全文获取类型
收费全文 | 864篇 |
免费 | 25篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 20篇 |
化学工业 | 204篇 |
金属工艺 | 26篇 |
机械仪表 | 11篇 |
建筑科学 | 31篇 |
能源动力 | 45篇 |
轻工业 | 83篇 |
水利工程 | 1篇 |
石油天然气 | 1篇 |
武器工业 | 1篇 |
无线电 | 48篇 |
一般工业技术 | 164篇 |
冶金工业 | 179篇 |
原子能技术 | 15篇 |
自动化技术 | 61篇 |
出版年
2023年 | 7篇 |
2022年 | 10篇 |
2021年 | 16篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 22篇 |
2017年 | 14篇 |
2016年 | 13篇 |
2015年 | 10篇 |
2014年 | 20篇 |
2013年 | 56篇 |
2012年 | 34篇 |
2011年 | 43篇 |
2010年 | 32篇 |
2009年 | 35篇 |
2008年 | 23篇 |
2007年 | 21篇 |
2006年 | 35篇 |
2005年 | 23篇 |
2004年 | 32篇 |
2003年 | 32篇 |
2002年 | 25篇 |
2001年 | 13篇 |
2000年 | 13篇 |
1999年 | 20篇 |
1998年 | 36篇 |
1997年 | 25篇 |
1996年 | 23篇 |
1995年 | 19篇 |
1994年 | 17篇 |
1993年 | 20篇 |
1992年 | 11篇 |
1991年 | 9篇 |
1990年 | 10篇 |
1989年 | 18篇 |
1988年 | 13篇 |
1987年 | 8篇 |
1986年 | 11篇 |
1985年 | 8篇 |
1984年 | 7篇 |
1983年 | 7篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 7篇 |
1979年 | 7篇 |
1977年 | 9篇 |
1976年 | 10篇 |
1974年 | 10篇 |
1972年 | 5篇 |
1969年 | 5篇 |
排序方式: 共有890条查询结果,搜索用时 15 毫秒
1.
2.
As a model for organic ferromagnetism in a one-dimensional system, substituted polyacetylenes are re-considered on the basis of the molecular orbital (MO) and the crystal orbital (CO) methods. The semiempirical MO calculations with configuration interaction for the dimer model show that the exchange interaction on poly[(4-oxyphenyl)acetylene] (1) is negative in spite of Ovchinnikov's prediction, due to the direct interaction between the adjacent pendant spins. On the other hand, it is shown that a polyacetylene chain with phenoxy radicals as pendants on every other active site can become a one-dimensional feromagnet. Moreover, the CO calculations by means of the unrestricted Hartree-Fock method give a theoretical background for the realization of a ground state with macroscopic spin alignment on the improved model chain. 相似文献
3.
We study theoretically the effect of the quasiparticle scattering in field-induced spin density waves (FISDW) in Bechgaard salts in a high magnetic field. The effects of scattering are introduced by a random impurity model similar to the one used by Zittartz in his analysis of the charge density wave. Within the single-gap approximation and weak impurity scattering, we find that the FISDW with normal impurities is similar to a superconductor with magnetic impurities. From this analogy the thermodynamics as well as the electronic thermal conductivity and the sound attenuation coefficient of the FISDW are obtained.On leave of absence from Nankai University, China. 相似文献
4.
It has been previously reported that Bryostatin 1 (Bryo1) induces differentiation of the human acute lymphoblastic leukemia (ALL) cell line, Reh, to a monocytoid B-cell stage. In this study we demonstrate that a novel protein, ubiquitin COOH-terminal hydrolase (UCH-L1), is associated with this differentiation. Reh cells were treated with 200 nmol/l of Bryo1 for 72 h and analyzed for changes in morphology, surface immunophenotype, acid phosphatase and terminal deoxynucleotidyl transferase. Protein patterns of the parent and differentiated cells, by two-dimensional polyacrylamide gel electrophoresis (2D PAGE), were studied. Bryo1-treated cells expressed morphologic, phenotypic and enzymatic features of the monocytoid B-cell stage. The UCH-L1 enzyme (MW-pl 34-5.3) was detected by 2 D PAGE in the differentiated, but not in parent cells. The presence of UCH-L1 in the Bryo1-treated cells was further confirmed by immunoblotting of 2 D PAGE using UCH-L1 polyclonal antibody. Ubiquitin expression was studied in parent and Bryo1-treated cells and was compared with 12-O-tetradecanoylphorbol-13-acetate (TPA)-treated cells. Both agents, TPA and Bryo1, increased the level of ubiquitin expression as detected by flow cytometry. Sodium borohydride, an inhibitor of UCH-L1, inhibited the Bryo1-induced differentiating effect on Reh cells. To date, the mechanism by which Bryo1, exerts its B-cell differentiating effect is not fully understood. This study shows that UCH-L1 expression may play a major role in Bryo1-induced differentiation in pre-B-ALL. 相似文献
5.
