Properties of poly(ethylene terephthalate)–poly(ethylene naphthalene 2,6‐dicarboxylate) blends with montmorillonite clay

The production and properties of blends of poly(ethylene terephthalate) (PET) and poly(ethylene naphthalene 2,6‐dicarboxylate) (PEN) with three modified clays are reported. Octadecylammonium chloride and maleic anhydride (MAH) are used to modify the surface of the montmorillonite–Na⁺ clay particles (clay–Na⁺) to produce clay–C18 and clay–MAH, respectively, before they are mixed with the PET/PEN system. The transesterification degree, hydrophobicity and the effect of the clays on the mechanical, rheological and thermal properties are analysed. The PET–PEN/clay–C18 system does not show any improvements in the mechanical properties, which is attributed to poor exfoliation. On the other hand, in the PET–PEN/clay–MAH blends, the modified clay restricts crystallization of the matrix, as evidenced in the low value of the crystallization enthalpy. The process‐induced PET–PEN transesterification reaction is affected by the clay particles. Clay–C18 induces the largest proportion of naphthalate–ethylene–terephthalate (NET) blocks, as opposed to clay–Na⁺ which renders the lowest proportion. The clay readily incorporates in the bulk polymer, but receding contact‐angle measurements reveal a small influence of the particles on the surface properties of the sample. The clay–Na⁺ blend shows a predominant solid‐like behaviour, as evidenced by the magnitude of the storage modulus in the low‐frequency range, which reflects a high entanglement density and a substantial degree of polymer–particle interactions. Copyright © 2005 Society of Chemical Industry     

Impact of the addition of an enzyme pool on an activated sludge system treating dairy wastewater under fat shock loads

BACKGROUND: The application of lipase‐rich enzyme pools (such as the crude solid enzymatic preparation (SEP) obtained from Penicillium restrictum solid‐state fermentation of agro‐industrial wastes) to activated sludge systems may be an effective strategy for preventing various operational problems. The continuous addition of SEP to the treatment system can become cost‐prohibitive when in situ production and/or storage are factored in. The application of SEP to high‐fat wastewater treatment would only be justified as an emergency measure, such as a sudden increase in the fat content of the bioreactor influent. Therefore, the primary objective of this work was to investigate the efficiency of a crude SEP during fat shock loads, simulated through the periodic addition of dairy industry waste containing high fat concentrations to the feed stock of an activated sludge system, operated in continuous mode. RESULTS: The test bioreactor exhibited a higher average chemical oxygen demand (COD) removal efficiency than the control bioreactor (83% for control and 90% for test) and the fat accumulation in the biological flocs of the test bioreactor was 3.2 times lower than that in the control bioreactor. Turbidity was also lower in the effluent of the test bioreactor (123 and 66 FTU in control and test, respectively) and it had a shorter recovery time between shock loads, especially when the interval between loads was shorter than one month (biweekly and weekly shock loads). CONCLUSION: The addition of SEP during fat overloads in the reactor feed maintained efficient COD removal in the test bioreactor for 270 days without any operational problems. Copyright © 2008 Society of Chemical Industry     

On the decoding of binary cyclic codes with the Newton identities

We revisit in this paper the concept of decoding binary cyclic codes with Gröbner bases. These ideas were first introduced by Cooper, then Chen, Reed, Helleseth and Truong, and eventually by Orsini and Sala. We discuss here another way of putting the decoding problem into equations: the Newton identities. Although these identities have been extensively used for decoding, the work was done manually, to provide formulas for the coefficients of the locator polynomial. This was achieved by Reed, Chen, Truong and others in a long series of papers, for decoding quadratic residue codes, on a case-by-case basis. It is tempting to automate these computations, using elimination theory and Gröbner bases.Thus, we study in this paper the properties of the system defined by the Newton identities, for decoding binary cyclic codes. This is done in two steps, first we prove some facts about the variety associated with this system, then we prove that the ideal itself contains relevant equations for decoding, which lead to formulas.Then we consider the so-called online Gröbner basis decoding, where the work of computing a Gröbner basis is done for each received word. It is much more efficient for practical purposes than preprocessing and substituting into the formulas. Finally, we conclude with some computational results, for codes of interesting length (about one hundred).     

Benchmarking Image Segmentation Algorithms

We present a thorough quantitative evaluation of four image segmentation algorithms on images from the Berkeley Segmentation Database. The algorithms are evaluated using an efficient algorithm for computing precision and recall with regard to human ground-truth boundaries. We test each segmentation method over a representative set of input parameters, and present tuning curves that fully characterize algorithm performance over the complete image database. We complement the evaluation on the BSD with segmentation results on synthetic images. The results reported here provide a useful benchmark for current and future research efforts in image segmentation.     

