Electrolyte—solvent interaction in the dipolar aprotic solvent dimethyl sulphoxide at 25°C

Conductance measurements are reported for s-alkylisothiouronium bromide, iodide and picrate salts in the dipolar aprotic solvent DMSO at 25°C. The data were analysed by Fuoss's equation (1975–1980) for 1:1 electrolytes, from which the values of Λ₀, the Gurney's cosphere diameter R and K_A are obtained. The results are discussed in the light of the recorded values of the constants K_R and K_S and the free energy term G_s.     

A new application of Hydroxyapatite extracted from dromedary bone: Adsorptive removal of Congo red from aqueous solution

The aim of this paper is to evaluate the efficiency of the natural hydroxyapatite powder for anionic dye (Congo red) elimination from water and optimization of adsorption process parameters that are contact time (0-360 min), solution pH (4-9), initial dye concentration (400-2400 mg/l), and adsorbent dosage (0.4-20 g/l). Natural hydroxyapatite with high surface area was prepared from animal agriculture waste dromedary bone. X-ray diffraction, transmission electron microscopy, transform infrared spectroscopy, and elemental analysis characterizations of the powder prepared show a hexagonal structure, the irregular form of hydroxyapatite and presence of other elements as trace element. The results of adsorption tests demonstrated the high efficiency of natural hydroxyapatite for removal of Congo red from water solution whose maximum experimental capacity adsorption of Congo red by natural hydroxyapatite is 900 mg/g at pH 4.5, equilibrium time 240 min and adsorbent dosage 2 g/l. According to the correlation coefficient value, the pseudo-second order kinetic model identified the sorption mechanism of pollutant used on natural hydroxyapatite. The Freundlich isotherm is the best representative theoretical model of the dye molecules’ adsorption on the natural hydroxyapatite support.     

SOA$$^\mathrm{}$$: a new way to design the decision in SOA—based on the new standard Decision Model and Notation (DMN)

In recent years, Service Oriented Architecture (SOA) technologies are emerging as a powerful vehicle for organizations that need to integrate their applications within and across organizational boundaries. In addition, organizations need to make better decisions more quickly. Moreover, they need to change those decisions immediately to adapt to this increasingly dynamic business environment. It is primarily a question in ensuring the decisional aspect by adopting the SOA as a support architecture. In this paper, we describe a new approach called SOA\(^\mathrm{+d}\) based on a certain number of standards. It is going to be studied on three dimensions: The first is related to the definition of the information system implied in the SOA based on the use case model. The second develops the business dimension which is based on the BPMN (Business Process Modeling Notation). The last dimension addresses the need of decision; we use the new standard decision model and notation (DMN) which is recently approved by Object Management Group (OMG) and considered as a simple notation to specify the decision. Finally, Service Oriented Architecture Modeling Language (SoaML) will be used for design of several services. We also present our meta-model Decisional Model of Service (DMS) to define a new set of concepts necessary for modeling the three levels. Some of them are already known, whereas others are new and are proposed as an element of this work. we illustrate our proposal with a real case study in the Pharmacy Inventory Management.     

Lossless,Passive Transportation of Low Surface Tension Liquids Induced by Patterned Omniphobic Liquidlike Polymer Brushes

Surfaces enabling directional liquid transportation are of great interest for a wide range of applications such as water collection, microfluidics, and heat transfer systems. Surfaces capable of lossless, long-range passive transportation of low surface tension (LST) liquids using wettability patterned, liquidlike coatings with minimal contact angle hysteresis are reported. Lossless LST droplet travel distances over 150 mm are achieved, enabled by a two-phase transportation mechanism: morphological transformation from a bulge to a channel shape, followed by directional transportation along the asymmetrical wedge-shaped channel. The developed surfaces can split, merge, and precisely transport various low-surface tension liquids, including alcohols, alkanes, and solvents. The developed transportation strategy can also enhance LST liquid dropwise condensation through continuous removal of the condensate, even on horizontally positioned surfaces without the assistance of gravity.     

A hybrid multi-criteria decision-making model for firms competence evaluation

In this paper, we present a hybrid multi-criteria decision-making (MCDM) model to evaluate the competence of the firms. According to the competence-based theory reveals that firm competencies are recognized from exclusive and unique capabilities that each firm enjoy in marketplace and are tightly intertwined within different business functions throughout the company. Therefore, competence in the firm is a composite of various attributes. Among them many intangible and tangible attributes are difficult to measure. In order to overcome the issue, we invite fuzzy set theory into the measurement of performance. In this paper first we calculate the weight of each criterion through adaptive analytic hierarchy process (AHP) approach (A³) method, and then we appraise the performance of firms via linguistic variables which are expressed as trapezoidal fuzzy numbers. In the next step we transform these fuzzy numbers into interval data by means of α-cut. Then considering different values for α we rank the firms through TOPSIS method with interval data. Since there are different ranks for different α values, we apply linear assignment method to obtain final rank for alternatives.     

