Development of nanocomposites based on organically modified montmorillonite and plasticized PVC with improved barrier properties

Montmorillonite (MMT) was organically modified with tributyl citrate (TBC). Organoclays (OMMTs) were processed with diisononyl phthalate (DINP)‐plasticized polyvinyl chloride (PVC) to form polymer nanocomposites. The produced composite materials showed a contradictory change in properties to that expected of a layered silicate nanocomposite, with a decreased E‐modulus and increased gas permeability compared with a material without OMMT. It was experimentally shown that the TBC modifier was extracted from the OMMT and was dispersed in the PVC/DINP matrix, whereupon the OMMT collapsed and formed micrometer‐sized agglomerates. Further investigation revealed that TBC has a significant effect on the gas permeability and the E‐modulus, even at low additions to a DINP‐plasticized PVC. A PVC nanocomposite with the TBC acting as both the OM for MMT and as the primary plasticizer was produced. This material showed a significantly increased E‐modulus as well as a decrease in gas permeability, confirming that it is possible to develop a nanocomposite based on plasticized PVC, if both the organo‐modification of the MMT and the formulation of the matrix are carefully selected. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 42876.     

Simplified Model and Closed-Loop Control of a Commutatorless DC Motor

A simplified dynamic model of a current-fed, self-commutated synchronous motor, operating with a constant angle between the motor counter electromotive force (CEMF) and the input current. The model, which is justified experimentally, includes only two time constants, associated with the rotor inertia and the dc link inductance. This permits the design of the current and speed controlling loops along the same principles used for classical armature-controlled dc motor drives. In this way, the experience which is widely available in industry can be applied, at least with a good approximation, to design of the commutatorless dc motor drives. Various control configurations are discussed. Control loops are designed and closed around the basic motor-inverter block. An experimental result is obtained for each control configuration, thus validating the proposed model.     

17 alpha-Hydroxyprogesterone responses to leuprolide and serum androgens in obese women with and without polycystic ovary syndrome offer dietary weight loss

Insulin resistance and increased ovarian cytochrome P450c17 alpha activity (i.e. increased 17 alpha-hydroxylase and, to a lesser extent, increased 17,20-lyase) are both features of the polycystic ovary syndrome (PCOS). Evidence suggests that hyperinsulinemia may stimulate ovarian P450c17 alpha activity in obese women with PCOS. We hypothesized that weight loss would decrease serum insulin and P450c17 alpha activity in PCOS. Therefore, we measured serum steroid concentrations and 17 alpha-hydroxyprogesterone responses to leuprolide administration and performed oral glucose tolerance tests before and after 8 weeks of a hypocaloric diet in 12 obese women with PCOS (PCOS group) and 11 obese women with normal menses (control group). Serum insulin decreased in both groups. In the PCOS group, basal serum 17 alpha-hydroxyprogesterone decreased from 4.2 +/- 0.6 to 3.0 +/- 0.5 nmol/L (P < 0.05), and leuprolide-stimulated peak serum 17 alpha-hydroxyprogesterone decreased from 14.9 +/- 2.6 to 8.9 +/- 0.8 nmol/L (P < 0.025). Serum testosterone decreased from 2.47 +/- 0.52 to 1.56 +/- 0.33 nmol/L (P < 0.05), and free testosterone decreased from 9.03 +/- 1.39 to 5.95 +/- 0.50 pmol/L (P < 0.02). None of these values changed in the control group. Serum sex hormone-binding globulin increased by 4.5- and 3-fold in the PCOS (P < 0.003) and control (P < 0.007) groups, respectively. We conclude that dietary weight loss decreases ovarian P450c17 alpha activity and reduces serum free testosterone concentrations in obese women with PCOS, but not in obese ovulatory women. The changes in women with PCOS may be related to a reduction in serum insulin.     

The calcium channel blocker amlodipine raises serum dehydroepiandrosterone sulfate and androstenedione, but lowers serum cortisol, in insulin-resistant obese and hypertensive men

To determine whether the calcium channel blocker amlodipine improves glucose tolerance and alters serum adrenal androgen and glucocorticoid levels in insulin-resistant men, 24 obese and hypertensive men were enrolled into a single blind, placebo-controlled study. An amlodipine group (n = 12) and a placebo group (n = 12) were studied before and after treatment with either amlodipine (5 mg) or placebo capsule twice daily for 7 days by determining serum insulin, glucose, dehydroepiandrosterone sulfate (DHEA-S), androstenedione, and cortisol in the fasting state and during an oral glucose tolerance test. Amlodipine treatment 1) lowered fasting serum insulin (from 273 +/- 19 to 200 +/- 17 pmol/L; P < 0.0005) and glucose (from 5.4 +/- 0.1 to 5.1 +/- 0.1 mmol/L; P < 0.02), 2) reduced the area under the curve for glucose (from 1342 +/- 25 to 1198 +/- 23 mmol/L.min; P = 0.0001) and the area under the curve for insulin (from 155.5 +/- 7.8 to 103.9 +/- 4.3 nmol/L.min; P = 0.0001) during the oral glucose tolerance test, 3) increased fasting serum DHEA-S (from 5.19 +/- 0.37 to 7.95 +/- 0.58 mumol/L; P = 0.0001) and androstenedione (from 5.65 +/- 0.65 to 6.83 +/- 0.53 nmol/L; P < 0.01), and 4) decreased fasting serum cortisol (from 538 +/- 35 to 494 +/- 26 nmol/L; P < 0.05). Fasting serum androstenedione declined slightly in the placebo group (from 5.96 +/- 0.60 to 5.74 +/- 0.57 nmol/L; P < 0.005), but no change occurred in glucose tolerance, fasting serum DHEA-S, or cortisol. We conclude that amlodipine treatment improves glucose tolerance, reduces fasting and glucose-stimulated serum insulin levels, increases serum DHEA-S and androstenedione levels, and decreases circulating cortisol.     

