Incoherent transport in NEMO5: realistic and efficient scattering on phonons

In this work, the coherent and incoherent transport simulation capabilities of the multipurpose nanodevice simulation tool NEMO5 are presented and applied on transport in tunneling field-effect transistors. The comparison with experimental resistivity data confirms the validity of NEMO5’s phonon-scattering models. Common pitfalls of numerical implementations and the applicability of common approximations of scattering self-energies are discussed. The impact of phonon-assisted tunneling on the performance of TFETs is exemplified with a concrete Si nanowire device. The communication-efficient implementation of self-energies in NEMO5 is demonstrated with a scaling comparison of self-energies solved with blocking and nonblocking MPI-communication.     

On the quality of VoIP with DCCP for satellite communications

We present experimental results for the performance of selected voice codecs using Datagram Congestion Control Protocol (DCCP) with CCID4 congestion control over a satellite link. We evaluate the performance of both constant and variable data rate speech codecs for a number of simultaneous calls using the ITU E‐model. We analyse the sources of packet losses and additionally analyse the effect of jitter, which is one of the crucial parameters contributing to Voice over IP (VoIP) quality and has, to the best of our knowledge, not been considered previously in the published DCCP performance results. We propose modifications to the CCID4 algorithm and demonstrate how these improve the VoIP performance, without the need for additional link information other than what is already monitored by CCID4. We also demonstrate the fairness of the proposed modifications to other flows. Although the recently adopted changes to TCP‐Friendly Rate Control specification alleviate some of the performance issues for VoIP on satellite links, we argue that the characteristics of commercial satellite links necessitate consideration of further improvements. We identify the additional benefit of DCCP when used in VoIP admission control mechanisms and draw conclusions about the advantages and disadvantages of the proposed DCCP/CCID4 congestion control mechanism for use with VoIP applications. Copyright © 2012 John Wiley & Sons, Ltd.     

Scalable Nanowire Photonic Crystals: Molding the Light Emission of InGaN

To date, there have been no efficient semiconductor light emitters operating in the green and amber wavelengths. This study reports on the synthesis of InGaN nanowire photonic crystals, including dot‐in‐nanowires, nanotriangles, and nanorectangles with precisely controlled size, spacing, and morphology, and further demonstrates that bottom‐up InGaN photonic crystals can exhibit highly efficient and stable emission. The formation of stable and scalable band edge modes in defect‐free InGaN nanowire photonic crystals is directly measured by cathodoluminescence studies. The luminescence emission, in terms of both the peak position (λ ≈ 505 nm) and spectral linewidths (full‐width‐half‐maximum ≈ 12 nm), remains virtually invariant in the temperature range of 5–300 K and under excitation densities of 29 W cm^?2 to 17.5 kW cm^?2. To the best of our knowledge, this is the first demonstration of the absence of Varshni and quantum‐confined Stark effects in wurtzite InGaN light emitters—factors that contribute significantly to the efficiency droop and device instability under high‐power operation. Such distinct emission properties of InGaN photonic crystals stem directly from the strong Purcell effect, due to efficient coupling of the spontaneous emission to the highly stable and scalable band‐edge modes of InGaN photonic crystals, and are ideally suited for uncooled, high‐efficiency light‐emitting‐diode operation.     

Changes in properties of tar obtained during underground coal gasification process

In this study,the composition of tars collected during a six-day underground coal gasification (UCG) test at the experimental mine 'Barbara'in Poland in 2013 wa...     

Plasmonic photothermal therapy of colon cancer cells utilising gold nanoshells: an in vitro study

In this study, gold nanoshell (GNS) were synthesised utilising the Halas method. The obtained nanoparticles (NPs) were characterised by Fourier‐transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–Vis spectroscopy and dynamic light scattering. FTIR spectra demonstrated the successful functionalisation of silica NP with 3‐aminopropyl trimethoxysilane. SEM and TEM images showed the morphology and diameter of the synthesised silica NPs (137 ± 26 nm) and GNS. UV–Vis spectrum illustrated the maximum absorbance of the resultant GNS and their average hydrodynamic diameter was 159 nm. For in vitro study, HCT‐116 cells were exposed to gold nanoshells and intense pulsed light in different experiment groups. The results showed that exposing the cells to nanoshells and 30 s irradiation would efficiently decrease the viability percentage of the cells to about 30% compared with the control. A continued exposure of 4 min decreased the viability of the cancer cells to 20%. The results demonstrated that photothermal therapy would be promising in treatment of colon cancer cells utilising gold nanoshells.Inspec keywords: gold, silicon compounds, nanomedicine, plasmonics, radiation therapy, bio‐optics, cancer, cellular biophysics, nanoparticles, Fourier transform spectra, infrared spectra, scanning electron microscopy, transmission electron microscopy, ultraviolet spectra, visible spectraOther keywords: plasmonic photothermal therapy, colon cancer cells, gold‐silica nanoshells, GNS, Halas method, Fourier transform infrared spectroscopy, FTIR, scanning electron microscopy, SEM, transmission electron microscopy, TEM, UV‐vis spectroscopy, dynamic light scattering, FTIR spectra, 3‐aminopropyl trimethoxysilane, morphology, in vitro study, HCT‐116 cells, cell viability, nanoparticles, time 30 s, time 4 min, Au     

Relationship between Translational and Rotational Dynamics of Alkyltriethylammonium-Based Ionic Liquids

¹H spin-lattice relaxation experiments have been performed for a series of ionic liquids including bis(trifluoromethanesulfonyl)imide anion and cations of a varying alkyl chain length: triethylhexylammonium, triethyloctylammonium, decyltriethylammonium, dodecyltriethylammonium, triethyltetradecylammonium, and hexadecyltriethylammonium. The relaxation studies were carried out in abroad frequency range covering three orders of magnitude, from 10 kHz to 10 MHz, versus temperature. On the basis of a thorough, quantitative analysis of this reach data set, parameters characterizing the relative, cation-cation, translation diffusion (relative diffusion coefficients and translational correlation times), and rotational motion of the cation (rotational correlation times) were determined. Relationships between these quantities and their dependence on the alkyl chain length were discussed in comparison to analogous properties of molecular liquids. It was shown, among other findings, that the ratio between the translational and rotational correlation times is smaller than for molecular liquids and considerably dependent on temperature. Moreover, a comparison of relative and self-diffusion coefficients indicate correlated translational dynamics of the cations.     

Relative Cation-Anion Diffusion in Alkyltriethylammonium-Based Ionic Liquids

¹⁹F Nuclear Magnetic Resonance spin-lattice relaxation experiments have been performed for a series of ionic liquids including the same anion, bis(trifluoromethanesulfonyl)imide, and cations with alkyl chains of different lengths: triethylhexylammonium, triethyloctylammonium_, decyltriethylammonium, dodecyltriethylammonium, decyltriethylammonium, and hexadecyltriethylammonium. The experiments have been carried out in a frequency range of 10 kHz to 10 MHz versus temperature. A thorough analysis of the relaxation data has led to the determination of the cation–anion as a relative translation diffusion coefficient. The diffusion coefficients have been compared with the corresponding cation–cation and anion–anion diffusion coefficients, revealing a correlation in the relative translation movement of the anion and the triethylhexylammonium, triethyloctylammonium, decyltriethylammonium, and dodecyltriethylammonium cations, whereas the relative translation diffusion between the anion and the cations with the longer alkyl chains, decyltriethylammonium and hexadecyltriethylammonium, remains rather uncorrelated (correlated to a much lesser extent).