Use of Al2O3 in an automated on-line pre-concentration system for determination of cadmium(II) by FAAS

This paper presents the development of an on-line pre-concentration system to determine cadmium(II) in aqueous samples. The analyte was trapped in a mini-column filled with Al(2)O(3) in the form of macro-spheres obtained by the mixture of Al(NO(3))(3).9H(2)O(aq) and chitosan dissolved in acetic acid. The mixture was dropped into an NH(4)OH aqueous solution under rigorous agitation using a peristaltic pump, the macro-spheres were separated from alkaline solution and dried, and finally were submitted to thermal treatment. The pre-concentration system was linear between 1.0 and 100 microg L(-1), with a linearity of 0.999, sensitivity of 3.58 x 10(-3)L microg(-1) and enrichment factor of 21.9. The limits of detection and quantification were 0.08 microg L(-1) and 0.28 microg L(-1), respectively. The repeatability was between 2.6 and 5.9%. Recovery tests were carried out with a real aqueous sample.     

Dealing with multiple experts and non-stationarity in inverse reinforcement learning: an application to real-life problems

Machine Learning - In real-world applications, inferring the intentions of expert agents (e.g., human operators) can be fundamental to understand how possibly conflicting objectives are managed,...