The Mechanical Properties of the Novel Nanocrystalline Refractory Tantalum Alloys

Protection of Metals and Physical Chemistry of Surfaces - The nanocrystalline tantalum alloys were investigated in terms of mechanical properties. The materials were obtained by powder metallurgy...     

Insulin stimulates testosterone biosynthesis by human thecal cells from women with polycystic ovary syndrome by activating its own receptor and using inositolglycan mediators as the signal transduction system

To determine whether insulin stimulates human ovarian testosterone production in the polycystic ovary syndrome by activating its own receptor and using inositolglycan mediators as the signal transduction system, thecal cells from polycystic ovary syndrome women were isolated and cultured. Insulin and insulin-like growth factor I stimulated thecal testosterone biosynthesis. Antibody blockade of the insulin receptor abolished insulin's stimulatory action, whereas effective antibody blockade of the insulin-like growth factor I receptor did not alter insulin's stimulation of thecal testosterone biosynthesis. A chiro-inositol containing glycan (INS-2) increased thecal testosterone biosynthesis. Preincubation of cells with an antiinositolglycan antibody (A23939 or alpha IGP) abolished insulin's stimulatory effect, but not that of hCG. These findings suggest that inositolglycans serve as the signal transduction system for insulin's stimulation of human thecal testosterone biosynthesis.     

Initial surface topography changes during divalent dissolution of silicon electrodes

The changes of the surface topography of float zone (FZ) n-Si(1 1 1) upon conditioning of the electrodes at potentials slightly anodic of the rest potential are monitored with atomic force microscopy (AFM) in the contact mode. The influence of the composition of the used 0.1 and 0.2 M NH₄F electrolyte at pH 4, of the potential and of the charge passed on the topography is investigated. The dissolution charges Q_diss ranged from 0.28 to 10.6 mC cm⁻² corresponding to ∼0.5 and ∼21 bilayers (BL), respectively. The root mean square roughness R_q changes from R_q=0.2 nm for the H-terminated surface to 2.9 nm for a charge passed of 10.6 mC cm⁻² at an electrode potential of 0.1 V positive of the rest potential. The evaluation of height, deflection and line scan AFM data shows pitting to originate at edges of oriented steps which separate atomically smooth terraces. Upon increased dissolution charge, island-type smooth and rather circular features form. Only for the highest Q_diss, these islands are beginning to show corrosion. An exponential relation between R_q and Q_diss is found by evaluation of the three-dimensional roughness. The slope, i.e. the increase of ln R_q with Q_diss depends on the composition of the electrolyte and is higher for the 0.1 M NH₄F solution. From these data, a branching of the dissolution reaction between charge going into terrace removal or pit formation is obtained. Synchrotron radiation photoelectron spectroscopy (SRPES) is used to identify chemical products of the dissolution process.Comparison of data obtained at 0.15 V anodic of the electrode rest potential with an elaborate model of Gerischer and coworkers (which, however, only describes terrace dissolution) yields partial agreement with the predictions.     

Etude voltamperometrique de la n-acetyl l-tyrosine amide sur electrode a pate de graphite en milleux aqueux I—comportement dans les domaines de balayage superieurs a 0,5 v/enh

Graphite paste electrode allows to determine elementary processes of the electrochemical oxidation in aqueous media of an electrochemical probe such as: N-acetyl L-tyrosine amide. Mathematical analysis of voltammograms gives the following EC mechanism: R?C₆H₅OH?R?C₆H₅O^. + H⁺ + e 2 R?C₆H₅O^. → R?C₆H₅O⁺ + R?C₆H₅O^?, R?C₆H₅O^? + H⁺ → R?C₆H₅OH, R?C₆H₅O⁺ → [R?C₆H₄O]^.. + H⁺, n[R?C₆H₄O]^.. → ?[R?C₆H₄O]^?_n.     

Aircraft classification with a low resolution infrared sensor

Existing computer simulations of aircraft infrared signature (IRS) do not account for dispersion induced by uncertainty on input parameters, such as aircraft aspect angles and meteorological conditions. As a result, they are of little use to quantify the detection performance of IR optronic systems: in this case, the scenario encompasses a lot of possible situations that must indeed be considered, but cannot be individually simulated. In this paper, we focus on low resolution infrared sensors and we propose a methodological approach for predicting simulated IRS dispersion of an aircraft, and performing a classification of different aircraft on the resulting set of low resolution infrared images. It is based on a quasi-Monte Carlo survey of the code output dispersion, and on a maximum likelihood classification taking advantage of Bayesian dense deformable template models estimation. This method is illustrated in a typical scenario, i.e., a daylight air-to-ground full-frontal attack by a generic combat aircraft flying at low altitude, over a database of 30,000 simulated aircraft images. Assuming a spatially white noise background model, classification performance is very promising, and appears to be more accurate than more classical state of the art techniques (such as kernel-based support vector classifiers).     

A Self-Controlled Synchronous Motor Drive using Terminal Voltage System

A current-fed self-controlled synchronous motor drive is described, in which the motor terminal voltage is used to synchronize the inverter triggering pulses. Power-factor optimization control strategy is studied, and its implementation in a microprocessor-based control system is described. Analysis of the z-domain using linearized models for system components is presented. Experimental results are given.