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1.
Modeling of stress and electromigration at the microscopic level, in confined interconnect metallic lines with tungsten studs, can very well account for the resistance behaviour in time. The resistance change at saturation for a metallic line with blocking boundaries at both ends can be related, according to the model, to threshold product (jL)c found by Blech [1]. 相似文献
2.
Summary A mathematical model for the solidification process of a melted film coating a spherical particle plunged in an immobile fluid is presented. This model may be used in order to determine temperature distribution in the vicinity of the particle. The results obtained using a melted sulphur thin film cooled with air are consistent with the data available in literature. 相似文献
3.
Bianca Stoean Dumitrita Rugina Monica Focsan Ana-Maria Craciun MÎdÎlina Nistor Tamas Lovasz Alexandru Turza Ioan-Dan Porumb Emese Gl Castelia Cristea Luminita Silaghi-Dumitrescu Simion Astilean Luiza Ioana Gaina 《International journal of molecular sciences》2021,22(6)
We report here the synthesis and structural characterization of novel cationic (phenothiazinyl)vinyl-pyridinium (PVP) dyes, together with optical (absorption/emission) properties and their potential applicability as fluorescent labels. Convective heating, ultrasound irradiation and mechanochemical synthesis were considered as alternative synthetic methodologies proficient for overcoming drawbacks such as long reaction time, nonsatisfactory yields or solvent requirements in the synthesis of novel dye (E)-1-(3-chloropropyl)-4-(2-(10-methyl-10H-phenothiazin-3-yl)vinyl)pyridin-1-ium bromide 3d and its N-alkyl-2-methylpyridinium precursor 1c. The trans geometry of the newly synthesized (E)-4-(2-(7-bromo-10-ethyl-10H-phenothiazin-3-yl)vinyl)-1-methylpyridin-1-ium iodide 3b and (E)-1-methyl-4-(2-(10-methyl-10H-phenothiazin-3-yl)vinyl)pyridin-1-ium tetrafluoroborate 3a′ was confirmed by single crystal X-ray diffraction. A negative solvatochromism of the dyes in polar solvents was highlighted by UV-Vis spectroscopy and explanatory insights were supported by molecular modeling which suggested a better stabilization of the lowest unoccupied molecular orbitals (LUMO). The photostability of the dye 3b was investigated by irradiation at 365 nm in different solvents, while the steady-state and time-resolved fluorescence properties of dye 3b and 3a′ in solid state were evaluated under one-photon excitation at 485 nm. The in vitro cytotoxicity of the new PVP dyes on B16-F10 melanoma cells was evaluated by WST-1 assay, while their intracellular localization was assessed by epi-fluorescence conventional microscopy imaging as well as one- and two-photon excited confocal fluorescence lifetime imaging microscopy (FLIM). PVP dyes displayed low cytotoxicity, good internalization inside melanoma cells and intense fluorescence emission inside the B16-F10 murine melanoma cells, making them suitable staining agents for imaging applications. 相似文献
4.
Summary A mathematical model for the cooling process of a molten drop, falling freely in a fluid, is presented. This model is used to determine the duration of the cooling stage of an urea drop. The distribution of the temperature, as function of time and radius, is determined. 相似文献
5.
Gallo Linda C.; Bogart Laura M.; Vranceanu Ana-Maria; Matthews Karen A. 《Canadian Metallurgical Quarterly》2005,88(2):386
The current study used ecological momentary assessment to test several tenets of the reserve capacity model (L.C. Gallo & K. A. Matthews, 2003). Women (N = 108) with varying socioeconomic status (SES) monitored positive and negative psychosocial experiences and emotions across 2 days. Measures of intrapsychic and social resources were aggregated to represent the reserve capacity available to manage stress. Lower SES was associated with less perceived control and positive affect and more social strain. Control and strain contributed to the association between SES and positive affect. Lower SES elicited greater positive but not negative emotional reactivity to psychosocial experiences. Women with low SES had fewer resources relative to those with higher SES, and resources contributed to the association between SES and daily experiences. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
6.
