Sustainable Oxidative Cleavage of Vegetable Oils into Diacids by Organo-Modified Molybdenum Oxide Heterogeneous Catalysts

Exploiting vegetable oils to produce industrially valuable diacids via an eco‐friendly process requires an efficient and recyclable catalyst. In this work, a novel catalytic system based on organo‐modified molybdenum trioxide was synthesized by a green hydrothermal method in one simple step, using Mo powder as precursor, hydrogen peroxide, and amphiphilic surfactants cetyltrimethylammonium bromide (CTAB) and tetramethylammonium bromide (TMAB) as capping agents. The synthesized materials were first characterized by different techniques including XRD, SEM, TGA, and FT‐IR. Interestingly, various morphologies were obtained depending on the nature of the surfactants and synthetic conditions. The synthesized catalysts were employed in oxidative cleavage of oleic acid, the most abundant unsaturated fatty acid, to produce azelaic and pelargonic acids with a benign oxidant, H₂O₂. Excellent catalytic activities resulting in full conversion of initial oleic acid were obtained, particularly for CTAB‐capped molybdenum oxide (CTAB/Mo molar ratio of 1:3) that gave 83 and 68% yields of production of azelaic and pelargonic acids, respectively. These are the highest yields that have been obtained for this reaction by heterogeneous catalysts up to now. Moreover, the CTAB‐capped catalyst could be conveniently separated from the reaction mixture by simple centrifugation and reused without significant loss of activity up to at least four cycles.     

When does length cause the word length effect?

The word length effect, the finding that lists of short words are better recalled than lists of long words, has been termed one of the benchmark findings that any theory of immediate memory must account for. Indeed, the effect led directly to the development of working memory and the phonological loop, and it is viewed as the best remaining evidence for time-based decay. However, previous studies investigating this effect have confounded length with orthographic neighborhood size. In the present study, Experiments 1A and 1B revealed typical effects of length when short and long words were equated on all relevant dimensions previously identified in the literature except for neighborhood size. In Experiment 2, consonant–vowel–consonant (CVC) words with a large orthographic neighborhood were better recalled than were CVC words with a small orthographic neighborhood. In Experiments 3 and 4, using two different sets of stimuli, we showed that when short (1-syllable) and long (3-syllable) items were equated for neighborhood size, the word length effect disappeared. Experiment 5 replicated this with spoken recall. We suggest that the word length effect may be better explained by the differences in linguistic and lexical properties of short and long words rather than by length per se. These results add to the growing literature showing problems for theories of memory that include decay offset by rehearsal as a central feature. (PsycINFO Database Record (c) 2011 APA, all rights reserved)     

Membrane as Solid∕Liquid Separator and Air Diffuser in Bioreactor

A bench-scale pilot plant was operated to evaluate the potential of using microfiltration hollow fiber membrane modules as an air diffuser and solid∕liquid separator in an alternate cycle within a bioreactor treating domestic wastewater. Two modules capable of air backwashing were immersed in a bioreactor. Compressed air backwashing and filtration by suction were effected alternatively. The experimental results reveal that application of the air backwashing technique to submerged membrane modules is capable of not only declogging the membranes but also of aerating the mixed liquor. Thus, better filtration flux rate and aeration without a separate aeration device were attained simultaneously. It was also noted that the introduction of an anoxic zone enhanced the removal of nitrogen. In addition, operation at low hydraulic retention time with high sludge concentration and the absence of a sedimentation tank indicate considerable savings on the plant area.     

Influence of Silicification on the Structural and Biological Properties of Buffer‐Mediated Collagen Hydrogels

A buffer‐mediated gelation route for collagen hydrogels that allows the formation of homogeneous composite and hybrid materials with various silica sources (i.e., colloidal silica and soluble silicates) at high concentration (up to 25 × 10^?3 M ) is described. Most significant improvement in rheological properties and proliferation of primary adult human dermal fibroblasts was obtained for the silicate‐based hybrid materials. A similar trend was observed in composite materials incorporating 14 nm SiO₂ nanoparticles, although to a much lesser extent, whereas larger colloids (80 and 390 nm) did not significantly impact mechanical stability and cell behavior. Modification of 80 nm particles surface with amine groups weakens the collagen‐mineral interface, resulting in the decrease of material stability and leading to particle aggregation during the course of cell proliferation experiments.     