Novel nano polymeric system containing biosynthesized core shell silver/silica nanoparticles for functionalization of cellulosic based material

An innovative strategy for functional finishing of cellulosic based materials is based on the incorporation of a thin layer of surface modifying systems (SMS) in the form of stimuli-sensitive nanogels containing combining metal nanoparticles and silica. The silver–silica core–shell nanoparticles (NPs) were synthesized by simple one pot chemical method. Silica/silver nanoparticles have been synthesized using low concentration of dextran as reducing and stabilizing agent and using ascorbic acid as antioxidant agent. The core–shell NPs were characterized for their structural, morphological, compositional and optical behaviour using X-ray diffraction, scanning electron microscopy and energy dispersive X-ray analysis. Stimuli-responsive nanogel was prepared by copolymerization of poly(N-isopropylacrylamide) with pullulan, results in a nanogel that is responsive to both temperature and pH, the nano-particulate hydrogel of poly-NiPAAm-pullulan copolymer was synthesized using surfactant-free emulsion method. The prepared nano-particles were used during the preparation steps of the pullulan nanogel to obtain nanogel/combining metal/silica NPs to produce a composite materials. The nanoparticle size in dry (collapsed) state is estimated at 250 nm by SEM and TEM, and effect of temperature and pH on gel-nanoparticles was investigated by DLS and UV–vis spectrophotometry. The incorporation of the nanoparticles to cellulosic material was done by a simple pad dry-cure procedure from aqueous nanoparticle dispersion that contained a cross-linking agent. This application method provided sufficient integrity to coating by maintaining the responsiveness of surface modifying system. The stimuli responsiveness of modified cellulosic materials has been confirmed in terms of regulating its water uptake in dependence of pH and temperature.     

A soft robotics nonlinear hybrid position/force control for tendon driven catheters

Minimally invasive steerable catheters, commonly implemented in cardiac ablation, are currently operated by interventionalists exposing them to X-ray radiation and requiring the dexterity for accurate steering. To conduct robot-assisted cardiac ablation, highly accurate stable control platform for precise force/position control on the moving tissue is required. This paper introduces hybrid force/position control strategy to apply a constant force to the cardiac tissue while tracking the desired trajectory. The position controller is based on a nonlinear model predictive tracking control satisfying the input constraints. Cosserat rod theory is incorporated for the distal shaft modeling of tendon-driven catheters, and the model is reformulated for controller design and stability proof. Lyapunov-based stability analysis is conducted. To apply the controller, the force-displacement mapping of the cardiac tissue is obtained through ex vivo experimental tests. The performance of the controller is evaluated, and the catheter is capable of regulating the force with the RMSE of 4.9 mN and tracking the position with the RMSE of 0.89 mm. The promising results verify the potential of the application of the introduced approach in real applications including in vitro and clinical cardiac ablation.     

Modeling industrial thickener using computational fluid dynamics (CFD), a case study: Tailing thickener in the Sarcheshmeh copper mine

Separation of particles from liquid in the large gravitational tanks is widely used in mining and industrial wastewater treatment process. Thickener is key unit in the operational processes of hydrometallurgy and is used to separate solid from liquid. In this study, population balance models were combined with computational fluid dynamics (CFD) for modeling the tailing thickener. Parameters such as feed flow rate, flocculant dosage, inlet solid percent and feedwell were investigated. CFD was used to simulate the industrial tailing thickener with settled bed of 120 m diameter which is located in the Sarcheshmeh copper mine. Important factor of drag force that defines the rake torque of rotating paddles on the bed was also determined. Two phases turbulence model of Eulerian/Eulerian in accordance with turbulence model of k-ε was used in the steady-state. Also population balance model consists of 15 groups of particle sizes with Luo and Lehr kernel was used for aggregation/breakage kernel. The simulation results showed good agreement with the operational data.     

The diversity and distribution of freshwater macrophytes in the wedian of the mountainous northern Oman

The paper reports the first study of diversity and distribution of freshwater macrophytes in the wedian (plural of wadi = seasonal river) of the northern Al Hajar Mountain range in Oman. Fifteen lentic habitats in the wedian were surveyed. The number of species, their growth forms and abundance were recorded in the studied habitat of each wadi. In all, 41 species belonging to 14 families and 32 genera were collected. Of these 37 species were emergent and four were submergent. Poaceae was the most diverse emergent family with 17 species. Phragmites australis was the most common emergent followed by Typha domingensis. Among submerged macrophytes, Chara vulgaris had higher frequency of occurrence with low abundance followed by Potamogeton distinctus with relatively high abundance. Floristic diversity was estimated using species richness (Margalef’s D), general diversity (Shannon–Wiener H′), evenness (Pielous’s EH), and dominance (Berger–Parker d) indices for each study habitat. Principal component analysis was used to evaluate the variability using four indices. PC1 and PC2 explained 98.18% of the variability. Some habitats in different watersheds exhibited similar species diversity, but some in the same watershed were different. Baseline data on the freshwater macrophytes in northern Oman are provided here.     

Error from Delay Drift in Terahertz Attenuated Total Reflection Spectroscopy

In this article we discuss the influence of temporal stability on the value obtained for dielectric properties of materials measured by terahertz time-domain spectroscopy with particular emphasis on attenuated total reflection. The stability of three different terahertz attenuated total reflection spectroscopy systems is carefully characterized. The formalism for the complex refractive index extraction is presented and the effect of delay errors is calculated numerically. We found that good thermal stability of the terahertz system helps to minimize delay fluctuations and therefore the uncertainty of the resulting complex refractive index.