Hydrous iron oxide for removal of inorganic contaminants in simulated stormwater: A batch sorption kinetics study

Urban stormwater runoff, which consists of inorganic and organic contaminants, is a major source of pollutants to receiving waters and therefore they need to be removed. Simultaneous removal of contaminants, Cd²⁺, Cu²⁺, Ni²⁺, Zn²⁺ (heavy metal cations), and SeO₄²⁻ (oxyanion) from a simulated stormwater by a hydrous ferric oxide (HFO) was studied in batch and column sorption experiments. In the batch experiment the rate of sorption of the ions was rapid at the beginning and reached equilibrium in approximately 300 min. The amounts of ions sorbed were proportionate to the respective initial concentration of the ions added to the HFO. Cluster analysis showed that all heavy metals had similar sorption behavior, whereas Se had a distinctly different sorption process. Of the three different kinetic models tested the pseudo-first order kinetic model fitted the data the best. The column experimental results beyond 180 min were consistent with those of the batch experiment that the removal efficiencies of the ions were in proportion to the ion concentration in the feed. Below 180 min, Cu appeared to be preferentially removed than Zn.     

Co‐optimization of SnS absorber and Zn(O,S) buffer materials for improved solar cells

Thin‐film solar cells consisting of earth‐abundant and non‐toxic materials were made from pulsed chemical vapor deposition (pulsed‐CVD) of SnS as the p‐type absorber layer and atomic layer deposition (ALD) of Zn(O,S) as the n‐type buffer layer. The effects of deposition temperature and annealing conditions of the SnS absorber layer were studied for solar cells with a structure of Mo/SnS/Zn(O,S)/ZnO/ITO. Solar cells were further optimized by varying the stoichiometry of Zn(O,S) and the annealing conditions of SnS. Post‐deposition annealing in pure hydrogen sulfide improved crystallinity and increased the carrier mobility by one order of magnitude, and a power conversion efficiency up to 2.9% was achieved. Copyright © 2014 John Wiley & Sons, Ltd.     

Identification and extraction of brain tumor from MRI using local statistics of Zernike moments

In this article, a novel method is proposed for the detection of brain tumor in magnetic resonance images (MRIs). The features of Zernike moments are used to analyze the MRIs. The image is divided into two parts from the center of the image based on the average value of the pixel located at the center boundary, and new image vectors are formed to extract the tumor. The local statistics values obtained from the low and high order Zernike moments are used to calculate the appropriate threshold value for efficient tumor extraction. The proposed method successfully analyzes the tumor part of the image on testing with different MRIs.     

Electrochemical synthesis of hexagonal closed pack nickel: A hydrogen storage material

An in situ hydrogen generation and storage technique is demonstrated during the electrodeposition of hexagonal closed pack (HCP) nickel from NiCl₂-1-ethyl-3-methylimidazolium chloride (NiCl₂-EmimCl) and NiCl₂·6H₂O-1-ethyl-3-methylimidazolium chloride (NiCl₂·6H₂O-EmimCl) melts. During electrolysis, the dissolution of hydrogen in nickel takes place due to the electrolysis of water. This results in the production of HCP nickel. The hydrogen content of the electrodeposited nickel from NiCl₂-EmimCl was found to be 1.2 wt.%. Thermal analysis showed that the phase transformation from HCP nickel to FCC occurred at 462 °C, releasing hydrogen in the process.     

The production of renewable transportation fuel through fed‐batch and continuous deoxygenation of vegetable oil derived fatty acids over Pd/C catalyst

Renewable fuels such as green diesel from renewable biomass have received attentions because of energy and environmental concerns. Deoxygenation, used to upgrade biomass derived oils has been applied intensively nowadays. To successfully improve this process, fed‐batch and following continuous processes on real biomass derived fatty acids need to be investigated. In this study, liquid‐phase deoxygenation of vegetable oil derived fatty acids was carried out over 5% Pd/C with cofeeding H₂. With sufficient hydrogen, complete hydrogenation of unsaturated fatty acids occurred, leading to successive deoxygenation of the saturated fatty acids with n‐alkane yields of 99% and 88% and average CO₂ selectivity of 94.9% and 94.6% in the fed‐batch and continuous mode, respectively. After hydrogenation is completed, lower than 5% of effective H₂ partial pressure was found to be favorable for the decarboxylation pathway and ideal for deoxygenation of biomass derived fatty acids. Copyright © 2015 John Wiley & Sons, Ltd.     

