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1.
Summary To clarify the mechanism of living radical polymerization of methyl methacrylate (MMA) with tetraphenylsuccinodinitrile (TPSN) as a thermal iniferter, a model compound for the end group of the poly(MMA) produced, methyl 2,2-dimethyl-3,3-diphenyl-3-cyanopropionate (2), was synthesized and found to initiate a living radical polymerization of MMA, indicating that the hexa-substituted C-C bond in 2 dissociated into radicals. The poly(MMA) thus obtained further initiated the radical polymerization of styrene (St) to give a block copolymer. 相似文献
2.
Kimihiro Yamashita Motohide Matsuda Yasushi Inda Takao Umegaki Masayuki Ito Toshinori Okura 《Journal of the American Ceramic Society》1997,80(7):1907-1909
Dielectric depression and dispersion were observed in BaTiO3 ceramic films fabricated by electrophoretic deposition followed by sintering. The dielectric constants were depressed down to 6800–4600 around the Curie point ( T C ). The dielectric dispersion occurred above T C . These dielectric properties are attributable to a surface layer formed during sintering. XRD analysis indicated that the surface layer was a hexagonal-like BaTiO3 phase. A mixed solvent of acetylacetone and alcohol employed in the present work may have been responsible for the formation of the surface layer. 相似文献
3.
4.
The Spiro compound N3P3(OCH2CF3)4(NH)2Si(CH3)2 formed by reaction of 1,1-diamino-3,3,5,5-tetrakis(2,2,2-trifluoroethoxy)cyclotriphosphazene N3P3(OCH2CF3)4(NH2)2 and dimethyldichlorosilane Cl2Si(CH3)2 is a yellow or orange coloured oil soluble in organic solvents, vapourized at 160°C without decomposition, and not hydrolysed appreciably in boiling water. Linear compounds are formed by reaction of N3P3(OCH2CF3)4(NH2)2 with diphenyldichlorosilane or phenyltrichlorosilane owing to hindrance of the phenyl radical. These compounds are amorphous or tacky solids, soluble in organic solvents and stable to water. 相似文献
5.
Development of high performance,waterborne coatings. Part II: Factors affecting adhesion performance
A new manufacturing process for high performance, waterborne coatings for can coating application was developed, which includes emulsification of an epoxy resin with or without a hardener by incorporation of an acrylic resin. It is possible by this new process to emulsify a variety of resins with minimum effects of the surfactant. (acrylic resin). The effects of surfactant and neutralizer on adhesion performance were studied. It was found that the effects of the acrylic resin amount were relatively small, and that the effects of the neutralizer were significant. It was confirmed that the usage of ammonia or amines with a branched alkyl group is required to achieve balanced dry and wet adhesion. 相似文献
6.
Summary The bulk polymerization of methyl methacrylate (MMA) with 1,2-disubstituted tetraphenylethanes, tetraphenylsuccinodinitrile (TPSN), tetra(p-methoxyphenyl)succinodinitrile (TMPSN), and pentaphenylethane (PPE), was investigated. These compounds were found to serve as thermal iniferters to induce living radical polymerization via a mechanism close to the model proposed previously (see Eq. 2). However, the living nature was not so high, because undesirable side reactions occurred. The oligomer with molecular weight of 2500 was isolated from the reaction mixture of MMA with TPSN, which was found to cause further polymerization of MMA. From the polymerization of styrene (St) with the polymers obtained by these iniferters, the block copolymers were produced. 相似文献
7.
Poly(anilino sulphamicphosphazenes) such as [NP(HNC6H5)2–x
(HNC6H4SO3H)
x
]
n
for polymer (I) x=0.3 and for polymer (II) x=0.8 were prepared by the reaction of poly(anilinophosphazene) [NP(HNC6H5)2]
n
and sulphonic chloride HSO3Cl in tetrachloroethane solvent several timeS. Also, H protons in the polymer (I) and (II) were prepared from lithum hydroxide in aqueous solution. It was found, by chemical analysis, that the product prepared with (I) and (II) had compositions such as [NP(HNC6H5)1.7 (HNC6H4SO3H)0.1(HNC6H4SO3Li)0.2]
n
(III) and [NP(HNC6H5)1.2(HN-C6H4SO3Li)0.8]
n
(IV). Also, the resistivity of products (III) and (IV) were determined and found to be 3.3×107 and 1.5×107 cm–1, respectively. 相似文献
8.
Norihiro Moriyama Yuta Kawano Qing Wang Ryota Inoue Meng Guo Makoto Yokoji Hiroki Nagasawa Masakoto Kanezashi Toshinori Tsuru 《American Institute of Chemical Engineers》2021,67(7):e17223
Pervaporation (PV) is a membrane technology that holds great promise for industrial applications. To better understand the PV mechanism, PV dehydrations of various types of organic solvents (methanol, ethanol, iso-propanol, tert-butanol, and acetone) were performed on five types of organosilica and two types of silicon carbide-based membranes, all with different pore sizes. Water permeance was dependent on the types of organic aqueous solutions, which suggested that organic solvents penetrated the pores and hindered the permeation of water. In addition, water permeance of various types of membranes in PV was well correlated with hydrogen permeance in single-gas permeation. Furthermore, a clear correlation was obtained between the permeance ratio in PV and that in single-gas permeation, which was confirmed via the modified-gas translation model. These correlations make it possible to use single-gas permeation properties to predict PV performance. 相似文献
9.
The crystallization process of Pd74Si18Au8 amorphous alloy has been investigated by transmission electron microscopy, small angle X-ray scattering and three-dimensional atom probe techniques. Although literature suggests that the alloy decomposes into two glassy phases prior to the crystallization, we found that the crystallization occurs directly from a single amorphous phase by the primary crystallization of fcc Pd–Au solid solution, followed by the polymorphous crystallization of the remaining amorphous phase to a Pd3Si phase. 相似文献
10.
Kiyohiko Hattori Eri Homma Toshinori Kagawa Masayuki Otani Naoki Tatebe Yasunori Owada Lin Shan Katsuhiro Temma Kiyoshi Hamaguchi 《Artificial Life and Robotics》2016,21(4):451-459
Recently, many extensive studies have been conducted on robot control via self-positioning estimation techniques. In the simultaneous localization and mapping (SLAM) method, which is one approach to self-positioning estimation, robots generally use both autonomous position information from internal sensors and observed information on external landmarks. SLAM can yield higher accuracy positioning estimations depending on the number of landmarks; however, this technique involves a degree of uncertainty and has a high computational cost, because it utilizes image processing to detect and recognize landmarks. To overcome this problem, we propose a state-of-the-art method called a generalized measuring-worm (GMW) algorithm for map creation and position estimation, which uses multiple cooperating robots that serve as moving landmarks for each other. This approach allows problems of uncertainty and computational cost to be overcome, because a robot must find only a simple two-dimensional marker rather than feature-point landmarks. In the GMW method, the robots are given a two-dimensional marker of known shape and size and use a front-positioned camera to determine the marker distance and direction. The robots use this information to estimate each other’s positions and to calibrate their movement. To evaluate the proposed method experimentally, we fabricated two real robots and observed their behavior in an indoor environment. The experimental results revealed that the distance measurement and control error could be reduced to less than 3 %. 相似文献