Using a ball-milling technique, polymorphous iron particles were prepared by changing only the liquid-solid ratio λ. Effects of λ on their morphology, structure, conductivity, and electromagnetic properties were studied. The results show that an increase of λ from 0 to 0.25 causes a nonlinear decrease of the conductivity in the ranges of 88.50–2.25 S cm?1 and a regular variation of the electromagnetic parameters, corresponding to the as-obtained iron particles. This is ascribed to a combination of the increased shape anisotropy and the decreased fresh surface with active atoms deriving from the weakened welding-on action and the enhanced micro-malleation action in the ball-milling process. Hereinto, the iron flakes formed at wet-milling with λ=0.08?0.25 have lower conductivity, higher permittivity and permeability, and more excellent absorption property compared with the irregular iron particles obtained at dry-milling with λ=0. It is a consequence of the synergistic effect of dielectric relaxation loss, exchange energy and conductance loss originating from the flake-shape structures. This indicates that the morphology, structure, conductivity, and electromagnetic properties of the products can be effectively controlled by changing λ.
The one-stream hybrid thermal network is analyzed and discussed based on the entransy theory,and the results are compared with those from the entropy generation optimization.The theoretical analysis indicates that the minimum heat-flow-weighted temperature of the thermal networks corresponds to the minimum entransy dissipation rate and the minimum thermal resistance.For a simple hybrid thermal network consisting of three thermal components,the expression of entransy dissipation is conducted,and the heat transfer area and the mass flow rate are calculated and optimized.The optimal results are obtained in order to minimize the entransy dissipation and the thermal resistance.The optimal results are calculated for various combinations,such as series connection,parallel connection and other hybrid connections.The numerical results are in accordance with the theoretical analysis.Both the theoretical analysis and the numerical results show that the minimum entransy dissipation and the minimum thermal resistance correspond to the minimum heat-flow-weighted temperature of the thermal networks while the minimum entropy generation does not. 相似文献
The NaNbO3 powders were synthesized and their crystal structure changes were analyzed by ultrahigh pressure up to 6 GPa. The results indicate that the pure NaNbO3 powders can be synthesized at 300℃ under a pressure of 4 GPa, to significantly restrain the Na element volatilization compared with the traditional synthesis method. It is found that the crystal structure of synthesized NaNbO3 changes from low symmetry to high symmetry with the increase of the pressure. 相似文献