Insight into the Solid Electrolyte Interphase Formation in Bis(fluorosulfonyl)Imide Based Ionic Liquid Electrolytes

The formation of the solid electrolyte interphase (SEI) in an ionic liquid electrolyte of 0.5 m lithium bis(fluorosulfonyl)imide (LiFSI) in 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)imide at high cell voltages (1.7–1.9 V) is investigated in ordered mesoporous carbon (OMC) based Li metal cells using an operando small-angle neutron scattering (SANS) technique coupled with electrochemical impedance spectroscopy and ex situ X-ray photoelectron spectroscopy (XPS). It is demonstrated that discharging the OMC Li metal cells to ≈2 V and holding the cell voltage constant induces a rapid current increase with time, confirming extensive reduction and SEI formation. XPS analysis reveals that LiF is formed at open cell voltage (OCV), which is attributed to the carbenes generated at the lithium negative electrode because of its reaction with EMIm cation diffusing to and initiating the reaction with FSI⁻ anions at the carbon positive electrode. It is confirmed that the chemical reaction at OCV and electrochemical reduction at high cell voltage of the FSI⁻ anion plays a protective role against EMIm cation co-intercalation into the carbon positive electrode during the initial discharge. Operando SANS studies also suggest that slight differences occur in the surface composition and reaction mechanism as a function of cell voltage.     

Engineering the Interlayer Spacing by Pre-Intercalation for High Performance Supercapacitor MXene Electrodes in Room Temperature Ionic Liquid

MXenes exhibit excellent capacitance at high scan rates in sulfuric acid aqueous electrolytes, but the narrow potential window of aqueous electrolytes limits the energy density. Organic electrolytes and room-temperature ionic liquids (RTILs) can provide higher potential windows, leading to higher energy density. The large cation size of RTIL hinders its intercalation in-between the layers of MXene limiting the specific capacitance in comparison to aqueous electrolytes. In this work, different chain lengths alkylammonium (AA) cations are intercalated into Ti₃C₂T_x, producing variation of MXene interlayer spacings (d-spacing). AA-cation-intercalated Ti₃C₂T_x (AA-Ti₃C₂), exhibits higher specific capacitances, and cycling stabilities than pristine Ti₃C₂T_x in 1 m 1-ethly-3-methylimidazolium bis-(trifluoromethylsulfonyl)-imide (EMIMTFSI) in acetonitrile and neat EMIMTFSI RTIL electrolytes. Pre-intercalated MXene with an interlayer spacing of ≈2.2 nm, can deliver a large specific capacitance of 257 F g⁻¹ (1428 mF cm⁻² and 492 F cm⁻³) in neat EMIMTFSI electrolyte leading to high energy density. Quasi elastic neutron scattering and electrochemical impedance spectroscopy are used to study the dynamics of confined RTIL in pre-intercalated MXene. Molecular dynamics simulations suggest significant differences in the structures of RTIL ions and AA cations inside the Ti₃C₂T_x interlayer, providing insights into the differences in the observed electrochemical behavior.     

Assessment of an active-cooling micro-channel heat sink device,using electro-osmotic flow

