Room Temperature Ferromagnetism in Co-doped CuAlO2 Nanofibers Fabricated by Electrospinning

One-dimensional, diluted magnetic semiconductor nanofibers have attracted increasing attention for their unique magnetic properties, large specific surface area, and high porosity. These qualities lead to excellent performance in magneto-optical devices, magnetic resonance imaging, ferrofluids and magnetic separation. The purpose of this study is to fabricate P-type one dimensional CuAlO2-based diluted magnetic semiconductor nanofibers. First, we fabricated Cu Al0.95Co0.05O2 nanofibers with an average diameter of 1 μm with the electrospinning method. The annealed nanofibers were thermally treated at a temperature of 1 100 ℃ and then shrunk to a diameter of about 650 nm. We used X-ray diffraction measurements and Raman spectra to confirm that the Cu Al0.95Co0.05O2 nanofibers had a single impurity free delafossite phase. The X-ray photoelectron spectroscopy analysis indicates that Co was present in the +2 oxidation state, resulting in an room temperature ferromagnetism in the Cu Al0.95Co0.05O2 fiber. This contrasts with nonmagnetism in pristine CuAlO2 fiber. The coercivity(Hc) value of 65.26 Oe and approximate saturation magnetization(Ms) of 0.012 emu/g demonstrate good evidence of ferromagnetism at room temperature for Cu Al0.95Co0.05O2 nanofibers.     

Spin Dependent Hopping in Ti Doped La0.67 Ca0.33 MnO3

A systematic investigation of the magnetic and transport properties of Ti doped La0.67Ca0.33MnO3 was reported. The Ti substitution for Mn ions results in a reduction in ferromagnetism and conductivity. The metal-insulator transition temperature is close to Curie temperature which decreases from 274 to 82 K as x increases from 0 to 0.17. The most important effect of Ti doping is to introduce spin clusters in the samples due to the distortion of local lattice and the inhomogeneous magnetic structure induced primarily by the random distribution of Mn ions. A maximum magnetoresistance ratio as large as 90% in 1 T at 122 K was obtained for the sample with x =0. 055, which is four times larger than that obtained for LCMO sample at 272 K. There is a remarkable field-history dependent MR in the cooling process for the doped samples while such phenomenon disappears in the warming run. The resistivity follows well the variable range hopping behavior in paramagnetic state. Both the size effect and spin dependent hopping of carriers between the spin clusters should be considered in this system.     

钢筋混凝土受弯构件全约束优化设计

本文根据结构优化问题的特点，运用Ｋｕｈｕ－Ｔｕｃｋｅｒ最佳性条件，给出了满足现行ＧＢＪ１０－８９《混凝土结构设计规范》规定的钢筋混凝土受弯构件全约束优化设计方法。     

珠江口盆地开平凹陷油气聚集条件分析

珠江口盆地自新生代以来,曾先后受到不同方向张应力的作用,造成了不同时期构造体系的交叉叠合.中中新世以来构造运动强烈,并具有东强西弱的特点,对油气的运移与聚集产生了重要影响.开平凹陷的剧烈断裂和断陷活动始于始新世,并在同期沉积了巨厚的文昌组.晚渐新世以后,由于断裂活动非常微弱,在成熟的烃源岩与其上地层之间缺乏有效的油源断层,因而自生自储、近距离运移可能是开平凹陷油气聚集的基本特征.在凹陷内部,因重力滑动和欠压实泥岩共同作用所形成的KPll-1构造带可能是该区最具有油气远景的地区.     

MOS控制晶闸管的三重扩散工艺研究

本文对ＭＣＴ的核心工艺－三重扩散工艺进行了详细研究。通过ＳＵＰＲＥＭ－Ⅲ计算机工艺仿真，获得了三重扩散的工艺条件。     

吹风气回收装置运行总结

山西丰喜肥业（集团）股份有限公司临猗分公司合成氨一分厂建于2001年，造气采用固定床间歇气化技术，原料为阳泉洗中块煤。造气车间现有9台φ2650气化炉，配套D700型风机2台，D600风机1台，正常生产时9台炉全部满负荷生产，日产氨醇560t。     

影院建筑声学标准与测量(下)

2.声场分布及声缺陷的测量: 在影院及其它厅堂中,为使观(听)众区内任意位置都能清楚地听到对白、语言、音乐、动效等内容,故声场分布的均匀性也极为重要。 在相关标准中规定“在观众区内各测试点间声压级的最大值与最小值之差不大于6dB,最大值与平均值之差不大于3dB。”     

管好油库扭紧供应链条

中国油品市场的竞争将进入一个白势化的时期。参加这场角逐的各个竞争主体都在思考这祥一个问题:如何优化自己的成品油销售供应链,在竞争中发展并壮大自己。