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1.
Beneficial effects of wettability altering surfactants in oil-wet fractured reservoirs 总被引:3,自引:0,他引:3
Subhash C. Ayirala Chandra S. Vijapurapu Dandina N. Rao 《Journal of Petroleum Science and Engineering》2006,52(1-4):261
In fractured reservoirs, an effective matrix-fracture mass transfer is required for oil recovery. Surfactants have long been considered for oil recovery enhancement, mainly in terms of their ability to reduce oil–water interfacial tension. These surfactants are effective when the fractured formations are water-wet, where capillary imbibition of surfactants from the fracture into the matrix contributes to oil recovery. However, another beneficial aspect of surfactants, namely their ability to alter wettability, remains to be explored and exploited. Surfactants capable of altering wettability can be especially beneficial in oil-wet fractured formations, where the surfactant in the fracture diffuses into the matrix and alters the wettability, enabling imbibition of even more surfactant into the matrix. This sequential process of initial diffusion followed by imbibition continues well into the matrix yielding significant enhancements in oil recovery.In order to test this hypothesis of sequential diffusion–imbibition phenomenon, Dual-Drop Dual-Crystal (DDDC) contact angle experiments have been conducted using fractured Yates dolomite reservoir fluids, two types of surfactants (nonionic and anionic) and dolomite rock substrates. A new experimental procedure was developed in which crude oil equilibrated with reservoir brine has been exposed to surfactant to simulate the matrix-fracture interactions in fractured reservoirs. This procedure enables the measurements of dynamic contact angles and oil–water interfacial tensions, in addition to providing the visual observations of the dynamic behavior of crude oil trapped in the rock matrix as it encounters the diffusing surfactant from the fractures. Both the measurements and visual observations indicate wettability alterations of the matrix surface from oil-wet to less oil-wet or intermediate wet by the surfactants. Thus this study is of practical importance to oil-wet fractured formations where surfactant-induced wettability alterations can result in significant oil recovery enhancements. In addition, this study has also identified the need to include contact angle term in the dimensionless Bond number formulations for better quantitative interpretation of rock–fluids interactions. 相似文献
2.
We propose a space-efficient scheme for summarizing multidimensional data streams. Our sketch can be used to solve spatial
versions of several classical data stream queries efficiently. For instance, we can track ε-hot spots, which are congruent
boxes containing at least an ε fraction of the stream, and maintain hierarchical heavy hitters in d dimensions. Our sketch
can also be viewed as a multidimensional generalization of the ε-approximate quantile summary. The space complexity of our
scheme is O((1/ε) log R) if the points lie in the domain [0, R]d, where d is assumed to be a constant. The scheme extends to the sliding window model with a log (ε n) factor increase in
space, where n is the size of the sliding window. Our sketch can also be used to answer ε-approximate rectangular range queries
over a stream of d-dimensional points. 相似文献
3.
Bayesian and Dempster-Shafer fusion 总被引:3,自引:0,他引:3
The Kalman Filter is traditionally viewed as a prediction-correction filtering algorithm. In this work we show that it can
be viewed as a Bayesian fusion algorithm and derive it using Bayesian arguments. We begin with an outline of Bayes theory,
using it to discuss well-known quantities such as priors, likelihood and posteriors, and we provide the basic Bayesian fusion
equation. We derive the Kalman Filter from this equation using a novel method to evaluate the Chapman-Kolmogorov prediction
integral. We then use the theory to fuse data from multiple sensors. Vying with this approach is the Dempster-Shafer theory,
which deals with measures of “belief”, and is based on the nonclassical idea of “mass” as opposed to probability. Although
these two measures look very similar, there are some differences. We point them out through outlining the ideas of the Dempster-Shafer
theory and presenting the basic Dempster-Shafer fusion equation. Finally we compare the two methods, and discuss the relative
merits and demerits using an illustrative example. 相似文献
4.
5.
Oxynitride compositions in the Si-Ca-Al-O-N and Si-Ca-Al, B-O-N systems were melted and furnace-cooled in BN crucibles at temperatures from 1650 to 1850° C under dry nitrogen atmosphereS. Glass formation, phase stability and crystallization were studied by characterizing the cooled melts by X-ray diffraction, DTA, and electron microscopy. Oxynitride batches with nitrogen content up to 11 at % formed glasses in the Si-Ca-Al-O-N system. Glasses in the Si-Ca-Al, B-O-N system could be formed only when the B2O3 content of the batch was less than 3 wt %. Oxynitride glasses in these boron-containing systems were characteristically inhomogeneous, difficult to process, and prone to crystallization. In both the systems, glasses exhibited glass transitions beginning at 1000° C and crystallization at 1300 to 1500° C. Nitrogen-containing crystalline phases were identified in devitrified glasses via microstructural and micro-mechanical analyses. 相似文献
6.
