Efficient Telomerization of Butadiene with Starch in Water: The Role of the Surfactant

The synthesis of hydrophobic starch was performed via palladium-catalyzed telomerization of butadiene with native starch. This reaction is efficiently performed in water in the presence of neutral or cationic surfactant with high HLB. After optimization of the reaction conditions, TOF up to 446 was achieved.     

Ferromagnetic inserts for magnetic force field generation

We present a new way of creating a magnetic force field by using ferromagnetic inserts inside a superconducting solenoidal coil. By means of a purely analytical calculation, we describe the configuration of the ferromagnetic inserts and the force field they create. We demonstrate the relevance of the structure both by numerical computation and by experimentation with a prototype.     

A magnet system design for reduced gravity environment

Simulating a reduced gravity environment experienced in spaceships in a laboratory setting for studying different technical aspects (fluid transfer or propellant behavior, for example) is a primordial step prior to extraterrestrial explorations. We first present some results on boiling heat transfer in helium under reduced gravity using a commercial magnet and point out the limitations in volume and magnetic force homogeneity to perform reduced gravity experiments with such a non ad hoc magnet. Then, we present a new magnetic design to create a reduced gravity environment in large volume suitable for boiling test experiments in oxygen. Based on a modified design we present the magnetic configurations that allow compensating gravity for different elements such as hydrogen, water or helium but in smaller volumes. We detail the different aspects of winding techniques to achieve the requirements on magnetic force.     

Commissioning of the Iseult CEA 11.7 T whole-body MRI: current status,gradient–magnet interaction tests and first imaging experience

Objectives

The Iseult MRI is an actively shielded whole-body magnet providing a homogeneous and stable magnetic field of 11.7 T. After nearly 20 years of research and development, the magnet successfully reached its target field strength for the first time in 2019. This article reviews its commissioning status, the gradient–magnet interaction test results and first imaging experience.

Materials and methods

Vibration, acoustics, power deposition in the He bath, and field monitoring measurements were carried out. Magnet safety system was tested against outer magnetic perturbations, and calibrated to define a safe operation of the gradient coil. First measurements using parallel transmission were also performed on an ex-vivo brain to mitigate the RF field inhomogeneity effect.

Results

Acoustics measurements show promising results with sound pressure levels slightly above the enforced limits only at certain frequency intervals. Vibrations of the gradient coil revealed a linear trend with the B₀ field only in the worst case. Field monitoring revealed some resonances at some frequencies that are still under investigation.

Discussion

Gradient-magnet interaction tests at up to 11.7 T are concluded. The scanner is now kept permanently at field and the final calibrations are on-going to pave the road towards the first acquisitions on volunteers.