Theoretical and experimental analyses of rheological,compatibility and mechanical properties of PVMQ/XNBR-g GMA/XNBR/GO ternary hybrid nanocomposites

Iranian Polymer Journal - Effects of graphene oxide (GO) on various properties of rubber hybrid nanocomposites based on PVMQ/XNBR-g-GMA/XNBR (phenyl-vinyl-methyl-polysiloxane/carboxylated nitrile...     

Tensile behavior change depending on the varying tungsten content of W–Ni–Fe alloys

Tungsten heavy alloys (WHAs) are metal–metal composites consisting of nearly pure spherical tungsten particles embedded in a Ni–Fe–W or Ni–Co–W or Ni–Cu–W ductile matrix. In this dual phase alloy, there are several complicated relations between the ductile matrix and hard tungsten particles. The aim of this research was to examine the effect of varying tungsten content on the microstructure and mechanical properties of tungsten heavy alloys. The microstructural parameters (grain size, connectivity, contiguity and solid volume fraction) were measured and were found to have a significant effect on the mechanical properties of tungsten-based heavy alloys. The result shows that the binding strength between the W and the matrix phase has a major influence on the ductility of tungsten-based alloys. The larger this binding force is, the better the ductility is.     

Carbon nanotube based miniaturized electron gun and column assembly

We report on the application of silicon micromachining for the fabrication of miniaturized electron gun (MEG) assembly using vertically aligned carbon nanotubes. The proposed MEG consists of two main parts of electron gun and the accelerating column. While the electron gun consists of carbon nanotubes grown on a silicon substrate acting as an electron emission source, the accelerating column is made of micromachined silicon wafers with 5 μm thick membranes operating as objective lenses. These two wafers are placed together and sealed using a three-dimensional packaging technique. The simulation and experimental results show the evolution of a narrow electron beam by applying a proper voltage to the anodes and objective lens. The diverging and focusing of the beam can be controlled by applying the proper voltage on electrostatic lenses. This structure could be suitable for low energy SEM devices and surface physics applications.     

Estimation of the critical properties of compounds using volume-based thermodynamics

The importance, yet scarcity of the critical constants of thermally unstable fluids warrants the development of reliable methods for the estimation of these essential thermodynamic properties. A thorough investigation undertaken in this study on 1,589 compounds belonging to 83 chemical classes, indicated that the ratio of critical temperature to critical pressure of both low and high molecular weight compounds could be well expressed in terms of their volumetric properties. In addition, two new methodologies are presented for estimating V_c, as well as an indirect approach for prediction of T_c from surface tension data, altogether allowing the calculation of Z_c. Moreover, comparative studies are made with five group contribution methods. It is also demonstrated that by employing the Peng-Robinson EOS, and without prior knowledge of the critical properties, it is possible to calculate various thermophysical properties including P^sat., T_b, , ∆H^vap. , C_p, and even the T_c and P_c themselves.     

The synthesis of nano-sized ZSM-5 zeolite by dry gel conversion method and investigating the effects of experimental parameters by Taguchi experimental design

In this study ZSM-5 Nano particles with high crystallinity were synthesized using a dry gel conversion technique. An L9 orthogonal array of the Taguchi method was applied to investigate the effect of synthesis parameters, such as crystallization time, gel drying temperature, molar composition of template (TPAOH) and water content in the crystallization stage on crystallinity and particle size of the ZSM-5 catalyst. The products were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Beside short crystallization time, the particle sizes were considerably smaller in comparison with those prepared using the hydrothermal method. The results showed that the particle size and crystallinity increased with increasing water content and crystallization time. The effects of gel drying temperature and molar composition of template were found to be more complex, however. Comparing to hydrothermal method, ZSM-5 samples synthesized with the dry gel conversion exhibited higher selectivity to gasoline than other hydrocarbons.     

