sodium salt (Na-CMC) (degrees of substitution (DS) = 1.2) with N-hydroxysuccinimide (Su-OH) in the presence of 1-hydroxybenzotriazole and 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC)
was carried out in water to obtain the Su-OH ester of carboxymethyl cellulose, Su-CMC, with the DS values of 0.19 – 1.04.
N-Allylcarbamoylmethyl cellulose (Allyl-CMC), which was prepared from the reaction of Su-CMC with an excess amount of allylamine,
was crosslinked by UV-irradiation. In addition, the photocrosslinked Allyl-CMC film was swollen with water to form a hydrogel
having a relatively high water-swelling property, e.g., the degree of swelling (ds) was ca. 360% for Allyl-CMC with the DS
of 0.93. 相似文献
9.
Teruhisa Horita Haruo Kishimoto Katsuhiko Yamaji Manuel E. Brito Yueping Xiong Harumi Yokokawa 《Journal of power sources》2009,193(1):180-184
Reactivity of oxide scale on Fe-Cr alloy with Na-containing gases was examined to estimate the stability against sodium (Na): vapors of NaCl and Na2SO4 exposures with air flow at 1073 K. The identified reaction phases were Cr-Mn spinel, Cr2O3, and alloy from the X-ray diffraction of surface with no Na-reaction products. However, the protective oxide scales (Mn-Cr spinel and Cr2O3 layers) on the Fe-Cr alloy were partially decomposed by reacting with Na to form Na-compounds inside the oxide scale/alloy interfaces. In some parts, anomalous oxide scales were found around the oxide scale/Fe-Cr alloy interfaces, with forming Na-rich compounds: the compounds were distributed inner parts of oxide scales around oxide scale/alloy interfaces. The stability of oxide scales and degradation were discussed based on the observed distribution of elements. 相似文献