全文获取类型
收费全文 | 2865篇 |
免费 | 88篇 |
国内免费 | 7篇 |
专业分类
电工技术 | 172篇 |
综合类 | 3篇 |
化学工业 | 827篇 |
金属工艺 | 99篇 |
机械仪表 | 70篇 |
建筑科学 | 68篇 |
能源动力 | 124篇 |
轻工业 | 251篇 |
水利工程 | 5篇 |
石油天然气 | 7篇 |
武器工业 | 2篇 |
无线电 | 224篇 |
一般工业技术 | 507篇 |
冶金工业 | 227篇 |
原子能技术 | 67篇 |
自动化技术 | 307篇 |
出版年
2023年 | 11篇 |
2022年 | 41篇 |
2021年 | 76篇 |
2020年 | 28篇 |
2019年 | 32篇 |
2018年 | 45篇 |
2017年 | 45篇 |
2016年 | 66篇 |
2015年 | 43篇 |
2014年 | 86篇 |
2013年 | 162篇 |
2012年 | 150篇 |
2011年 | 166篇 |
2010年 | 143篇 |
2009年 | 160篇 |
2008年 | 145篇 |
2007年 | 135篇 |
2006年 | 113篇 |
2005年 | 102篇 |
2004年 | 74篇 |
2003年 | 69篇 |
2002年 | 69篇 |
2001年 | 49篇 |
2000年 | 48篇 |
1999年 | 52篇 |
1998年 | 122篇 |
1997年 | 86篇 |
1996年 | 75篇 |
1995年 | 55篇 |
1994年 | 54篇 |
1993年 | 58篇 |
1992年 | 35篇 |
1991年 | 32篇 |
1990年 | 28篇 |
1989年 | 34篇 |
1988年 | 22篇 |
1987年 | 19篇 |
1986年 | 26篇 |
1985年 | 25篇 |
1984年 | 28篇 |
1983年 | 20篇 |
1982年 | 13篇 |
1981年 | 16篇 |
1980年 | 14篇 |
1979年 | 11篇 |
1977年 | 17篇 |
1976年 | 12篇 |
1975年 | 9篇 |
1974年 | 7篇 |
1973年 | 11篇 |
排序方式: 共有2960条查询结果,搜索用时 968 毫秒
1.
Makoto Yamaguchi 《应用聚合物科学杂志》2021,138(14):50172
Perfluorosulfonic acid ionomer membranes have been widely used as proton conducting membranes in various electrochemical processes such as polymer electrolyte fuel cells and water electrolysis. While their thermal stability has been studied by thermogravimetry and analysis of low molecular weight products, their decomposition mechanism is little understood. In this study a newly developed methodology of thermal desorption and pyrolysis in combination with direct analysis in real time mass spectrometry is applied for Nafion membrane. An ambient ionization source and a high-resolution time-of-flight mass spectrometer enabled unambiguous assignment of gaseous products. Thermal decomposition is initiated by side chain detachment above 350°C, which leaves carbonyls on the main chain at the locations of the side chains. Perfluoroalkanes are released above 400°C by main chain scission and their further decomposition products dominate above 500 °C. DFT calculation of reaction energies and barrier heights of model compounds support proposed decomposition reactions. 相似文献
2.
Abidur Rahman Makoto Kobayashi Kotaro Sugimoto Yuta Endo Manabu Kojima Shigenori Furukawa Takafumi Watanabe Shu Soeda Yuko Hashimoto Keiya Fujimori Hideki Chiba 《International journal of molecular sciences》2021,22(7)
Background: Within the claudin (CLDN) family, CLDN12 mRNA expression is altered in various types of cancer, but its clinicopathological relevance has yet to be established due to the absence of specific antibodies (Abs) with broad applications. Methods: We generated a monoclonal Ab (mAb) against human/mouse CLDN12 and verified its specificity. By performing immunohistochemical staining and semiquantification, we evaluated the relationship between CLDN12 expression and clinicopathological parameters in tissues from 138 cases of cervical cancer. Results: Western blot and immunohistochemical analyses revealed that the established mAb selectively recognized the CLDN12 protein. Twenty six of the 138 cases (18.8%) showed low CLDN12 expression, and the disease-specific survival (DSS) and recurrence-free survival rates were significantly decreased compared with those in the high CLDN12 expression group. We also demonstrated, via univariable and multivariable analyses, that the low CLDN12 expression represents a significant prognostic factor for the DSS of cervical cancer patients (HR 3.412, p = 0.002 and HR 2.615, p = 0.029, respectively). Conclusions: It can be concluded that a reduced CLDN12 expression predicts a poor outcome for cervical cancer. The novel anti-CLDN12 mAb could be a valuable tool to evaluate the biological relevance of the CLDN12 expression in diverse cancer types and other diseases. 相似文献
3.