A method of stepwise benchmarking for inefficient DMUs based on the proximity-based target selection

DEA is a useful nonparametric method of measuring the relative efficiency of a DMU and yielding a reference target for an inefficient DMU. However, it is very difficult for inefficient DMUs to be efficient by benchmarking a target DMU which has different input use. Identifying appropriate benchmarks based on the similarity of input endowment makes it easier for an inefficient DMU to imitate its target DMUs. But it is rare to find out a target DMU, which is both the most efficient and similar in input endowments, in real situation. Therefore, it is necessary to provide an optimal path to the most efficient DMU on the frontier through several times of a proximity-based target selection process. We propose a dynamic method of stepwise benchmarking for inefficient DMUs to improve their efficiency gradually.The empirical study is conducted to compare the performance between the proposed method and the prior methods with a dataset collected from Canadian Bank branches. The comparison result shows that the proposed method is very practical to obtain a gradual improvement for inefficient DMUs while it assures to reach frontier eventually.     

Incorporating technology in service-oriented i* business models: a case study

In recent years, considerable attention has been paid to enterprise information systems. This interest is motivated by the need for achieving better integration of new technologies (hardware and software) with the business processes of an organization. Business processes have become more and more dependent on technologies because technology has a direct impact on business processes, changing the way they are performed and thus also affecting the way analysts design the software system. However, at the present time, there are still some gaps between the definition of business processes and the technologies used in the organization. In practice, organizations have carried out their business processes using different technologies; however, it is sometimes not possible to determine how technologies are useful in achieving current business goals. This is because business models do not explicitly consider the technologies in the organizational requirements. The goal of this paper is to present a systematic process for integrating business processes and technologies at the conceptual level. To validate our approach, we present a case study that describes the processes of the inventory management department of a public research center.     

Effect of diacetyl piquerol on H+-ATPase activity of microsomes fromIpomoea purpurea

The effect of an allelopathic compound, diacetyl-piquerol on the H⁺ -ATPase activity of the microsomal fraction from the radicles of a common weedIpomoea purpurea was studied. The diacetyl-piquerol inhibited the germination and radicle growth fromI. purpurea; the radicle growth was increasingly inhibited (10% to 100%) as piquerol concentrations were raised (10 M to 1000 M). The H⁺-ATPase activity was inhibited (48%) by 500 M diacetyl-piquerol, and this inhibition was higher in plasma membrane ATPase (67.2%) than in tonoplast membrane ATPase (31.4%). Additional studies of the precise physiological mechanisms of interference caused by allelopathic compounds are needed.This study was sponsored by Project PCECCCNA-050954 of Consejo Nacional de Ciencia y Tecnología (CONACyT).     

Wafer-level fabrication process for fully encapsulated micro-supercapacitors with high specific energy

In this paper a wafer-level process is proposed to fully integrate carbon-based micro-supercapacitor onto silicon substrate. This process relies on the deposition of a paste containing carbon, PVDF and acetone into cavities etched in silicon. After electrolyte deposition in a controlled atmosphere, a wafer-level encapsulation is realized. Cyclic voltammetry performed on non-encapsulated micro-components showed specific energy of 257 mJ cm⁻² for 336 μm deep cavities. The specific encapsulation process developed was tested separately and proved to be efficient in terms of resistance to organic electrolytes and mechanical strength.     

Advances in Human Mitochondria-Based Therapies

Mitochondria are the key biological generators of eukaryotic cells, controlling the energy supply while providing many important biosynthetic intermediates. Mitochondria act as a dynamic, functionally and structurally interconnected network hub closely integrated with other cellular compartments via biomembrane systems, transmitting biological information by shuttling between cells and tissues. Defects and dysregulation of mitochondrial functions are critically involved in pathological mechanisms contributing to aging, cancer, inflammation, neurodegenerative diseases, and other severe human diseases. Mediating and rejuvenating the mitochondria may therefore be of significant benefit to prevent, reverse, and even treat such pathological conditions in patients. The goal of this review is to present the most advanced strategies using mitochondria to manage such disorders and to further explore innovative approaches in the field of human mitochondria-based therapies.     

Visual Analysis of protein‐ligand interactions

The analysis of protein‐ligand interactions is complex because of the many factors at play. Most current methods for visual analysis provide this information in the form of simple 2D plots, which, besides being quite space hungry, often encode a low number of different properties. In this paper we present a system for compact 2D visualization of molecular simulations. It purposely omits most spatial information and presents physical information associated to single molecular components and their pairwise interactions through a set of 2D InfoVis tools with coordinated views, suitable interaction, and focus+context techniques to analyze large amounts of data. The system provides a wide range of motifs for elements such as protein secondary structures or hydrogen bond networks, and a set of tools for their interactive inspection, both for a single simulation and for comparing two different simulations. As a result, the analysis of protein‐ligand interactions of Molecular Simulation trajectories is greatly facilitated.