Effects of Solvent Exchange Period and Heat Treatment on Physical and Chemical Properties of Rice Husk Derived Silica Aerogels

In this study, hydrophobic silica aerogels were synthesized from rice husk ash-derived sodium silicate through sol-gel processing, solvent exchange, surface modification and ambient pressure drying. By volume, 10% of trimethylchlorosilane (TMCS) in 90% of n-hexane was used as a hydrophobic solution in the surface modification process. The physical and chemical properties of silica aerogels were characterized by density and porosity measurements, scanning electron microscopy (SEM), Fourier transforms infrared (FTIR) spectroscopy, Brunauer–Emmett–Teller theory (BET) and dynamic scanning calorimetry (DSC). The hydrogels prepared were in the form of 2.5 ± 0.5 mm beads and then converted into alcogels through solvent exchange with ethanol for repetition of 3, 6 and 9 days. It is found that the optimal quality of silica aerogels with the BET surface area as high as 668.82 m²/g was obtained from the alcogels of the solvent exchange period of 9 days. Depending on the size of the gel’s block, a longer solvent exchange period will ensure adequate removal of pore water. Post heat treatment on silica aerogels obtained from the 9 days of solvent exchange at 200, 300 and 400 °C for 2 h results in slight decreased of aerogel’s density from 0.048 g/cm³ to 0.039 g/cm³ and the hydrophobicity of the aerogels is decreased above 380 °C as confirmed by DSC analysis.

     

Secure visual cryptography for medical image using modified cuckoo search

Multimedia Tools and Applications - Optimal secure visual cryptography for brain MRI medical image is proposed in this paper. Initially, the brain MRI images are selected and then discrete wavelet...     

Monoclonal antibody-based enzyme immunoassay for detection of porcine plasma in fish surimi

Detection of porcine plasma using indirect ELISA was developed using mAb B4E1 for the prevention of their usage in human food that creates religious and health conflicts. The immunoassay has a CV < 20% and did not cross-react to other meat and non-meat proteins. The sensitivity of the assay is 0.25% (w/w) of porcine plasma in spiked raw and cooked fish surimi. The assay did not produce a false positive result for any of the commercial fish surimi tested that were not contain porcine plasma. Determination of a 60-kDa antigenic protein of porcine blood using Western blot confirmed its presence in the plasma fraction of the porcine blood. Further proteomic analysis involving liquid chromatography–tandem mass spectrometry (LC-MS/MS) revealed the 60-kDa protein to be porcine serum albumin.     

Investigations for the optimal combination of zinc oxide nanoparticle-diesel fuel with optimal compression ratio for improving performance and reducing the emission features of variable compression ratio diesel engine

Clean Technologies and Environmental Policy - The continual hike in environmental pollution from diesel engines has raised the concern of researchers to identify certain clean fuels. For this...     

Effects of silica aerogel particle sizes on the thermal–mechanical properties of silica aerogel – unsaturated polyester composites

Silica aerogels with a surface area as high as 773?m²?g^?1 and a density of 0.077?g?cm^?3 were produced from rice husk via sol–gel process and ambient pressure drying. A particulate composite material was prepared by adding silica aerogel particles of three different particle sizes (powder, granules and bead) to unsaturated polyester resin with a fixed volume fraction of 30%. Thermogravimetric and thermal conductivity studies revealed that silica aerogel composites were having higher thermal stability and thermal insulation than the neat resin. It was suggested that the preservation of aerogel pores from resin intrusion is important for better thermal properties. Larger silica aerogel particles have more porous area (unwetted region) which results in a lower degradation rate and lower thermal conductivity of the base polymer. However, the addition of silica aerogel into resin has reduced the tensile modulus of the polymer matrix where smaller particle size displayed higher toughness than those with bigger particle size.     

Self‐similar characteristics of network intrusion attempts and the implications for predictability

One way of proactively detecting multistage attacks such as Distributed Denial of Service (DDoS), worms and coordinated spamming is to profile hosts that engage in scanning activity and predict their future actions, which is a difficult challenge. We attempt to better understand this challenge by hypothesising that network intrusion attempts exhibit self‐similar characteristics. We analyse logs from the DShield repository of globally distributed IDS alerts corresponding to the first 2 weeks of January 2005 and present three pieces of evidence in favour of this hypothesis. First, we observed that the persistence of hosts that attempt network intrusions obey a power‐law relationship such that the overwhelming majority of hosts are short‐lived whereas a small number are highly persistent. Second, the distribution of hosts in the IP address space is broadly identical regardless of different categories of lifetimes and intrusion attempts. Finally, there is a scale invariant diurnal cycle with long‐range dependence in the number of unique hosts observed per unit time. The overall implication of these findings is that any predictive model must account for identical statistical characteristics regardless of the volumetric, spatiotemporal and categorical resolution of the observations used to build and train that model. Copyright © 2010 John Wiley & Sons, Ltd.     

Development of Wi-Fi Based Home Energy Monitoring System for Green Internet of Things

Green Internet of things (IoT) has been heralded as the next big thing waiting to be realized in energy-efficient ubiquitous computing. Green IoT revolves around increased machine-to-machine communications and encompasses energy-efficient wireless embedded sensors and actuators that assist in monitoring and controlling home appliances. Energy efficiency in home applications can be achieved by better monitoring of the specific energy consumption by the appliances. There are many wireless standards that can be adopted for the design of such embedded devices in IoT. These communication technologies cater to different requirements and are classified as the short-range and long-range ones. To select the best communication method, this paper surveys various IoT communication technologies and discusses the advantages and disadvantages to develop an energy monitoring system. An IoT device based on the Wi-Fi technology system is developed and tested for usage in the home energy monitoring environment. The performance of this system is then evaluated by the measurement of power consumption metrics. In the efficient deep-sleep mode, the system saves up to 0.3 W per cycle with an average power dissipation of less than 0.1 W/s.     

Influence of incorporation methods of ATH on microstructure,elastomeric properties,flammability, and thermal decomposition of dynamically vulcanized NR/PP blends

Flame‐retardant thermoplastic vulcanizates (TPVs) of natural rubber (NR)/polypropylene (PP) (60/40 wt %) blends filled with alumina trihydrate (ATH) were prepared with an internal mixer. To increase the properties of flame‐retardant NR/PP TPV, the new mixing method, stepwise masterbatch mixing (SMB) method was adopted. The effects of SMB method along with different ATH loadings on microstructure and properties of NR/PP TPVs were investigated. Conventional one‐step mixing (CV) method was also studied for comparison. Transmission electron microscopy analysis showed that different processes led to a variation in microstructural homogeneity, which imposed various effects on blend properties. The mechanical properties of TPVs changed with ATH loading, and the strength of the samples obtained from SMB method was higher than those of CV method. LOI and cone calorimetry tests revealed that the flame retardancy of NR/PP blends dramatically increased at higher ATH loading. Furthermore, the increment level of flame retardancy was accelerated in the blends produced particularly through SMB method, resulting from homogeneity of local ATH distribution in NR/PP blend. Greater combustion resistance of blends prepared from SMB route were confirmed by thermogravimetry and pyrolysis‐gas chromatography–mass spectrometry techniques. Finally, a burning mechanism between filler structure and flammability of NR/PP TPVs obtained from CV and SMB methods was discussed. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46231.