Aniruddha Nag Mohammed Asif Ali Jiabei Zhou Makoto Ogawa Tatsuo Kaneko 《大分子材料与工程》2021,306(11):2100459
Aromatic and functional polymers with processibility derived from biobased starting materials are prerequisite considering sustainable society. Poly(2,5-benzimidazole)s are rigid-rod polymers to show ultrahigh thermal stability such as flame retardance, while usually suffer from poor solubility. Here, poly(benzimidazole-co-amide)s are synthesized from two biobased monomers, 3,4-diaminobenzoic acid and a semirigid comonomer, 4-aminohydrocinnamic acid. The copolymers with an amide composition of 80 mol% and higher are soluble in widely used polar solvents to fabricate the films keeping high flame retardance, which is comparable with popular high-performance polymers such as aromatic polyimides, polyetheretherketone, polyphenylene sulfide, etc. 相似文献
4.
Shouko Nishida Masaya Shibano Hiroshi Kamitakahara Toshiyuki Takano 《International journal of molecular sciences》2015,16(12):29093-29102
We recently observed that the decanoylation of N-phenylthiocarbamoyl chitosan (2) with a mixture of decanoic anhydride and pyridine at 60 °C for 24 h afforded N,N-(decanoyl)phenythiocarbamoyl-/2-isothiocynato chitosan decanoate (3b) rather than the expected product N,N-(decanoyl)phenylthiocarbamoyl chitosan decanoate (3a). This result suggested that some of the N,N-(decanoyl)phenylthiocarmbamoyl groups had been converted to isothiocyanate groups during the decanoylation process. The subsequent reaction of compound 3b with aniline gave N,N-(decanoyl)phenylthiocarbamoyl/N-phenylthiocarbamoyl chitosan decanoate (4) in high yield. A solution of compound 4 in CHCl3 was then added to a solution of copper decanoate (5) in the same solvent, and the resulting mixture was cast onto a glass plate to give a cast film. The film was annealed at 200 °C in an oven to give a greenish film, which showed good near-infrared absorption characteristic in the range of 800–2200 nm. 相似文献
5.
Ohsaki Makoto Fujiwara Jun Takeda Fumiyoshi 《International Journal of Mechanics and Materials in Design》2020,16(4):883-896
International Journal of Mechanics and Materials in Design - A simple iterative method is presented for cutting pattern optimization of frame-supported and pneumatic membrane structures for... 相似文献
6.
7.
N Okada S Sato T Sasou M Aoyama K Nishida K Yoshikawa 《Canadian Metallurgical Quarterly》1993,129(4):403-407
Ambiguous abdominal situs, asplenia/polysplenia and severe cardiac malformations characterize heterotaxy in humans. These anomalies result from the inability of the developing embryo to establish normal left-right asymmetry. We have studied an interesting family in which the heterotaxy phenotype segregates as an X-linked recessive trait. In order to map the heterotaxy locus (HTX), we have analysed 39 family members using highly-polymorphic microsatellite markers from the X chromosome. One of these markers, DXS994, shows no recombination with the disease locus in 20 informative meioses. Linkage analysis results in a maximum lod score of 6.37. Current genetic and physical mapping data assign the order of loci in Xq24-q27.1 as cen-DXS1001-(DXS994, HTX)-DXS984-tel. These results establish the first mapping assignment of situs abnormalities in humans. 相似文献
8.
We present simulation results of the vortex dynamics in a trapped Bose-Einstein condensate in the presence of a rotating optical
lattice. Changing the potential amplitude and the relative rotation frequency between the condensate and the optical lattice,
we find a rich variety of dynamical phases of vortices. In particular, when the optical lattice rotates faster than the condensate,
the competition between the pinning force and the interactions by nucleated interstitial vortices leads to the melting of
vortex lattice, yielding a vortex liquid phase. 相似文献
9.
Y Nishida T Fujimoto A Takagi I Honjo K Ogawa 《Canadian Metallurgical Quarterly》1993,65(1-2):274-280
Localization of fodrin, a membrane skeletal protein, in the outer hair cell of the guinea pig cochlea was examined by immunocytochemical techniques. By immunofluorescence microscopy, fodrin was observed in the cuticular plate, in the infracuticular network and along the lateral wall. By immunoelectron microscopy of ultrathin cryosections, labeling for fodrin along the lateral wall was localized between the cell membrane and the outermost layer of the subsurface cisternae. Furthermore, pre-embedding immunoelectron microscopy of permeabilized specimens showed that most immunogolds for fodrin were on the thin cross-linking component of the cortical lattice. The results indicate that fodrin is a constituent of the cortical lattice which is thought to play an important role in outer hair cell motility. 相似文献
10.