The microstructure and microchemistry of a sintered (≈ 1700° C) aluminosilicate ceramic (60 wt % Al2O3-40 wt% SiO2) was investigated by optical, scanning (SEM and EDAX), and analytical electron microscopy (TEM and STEM). The microstructural features of the fired ceramic consisted of unreacted Al2O3, glass, porosity, and equilibrium and metastable mullite phases. Residual Al2O3 agglomerates (≈ 15 to 30 μm in size) were surrounded by a ≈ 6 μm layer of equilibrium mullite (≈ 71.3 to 73.5 wt% Al2O3). The unreacted Al2O3-equilibrium mullite assembly formed islands embedded in a silica rich glass (≈ 4.5 to 14wt% Al2O3) which also contained 2 to 3 μm thick metastable mullite needles (≈ 70 to 77 wt% Al2O3). Phase separation and alumina rich glass compositions (≈ 57 to 59 wt% Al2O3) were also observed in some areas of the microstructure. 相似文献
7.
We consider an algorithmic problem that arises in the context of routing tables used by Internet routers. The Internet addressing scheme is hierarchical, where a group of hosts are identified by a prefix that is common to all the hosts in that group. Each host machine has a unique 32-bit address. Thus, all traffic between a source group s and a destination group d can be routed along a particular route c by maintaining a routing entry (s, d, c) at all intermediate routers, where s and d are binary bit strings. Many different routing tables can achieve the same routing behavior. In this paper we show how to compute the most compact routing table. In particular, we consider the following optimization problem: given a routing table D with N entries of the form (s, d, c) , determine a conflict-free routing table with fewest entries that has the same routing behavior as D. If the source and destination fields have up to w bits, and there are at most K different route values, then our algorithm runs in worst-case time O( NK w2) . 相似文献
8.
In this paper, we address a multi-product loading problem in which a vehicle (a truck or a ship) is used to transfer multiple products. The product demands are different but stationary over time. The vehicle consists of compartments of different sizes and each compartment can contain only one product type during each shipment. No shortages are permitted, and we assume that the inventory holding cost is significantly lower than the delivery cost. The objective is to minimize the setup rate, that is, the number of deliveries per time unit. A cyclic policy is shown to be optimal, and a heuristic algorithm is developed to determine the cycle length as well as the assignments of products to the compartments during each of the requisite number of shipments made during that cycle. A comparison of the solutions obtained by the proposed algorithm with the optimal solutions (or a bound) indicate that the algorithm provides solutions with optimal setup rates in most of the problem instances considered and, when not optimal, the setup rates of these solutions are close to optimal values. 相似文献
9.
The influence of whole-body vertical vibration on the dynamic human–seat interface pressure is investigated using a flexible grid of pressure sensors. The ischium pressure and the overall pressure distribution at the human–seat interface are evaluated as functions of the magnitude and frequency of vibration excitation, and seated posture and height. The dynamic pressure at the seat surface is measured under sinusoidal vertical vibration of different magnitudes in the 1–10 Hz frequency range. Two methods based on ischium pressure and ischium force are proposed to study the influence of seat height, posture and characteristics of vibration. The results of the study reveal that the amplitude of dynamic pressure component increases with an increase in the excitation amplitude in almost entire frequency range considered in this study. The dynamic components of both the ischium pressure and the ischium force reveal peaks in the 4 to 5 Hz frequency band, the range of primary resonant frequency of the seated human body in the vertical mode. The mean values of the dynamic ischium pressure and the ischium force remain constant, irrespective of the excitation frequency and amplitude. The magnitudes of mean pressure and force at the human–seat interface, however, are dependent upon the seat height and the subject's posture. The inter-subject variability of the static ischium pressure and effective contact area are presented as functions of the subject weight and subject weight-to-height ratio. It was found that heavy subjects tend to induce low ischium pressure as a result of increased effective contact area.
Relevance to industry
Pressure distribution at the human–seat interface has been found to be an important factor affecting the seating comfort and work efficiency of various workers. The study of human–seat interface pressure distribution under vibration is specifically critical to the comfort, work efficiency and health of vehicle drivers, who are regularly exposed to vibration. The results reported in this paper will be useful to study dynamic response of the interface pressure and design vehicle seats. 相似文献
10.
Binary liquid-liquid-equilibria data for several aniline-paraffin and furfural-paraffin systems have been taken. These data along with data for other aniline-hydrocarbon and furfural-hydrocarbon systems from literature have been correlated using UNIFAC model. The UNIFAC group interaction parameters have been found to have a linear temperature dependence. The CH2 groups in cyclo and non cyclo paraffins require different interaction parameters. It was also found that a scaling of the combinatorial term is necessary for higher molecular weight hydrocarbons. 相似文献