This work continued our general research program on obtaining metallic cerium by electrodeposition from NaCeF4 dis-solved in different molten fluorides. The structure of NaCeF4 (cubic or hexagonal depe... 相似文献
7.
Mihail Elisa Lucica Boroica Bogdan Alexandru Sava Stefan Marian Iordache Ana-Maria Iordache Ileana Cristina Vasiliu Raluca Constantina Stefan Aurelian Catalin Galca Victor Kuncser Mihai Eftimie 《Journal of the American Ceramic Society》2020,103(7):3978-3990
This work is focused on investigation of thermal, structural, optical, magnetic, and magneto-optical properties of novel titanium phosphate-tellurite glass applied as Faraday rotators. The glass belonging to the system 35Li2O–10Al2O3–5TiO2–45P2O5–5TeO2 was prepared by a nonconventional wet route of raw materials processing, followed by melting-quenching-annealing steps. Some important physical properties of the investigated glass have been measured and calculated, providing knowledge related to glass compactness, electronic structure, glass forming capability, etc. XRD analysis evidenced an amorphous network structure of the investigated glass. The optical absorption in the Vis domain is mainly due to Ti3+ ions and Te2 clusters formed during the glass melting process. A relatively low optical absorption is noticed over 600 nm that activates a significant Faraday magneto-optical effect. Photoluminescence bands in the blue, red, and infrared domains are observed, caused by Te2 clusters formed during the glass melting process. The magnetization in dependency on applied magnetic field reveals a complex behavior of the glass, depending on temperature. Thus, it is found a ferromagnetic behavior up to 2000 Oe, a paramagnetic component up to 40 000 Oe, followed by a diamagnetic one over 40 000 Oe. Faraday rotation angle and Verdet constant values in the visible domain are correlated with the reduced TeO2 content of the glass. 相似文献
8.
Calin-Cristian Cormos Ana-Maria CormosLetitia Petrescu 《Chemical Engineering Research and Design》2014
Carbon capture and storage (CCS) technologies are expected to play a significant role in the coming decades for curbing the greenhouse gas emissions and to ensure a sustainable development of power generation and other energy-intensive industrial sectors. Chemical looping systems are very promising options for intrinsically capture CO2 with lower cost and energy penalties. Gasification offers significant advantages compared with other technologies in term of lower energy and cost penalties for carbon capture, utilization of wide range of fuels, poly-generation capability, plant flexibility, lower environmental impact, etc. 相似文献
9.
10.
Christos G. Papadimitriou Anna Vafopoulou-Mastrojiannaki Sofia Vieira Silva Ana-Maria Gomes Francisco Xavier Malcata Efstathios Alichanidis 《Food chemistry》2007,105(2):647-656
Two sets of traditional Greek sheep milk yoghurt were produced: the first one (YC) using normal yoghurt culture (Lactobacillus delbrueckii subsp. bulgaricus ?10.13 and Streptococcus thermophilus ?10.7) and the second (PR) with the same normal culture mixed with Lactobacillus paracasei subsp. paracasei DC412. YC and PR had similar physicochemical properties and proteolysis patterns throughout storage. Both products showed similar peptide profiles by RP-HPLC but quantitative differences were observed in respect to storage time. Single-strain cultures of the microorganisms used showed similar peptide profiles for both lactobacilli, yet L. delbrueckii subsp. bulgaricus was the most proteolytic of all three microorganisms. The peptide content and the ACE-inhibitory activity of the water-soluble extracts of yoghurts, YC and PR, increased throughout storage. Major peptides were identified from yoghurt PR and from the separate cultures of L. delbrueckii subsp. bulgaricus and L. paracasei subsp. paracasei. Most of these peptides were derived from β-casein. A peptide, β-CN f114-121, with well-established ACE-inhibitory and opiate-like activity was identified in yoghurt PR. Further identified peptides were regarded as potential ACE-inhibitors according to their sequence. 相似文献