Tachikawa M. Evenson K.M. Zink L.R. Maki A.G. 《Quantum Electronics, IEEE Journal of》1996,32(10):1732-1736
We have measured frequencies of N2O transitions by heterodyning sub-Doppler fluorescence-stabilized N2O laser radiation with that from a reference CO2 laser. A high-resolution cavity incorporates a ribbed tube and a highly reflective grating, permitting the CW oscillation of both the 100 0-0200 9-μm and the 1000-0001 10-μm regular bands. This is the first sub-Doppler frequency measurement of the 9-μm band. The accuracy in the determination of the rotational constants for both bands has been improved by an order of magnitude, and calculated transition frequencies are presented 相似文献
6.
Fuminori Tanihara Maki Hirata Nhien Thi Nguyen Osamu Sawamoto Takeshi Kikuchi Takeshige Otoi 《International journal of molecular sciences》2021,22(5)
Xenoantigens cause hyperacute rejection and limit the success of interspecific xenografts. Therefore, genes involved in xenoantigen biosynthesis, such as GGTA1, CMAH, and B4GALNT2, are key targets to improve the outcomes of xenotransplantation. In this study, we introduced a CRISPR/Cas9 system simultaneously targeting GGTA1, CMAH, and B4GALNT2 into in vitro-fertilized zygotes using electroporation for the one-step generation of multiple gene-edited pigs without xenoantigens. First, we optimized the combination of guide RNAs (gRNAs) targeting GGTA1 and CMAH with respect to gene editing efficiency in zygotes, and transferred electroporated embryos with the optimized gRNAs and Cas9 into recipient gilts. Next, we optimized the Cas9 protein concentration with respect to the gene editing efficiency when GGTA1, CMAH, and B4GALNT2 were targeted simultaneously, and generated gene-edited pigs using the optimized conditions. We achieved the one-step generation of GGTA1/CMAH double-edited pigs and GGTA1/CMAH/B4GALNT2 triple-edited pigs. Immunohistological analyses demonstrated the downregulation of xenoantigens; however, these multiple gene-edited pigs were genetic mosaics that failed to knock out some xenoantigens. Although mosaicism should be resolved, the electroporation technique could become a primary method for the one-step generation of multiple gene modifications in pigs aimed at improving pig-to-human xenotransplantation. 相似文献
7.
The polymorphism of Ca3SiO5 has been studied microscopically by following changes in optic properties and modes of twinning of the crystal as a function of temperature. Besides the six modifications already established, a hitherto-unidentified monoclinic phase M3, which can be characterized only by microscopy at present, has been found to exist just below the rhombohedral phase (R). The transitions that give clear thermal effects on the DTA curve show no corresponding change under the microscope. 相似文献
8.
The redistribution of impurity in alite during recrystallization has been confirmed by means of the electron probe microanalysis. Each of the main impurity components shows a significant decrease in content during recrystallization. This demonstrates that the growth velocity of alite exerts influence on the amount of the impurity taken up in alite in solid solution from the interstitial melt. Whether M3 or M1 occurs at ambient temperature depends on the cooling rate of clinker as well as the chemical composition of alite. 相似文献
9.
Eiichi Hoshino Kazunari Maruta Yasunao Wada Kazuo Mori 《Journal of the American Oil Chemists' Society》1995,72(7):785-791
The interaction of highly purified alkaline protease fromBacillus sp. KSM-K16 with the horny cells of human skin contained in skin grime was directly visualized by electron microscopy. It
became clear that the protease first penetrates the horny cells and then adsorbs, mainly onto the internal structure of the
cells at the initial stage of hydrolysis, and directly hydrolyzes the keratin filaments, though the marginal band surrounding
them retains its original shape. Then, hydrolysate produced from the keratin filaments flows out of the cell, and early in
the hydrolysis process keratin filaments decrease and then disappear, leaving a marginal band, i.e., the cell turns to a hollow
state. As a result, the remaining marginal band loses support from inside the cell, thus promoting cleavage and dispersion.
Until this stage in the protease reaction, the remarkable liberation of hydrolysis products as water-soluble protein does
not occur. 相似文献
10.
Maki Itoh Toshimitsu Suzuki Yoshihiko Tsujimoto Ken-ichi Yoshii Yoshinobu Takegami Yoshihisa Watanabe 《Fuel》1983,62(1):98-102
Thermal cracking of tar-sand bitumens has been carried out using a two-stage pyrolysis reactor with temperature zones of 440°C and 750–800°C, respectively. Feedstocks were pyrolysed in the first stage into cracked oils, which were carried to the second stage for subsequent pyrolysis. Only 12–14 wt% of ethylene was obtained from tar-sand bitumens at the residence time of 1.2 s in the second stage, although 27 and 16 wt% were obtained from Taching and Iranian heavy vacuum residues, respectively. The tar-sand bitumens contain shorter paraffinic straight-chains and have more branched molecules than the vacuum residues of petroleum. A straight-chain paraffin index is proposed, with which a good correlation was obtained between ethylene yield and the fraction of straight-chain paraffin carbons in the heavy oil. 相似文献