大气压下等离子体喷涂制备Cu/W涂层性能研究(英文)

采用大气压等离子体喷涂和高速大气压等离子体喷涂技术制备Cu/W涂层,分别对该涂层断面的表面形貌、孔隙率、氧含量和结合强度进行测试分析.结果表明,高速大气压等离子体喷涂技术制备的Cu/W涂层在孔隙率和氧含量方面突显优势.采用高速大气压等离子体喷涂技术制备的Cu/W涂层孔隙率低于3%,且大部分孔径均小于1μm,利用EDS测得的W涂层氧含量为w(O)=0.41%,该值与真空等离子体喷涂制备的W涂层含氧量接近.与真空等离子体喷涂技术相比,高速大气压等离子体喷涂制备W涂层技术的复杂性和制作成本显著降低,在工程应用中实用可行.     

Plasma-Sprayed Coating of an Apatite-Type Lanthanum Silicate Electrolyte for Intermediate Temperature Solid Oxide Fuel Cells (IT-SOFCs)

Apatite-type lanthanum silicate was successfully synthesized via a solid state reaction protocol at 1400℃ in a vacuum for 4 hours. The powder was synthesized faster and at a lower reaction temperature than by conventional solid state reaction methods. The resulting powder was used in the fabrication of a coating deposited by atmospheric plasma spray (APS) technology. The microstructure of the coating was analyzed by X-ray diffraction and scanning electron microscopy. Heat treatment was found to fully crystallize the coating, increasing its density. The ionic conductivity of the apatite coating was 0.39 (0.054) mS/cm at 850 (700)℃, and its activation energy was 0.67 eV.