Synthesis method comparison of compositionally complex rare earth-based Ruddlesden–Popper n = 1 T′-type cuprates

The multicomponent approach has been successfully expanded to the Ruddlesden–Popper structure with the synthesis of two different high-entropy cuprate compositions: (La_0.2Nd_0.2Gd_0.2Tb_0.2Dy_0.2)₂CuO₄ and (La_0.2Pr_0.2Nd_0.2Sm_0.2Eu_0.2)₂CuO₄. The effect of synthesis method is explored using both solid-state reaction and polymeric steric entrapment (PSE) methods. It is found that PSE leads to more randomly distributed cation species, providing an advantageous method of synthesis for the growing field of high entropy oxides. In situ high-temperature x-ray diffraction tracks the amorphous to crystalline phase transformation in (La_0.2Nd_0.2Gd_0.2Tb_0.2Dy_0.2)₂CuO₄ powder, synthesized using the PSE method. Using the High-Temperature XRD data, a method for gaining information on the kinetic behavior is also applied. Magnetometry of both compositions indicates ferrimagnetic behavior at low temperatures.     

Remotely sensed surface water extent as an indicator of short-term changes in ecohydrological processes in sub-Saharan Western Africa

The highly variable rainfall in the arid and semi-arid regions of sub-Saharan Western Africa drives both surface water availability and vegetation cover. Recent studies have established linkages between rainfall and vegetation cover at local to regional scales, but no study related yet remote sensing derived rainfall and vegetation cover to the available surface water. A new dataset based on SPOT VEGETATION (VGT) represents surface water bodies (SWB) in the arid and semi-arid regions of sub-Saharan Western Africa. Water bodies represent the integrated hydrological response of a catchment, and changes in their spatial extent involve complex interactions at the catchment scale. We analyzed time series of remotely sensed vegetation cover, rainfall and surface water extent for the period 1999–2008, and could detect and statistically demonstrate the links between these biophysical variables. Our findings for two regions in Mali and Burkina Faso suggest that vegetation cover is positively related to the amount of available surface water for those catchments that are mainly covered by annual plants. The observed relationships between remotely sensed variables allow developing ecological indicators that can indicate short-term changes in arid and semi-arid ecosystems at local to regional scales.     

Staining of white marble

White marbles have been a popular building material since Greek and Roman times. Recently, the long-term aesthetical aspect of white marbles has been questioned. In this paper, the results of our research on the development of stains on different types of white marbles (seven Italian and one Greek marble) are presented. The staining of white marbles has been studied by using different microscopic techniques and staining methods. In addition, a new optimised staining technique is proposed for artificially staining of white Carrara marble. An objective normalised measuring method is also developed for quantifying the discolouration of natural materials. Although the inclusions of organic material in crystals in marbles are often suggested to be responsible for staining, this investigation illustrated that they have little or no influence on the discolouration of the natural stones. Systematic investigation showed that the presence of pyrite and hematite crystals plays a dominant role for the development of discolouration.     

A mathematical model of adult subventricular neurogenesis

Neurogenesis has been the subject of active research in recent years and many authors have explored the phenomenology of the process, its regulation and its purported purpose. Recent developments in bioluminescent imaging (BLI) allow direct in vivo imaging of neurogenesis, and in order to interpret the experimental results, mathematical models are necessary. This study proposes such a mathematical model that describes adult mammalian neurogenesis occurring in the subventricular zone and the subsequent migration of cells through the rostral migratory stream to the olfactory bulb (OB). This model assumes that a single chemoattractant is responsible for cell migration, secreted both by the OB and in an endocrine fashion by the cells involved in neurogenesis. The solutions to the system of partial differential equations are compared with the physiological rodent process, as previously documented in the literature and quantified through the use of BLI, and a parameter space is described, the corresponding solution to which matches that of the rodent model. A sensitivity analysis shows that this parameter space is stable to perturbation and furthermore that the system as a whole is sloppy. A large number of parameter sets are stochastically generated, and it is found that parameter spaces corresponding to physiologically plausible solutions generally obey constraints similar to the conditions reported in vivo. This further corroborates the model and its underlying assumptions based on the current understanding of the investigated phenomenon. Concomitantly, this leaves room for further quantitative predictions pertinent to the design of future proposed experiments.     

Effect of transfer on droplet size in liquid-liquid dispersions

Mean droplet diameter of the dispersed phase in pulsed plate extraction columns was measured for binary and ternary systems. A change in the droplet size in the presence of solute, dependent on such factors as the direction of mass transfer, droplet size in the binary system, radio of diffusion coefficients, viscosity of the continuous phase, interfacial tension and driving force for extraction was observed. Two new empirical correlations of mean droplet sizes in mass transfer conditions are proposed. These correlations have been successfully applied to other extraction columns.     

