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Ultra‐thin fibers, consisting of blends of a PPE derivative and polystyrene, with average diameters ranging from 430 to 1 200 nm, were produced by electrospinning. The electrospinnability was significantly improved by adding pyridinium formate to the spinning solution. FT‐IR spectroscopy was used to confirm the composition of the electrospun fibers and their morphology was probed by SEM. The optical properties of the as‐prepared solutions, pristine and annealed fibers, and corresponding spin‐coated and solution‐cast films were investigated by UV‐vis spectroscopy. A comparison of the PL emission spectra revealed aggregation of PPE molecules in the electrospun materials but the extent of aggregation can be reduced if the materials are annealed above the glass transition temperature.
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Napatporn Promsawat Wannasiri Wichaiwong Prawpraewa Pimpawat Khwanruedee Changsarn Kantapon Phimol Methee Promsawat 《Integrated ferroelectrics》2019,195(1):220-229
AbstractFlexible technology has recently received much attention in the field of flexible sensors, wearable electronic devices, flexible transparent displays, and energy harvesters. Zinc oxide (ZnO) thin film is the preferred material for use in flexible devices due to its environmental friendliness, high electrical performance and low synthesis temperature. In addition, ZnO possesses a non-centrosymmetric crystal structure, causing a piezoelectric effect in the material. This work presents the fabrication of flexible piezoelectric generators using the deposition of ZnO on a PET substrate using sputtering techniques. The fabricated flexible generators are capable of generating an output power of 14 µW through an optimal resistive load of 750 kΩ. An output voltage of 2.00 Vp and a current of 150 μA measured across a 750 kΩ resistor were subsequently obtained. 相似文献
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