Non-uniform heat flux generated by microchips causes “hot spots” in very small areas on the microchip surface. These hot spots are generated by the logic blocks in the microchip bay; however, memory blocks generate lower heat flux on contrast. The goal of this research is to design, fabricate, and test an active cooling micro-channel heat sink device that can operate under atmospheric pressure while achieving high-heat dissipation rate with a reduced chip-backside volume, particularly for spot cooling applications. An experimental setup was assembled and electro-osmotic flow (EOF) was used thus eliminating high pressure pumping system. A flow rate of 82 μL/min was achieved at 400 V of applied EOF voltage. An increase in the cooling fluid (buffer) temperature of 9.6 °C, 29.9 °C, 54.3 °C, and 80.1 °C was achieved for 0.4 W, 1.2 W, 2.1 W, and 4 W of heating powers, respectively. The substrate temperature at the middle of the microchannel was below 80.5 °C for all input power values. The maximum increase in the cooling fluid temperature due to the joule heating was 4.5 °C for 400 V of applied EOF voltage. Numerical calculations of temperatures and flow were conducted and the results were compared to experimental data. Nusselt number (Nu) for the 4 W case reached a maximum of 5.48 at the channel entrance and decreased to reach 4.56 for the rest of the channel. Nu number for EOF was about 10% higher when compared to the pressure driven flow. It was found that using a shorter channel length and an EOF voltage in the range of 400–600 V allows application of a heat flux in the order of 10⁴ W/m², applicable to spot cooling. For elevated voltages, the velocity due to EOF increased, leading to an increase in total heat transfer for a fixed duration of time; however, the joule heating also got elevated with increase in voltage.     

Evaluation of Enhanced Heat Transfer Within a Four Row Finned Tube Array of an Air Cooled Steam Condenser

Air cooled steam condensers (ACSC) consist of finned-tube arrays bundled in an A-frame structure. Inefficient performance under extreme temperature operating conditions is a common problem in ACSCs. The purpose of this study was to improve the heat transfer characteristics of an annular finned-tube system for better performance in extreme climatic conditions. Perforations were created on the surface of the annular fins to increase heat transfer coefficient (h). Mesh generation and finite volume analyses were performed using Gambit 2.4.6 and Fluent 6.3 with an RNG k–? turbulent model to calculate pressure drop (ΔP), heat flux (q), and heat transfer coefficient (h). Solid (no perforations) finned-tubes were simulated with free stream velocity ranging between 1 m/s–5 m/s and validated with the published data. Computations were performed for perforations at 30° interval starting at ±60°, ±90°, ±120°, ±150°, and ±180° from the stagnation point. Five cases with single perforation and three cases with multiple perforations were evaluated for determining the maximum q and h, as well as minimum ΔP. For the perforated case (perforations starting from 60° at interval of 30°), the fin q and h performance ratios increased by 5.96% and 7.07%, respectively. Consequently, the fin ΔP performance ratio increased by 11.87%. Thus, increased q and h is accompanied with a penalty of higher ΔP. In contrast, a single perforation location at 120° provided favorable results with a 1.70% and 2.23% increase in q and h performance ratios, respectively, while there was a relatively smaller increase (only 1.39%) of ΔP performance ratio. Perforations in the downstream region at ±120°, ±150°, and ±180° also resulted in a similar favorable outcome. Furthermore, the spacing of the fins along the arms of an A-frame ACSC was altered to decrease ΔP across the finned-tube array. Fin spacing in the A-frame structure with sparsely spaced fins in the center resulted in a 1.80% reduction in ΔP. Thus, penalty in ΔP for a perforated fin can possibly be offset by changing the fin spacing along the arms of an A-frame structure.     

Two-phase pressure drop response during load transients in a PEMFC

Transient behavior of PEM fuel cells can be categorized into electrochemical, thermal and two-phase flows. Overshoot/undershoot behavior has been observed in electrochemical cell voltage during transients, and are attributed to the transition time required for saturation conditions to reestablish. Similar behavior has been reported in two-phase flow pressure drop overshoot/undershoot in a previous work by the authors. In this work, three different temperatures, five ramp rates and four amplitudes of load change were used to investigate the transient two-phase pressure drop behavior. The overshoot/undershoot behavior is observed predominantly at the lower temperature of 40 °C, and is found to decrease at higher cell temperatures. There is a linear increase in the overshoot/undershoot behavior with increase in amplitude of load change. The overshoot/undershoot behavior was found to be independent of the ramp rates used to change the load current. The magnitude of overshoot in pressure drop was always larger than the magnitude of undershoot. The pressure drop required a longer time to return to steady state after an undershoot compared to the time required to return from an overshoot incident.