Eye-tracking Analysis in Landscape Perception Research: Influence of Photograph Properties and Landscape Characteristics

Abstract

The European Landscape Convention emphasises the need for public participation in landscape planning and management. This demands understanding of how people perceive and observe landscapes. This can objectively be measured using eye tracking, a system recording eye movements and fixations while observing images. In this study, 23 participants were asked to observe 90 landscape photographs, representing 18 landscape character types in Flanders (Belgium) differing in degree of openness and heterogeneity. For each landscape, five types of photographs were shown, varying in view angle. This experiment design allowed testing the effect of the landscape characteristics and photograph types on the observation pattern, measured by Eye-tracking Metrics (ETM). The results show that panoramic and detail photographs are observed differently than the other types. The degree of openness and heterogeneity also seems to exert a significant influence on the observation of the landscape.     

On the Relation between Morphology and FET Mobility of Poly(3‐alkylthiophene)s at the Polymer/SiO2 and Polymer/Air Interface

The influence of the interface of the dielectric SiO₂ on the performance of bottom‐contact, bottom‐gate poly(3‐alkylthiophene) (P3AT) field‐effect transistors (FETs) is investigated. In particular, the operation of transistors where the active polythiophene layer is directly spin‐coated from chlorobenzene (CB) onto the bare SiO₂ dielectric is compared to those where the active layer is first spin‐coated then laminated via a wet transfer process such that the film/air interface of this film contacts the SiO₂ surface. While an apparent alkyl side‐chain length dependent mobility is observed for films directly spin‐coated onto the SiO₂ dielectric (with mobilities of ≈10^?3 cm² V^?1 s^?1 or less) for laminated films mobilities of 0.14 ± 0.03 cm² V^?1 s^?1 independent of alkyl chain length are recorded. Surface‐sensitive near edge X‐ray absorption fine structure (NEXAFS) spectroscopy measurements indicate a strong out‐of‐plane orientation of the polymer backbone at the original air/film interface while much lower average tilt angles of the polymer backbone are observed at the SiO₂/film interface. A comparison with NEXAFS on crystalline P3AT nanofibers, as well as molecular mechanics and electronic structure calculations on ideal P3AT crystals suggest a close to crystalline polymer organization at the P3AT/air interface of films from CB. These results emphasize the negative influence of wrongly oriented polymer on charge carrier mobility and highlight the potential of the polymer/air interface in achieving excellent “out‐of‐plane” orientation and high FET mobilities.     

Indecisiveness and high school students' career decision-making process: Longitudinal associations and the mediational role of anxiety.

This study examined how indecisiveness relates to adolescents' process of choosing a study in higher education, using a longitudinal design. A sample of 281 students participated at the beginning, middle, and end of Grade 12. Findings show that indecisiveness was a risk factor for future levels of coping with the career decisional tasks of broad and in-depth environmental exploration (amount of information and exploratory behavior), amount of self-information, decisional status, and commitment. However, indecisiveness did not relate to the degree of change in decisional tasks during Grade 12. Moreover, results suggest that the linkage of indecisiveness with the amount of in-depth environmental information, the amount of self-information, decisional status, and commitment was mediated by adolescents' career choice anxiety. Finally, stability data provided support for the conceptualization of indecisiveness as a trait. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Mixed analogue/digital phase picking algorithm in oversampling burst-mode clock phase alignment

A novel mixed analogue/digital design of a phase picking algorithm in an oversampling clock phase recovery is presented. The proposed approach results in reduced processing time, improved integrability with analogue front-end and low noise generation. Simulations of a 10 Gbit/s burst-mode clock phase alignment circuit in a 0.25 m SiGe BiCMOS process, show a simulated processing delay of only 280 ps.     

OSNR Penalty Imposed by Linear In-Band Crosstalk Caused by Interburst Residual Power in Multipoint-To-Point Networks

We present an analysis of linear in-band crosstalk in high split long reach wavelength/time-division-multiplexing passive optical networks (WDM-TDM PONs). In this letter, a mathematical model is deducted for the first time to calculate optical signal-to-noise ratio penalties due to in-band crosstalk in multipoint-to-point networks. The network performance can be perturbed by in-band crosstalk caused by power leakages from burst-mode optical network units (ONUs) in off-state. Our study results show that the leaked powers in upstream ONU transmitters can have an impact on the achievable split factor of WDM-TDM PONs. Furthermore, the performance limitations caused by aggregated interburst residual power are discussed.