Drying nano particles solution on an oscillating tip at an air liquid interface: what we can learn, what we can do

Evaporation of fluid at micro and nanometer scale may be used to self-assemble nanometre-sized particles in suspension. Evaporating process can be used to gently control flow in micro and nanofluidics, thus providing a potential mean to design a fine pattern onto a surface or to functionalize a nanoprobe tip. In this paper, we present an original experimental approach to explore this open and rather virgin domain. We use an oscillating tip at an air liquid interface with a controlled dipping depth of the tip within the range of the micrometer. Also, very small dipping depths of a few ten nanometers were achieved with multi walls carbon nanotubes glued at the tip apex. The liquid is an aqueous solution of functionalized nanoparticles diluted in water. Evaporation of water is the driving force determining the arrangement of nanoparticles on the tip. The results show various nanoparticles deposition patterns, from which the deposits can be classified in two categories. The type of deposit is shown to be strongly dependent on whether or not the triple line is pinned and of the peptide coating of the gold nanoparticle. In order to assess the classification, companion dynamical studies of nanomeniscus and related dissipation processes involved with thinning effects are presented.     

A stochastic continuation approach to piecewise constant reconstruction.

We address the problem of reconstructing a piecewise constant 3-D object from a few noisy 2-D line-integral projections. More generally, the theory developed here readily applies to the recovery of an ideal n-D signal (n > or =1) from indirect measurements corrupted by noise. Stabilization of this ill-conditioned inverse problem is achieved with the Potts prior model, which leads to a challenging optimization task. To overcome this difficulty, we introduce a new class of hybrid algorithms that combines simulated annealing with deterministic continuation. We call this class of algorithms stochastic continuation (SC). We first prove that, under mild assumptions, SC inherits the finite-time convergence properties of generalized simulated annealing. Then, we show that SC can be successfully applied to our reconstruction problem. In addition, we look into the concave distortion acceleration method introduced for standard simulated annealing and we derive an explicit formula for choosing the free parameter of the cost function. Numerical experiments using both synthetic data and real radiographic testing data show that SC outperforms standard simulated annealing.     

Water,Energy and Environment Nexus: The California Experience

The paper addresses the local and inter-state connections between water, energy and the environment. Using California and the western USA as a case study, the paper highlights the difficulties of balancing the needs of diverse stakeholders and protecting valuable resources while providing reliable and safe supplies of both water and energy to agricultural, industrial and residential customers. The investigation of these complex relationships is necessary to inform local and national policy decisions regarding the management of water, energy and the environment.     

Biological filtration through a packed-column

A model of the biological removal of dissolved pollutants by filtration through a packed-column has been developed. The theoretical predictions concerning porosity change, oxygen depletion and purification efficiency have been tested with a dissolved substrate: the model allows, after laboratory trials, the design and optimization of a filter.     

An integrated model for optimisation of production and quality costs

Whether an industrial organisation is involved with production of new goods or engaged in reverse logistics to recycle used products, the items produced that do not meet specifications can cost the organisation in many different ways. The administrative expenses of handling returned items and the cost of reworking the items that have failed in plant quality control or returned by customers can be of concern to the manufacturers. While these are measurable costs, there are other costs such as loss of customers’ good will which are hard, if not impossible, to estimate. The model presented in this paper is aimed at optimising the measurable cost of reworking/scrapping the off-specification items as well as the cost of adjusting manufacturing processes with the aim of reducing or eliminating rejected pieces. The adjustment of process specification in relation to customer specification is a strategy that can affect production and quality cost. Consideration for optimal production specification is one of the elements of the model presented in this paper. In the proposed model, the direct cost of poor quality has been represented by a symmetrical truncated loss function. We have considered investment to adjust the mean and variance of the process. A numerical example is presented to demonstrate how the model can work in a real-world setting.