High strain electromechanical actuators based on electrodeposited polypyrrole doped with di-(2-ethylhexyl)sulfosuccinate

The low-voltage electromechanical actuation of polypyrrole (PPy) doped with di-(2-ethylhexyl)sulfosuccinate (DEHS) has been investigated. The PPy-DEHS has been prepared both chemically (cast as films from solution) and by more conventional electrochemical polymerization. Very large strains of ∼30% were obtained during slow-scan redox cycling of the electrochemically prepared PPy-DEHS films. In constrast, PPy-DEHS films cast from solutions of the chemically polymerized polymer gave actuation strains of ∼2.5%. The polymerization method was also found to have a significant effect on the structure, conductivity and mechanical properties of the PPy-DEHS materials. The conductivity of the electrochemically polymerized PPy-DEHS was 75 S cm⁻¹, considerably higher than that found for the chemically derived polymer (7 S cm⁻¹). The structure of the PPy-DEHS was further elucidated from UV-vis, Raman and FT-IR spectral studies which indicated that the conjugation length of the PPy could be increased significantly by varying the polymerization method. Films obtained by casting chemically prepared PPy-DEHS showed higher modulus (2.3 GPa) than electropolymerized PPy-DEHS (0.6 GPa), but were more brittle. Both materials were electroactive in acetonitrile/water electrolyte. The higher actuation strain observed in the electrochemically prepared films was attributed to a more open molecular structure (as indicated by the lower modulus) allowing for easier ion diffusion and a higher conductivity allowing easier charge transfer.     

An adaptive learning automata-based ranking function discovery algorithm

Due to the massive amount of heterogeneous information on the web, insufficient and vague user queries, and use of the same query by different users for different aims, the information retrieval process deals with a huge amount of uncertainty and doubt. Under such circumstances, designing an efficient retrieval function and ranking algorithm by which the most relevant results are provided is of the greatest importance. In this paper, a learning automata-based ranking function discovery algorithm in which different sources of information are combined is proposed. In this method, the learning automaton is used to adjust the portion of the final ranking that is assigned to each source of evidence based on the user feedback. All sources of information are first given the same importance. The proportion of a given source increases, if the documents provided by this source are reviewed by the user and decreases otherwise. As the proposed algorithm proceeds, the probability of appearance of each source in the final ranking gets proportional to its relevance to the user queries. Several simulation experiments are conducted on well-known data collections and query types to show the performance of the proposed algorithm. The obtained results demonstrate that the proposed algorithm outperforms several existing methods in terms of precision at position n, mean average precision, and normalized discount cumulative gain.     

Transmission pricing and recovery of investment costs in the deregulated power system based on optimal circuit prices

Transmission pricing has become a major issue in the discussions about the deregulated electricity markets.Consequently,open access to the transmission system is one of the basic topics to allow competition among participants in the energy market.Transmission costs have an important impact on relative competition among participants in the energy market as well as on short-and long-term economic efficiencies of the whole electricity industry,although they represent only close to 10% of the energy market price.This paper deals with the design and tests of a transmission pricing method based on the optimal circuit prices derived from the economically adapted network(EAN).Prices derived from the EAN have the advantage of being in tune with the maximum revenue allowed to the owner of transmission assets and simplifying the optimal allocation of transmission costs among participants.Beginning from the conceptual design,the proposed method is tested on a three-bus network and on the IEEE 24-bus reliability test system.     

A new rateless code with unequal error protection property

In our previous work, “robust transmission of scalable video stream using modified LT codes”, an LT code with unequal packet protection property was proposed. It was seen that applying the proposed code to any importance-sorted input data, could increase the probability of early decoding of the most important parts when enough number of encoded symbols is available at the decoder’s side. In this work, the performance of the proposed method is assessed in general case for a wide range of loss rate, even when there are not enough encoded symbols at the decoder’s side. Also in this work the degree distribution of input nodes is investigated in more detail. It is illustrated that sorting input nodes in encoding graph, as what we have done in our work, has superior advantage in comparison with unequal input node selection method that is used in traditional rateless code with unequal error protection property.