Infrared absorption in Li-intercalated tungsten oxide

Thin films of amorphous and polycrystalline tungsten oxide were produced by reactive dc magnetron sputtering and nanocrystalline films were deposited by advanced gas evaporation. The films were submitted to electrochemical intercalation of Li ions before infrared reflectance measurements were carried out. For crystalline films, the reflectance in the wavelength region 10–30 μm increases upon intercalation, indicating an increasing free-electron contribution. On the other hand, all the films display an increased absorption at wavelengths less than 10 μm when intercalated. The thermal emittance could be varied from about 0.5 to 0.7–0.75 by intercalation in films with thicknesses in excess of 1 μm. Both absorption and interference contribute to the emittance contrast.     

Amperometric biosensor for formic acid in air

The possibility of developing a simple, inexpensive and specific personal passive “real-time” air sampler incorporating a biosensor for formic acid was investigated. The sensor is based on the enzymatic reaction between formic acid and formate dehydrogenase (FDH) with nicotinamide adenine dinucleotide (NAD⁺) as a co-factor and Meldola's blue as mediator. An effective way to immobilise the enzyme, co-factor and Meldola's blue on screen-printed, disposable, electrodes was found to be in a mixture of glycerol and phosphate buffer covered with a gas-permeable membrane. Steady-state current was reached after 4–15 min and the limit of detection was calculated to be below 1 mg/m³. However, the response decreased by 50% after storage at −15°C for 1 day.     

New method for selectivity enhancement of SiC field effect gas sensors for quantification of NO x

A silicon carbide based enhancement type metal insulator field effect transistor with porous gate metallization has been investigated as a total NO _x sensor operated in a temperature cycling mode. This operating mode is quite new for gas sensors based on the field effect but promising results have been reported earlier. Based on static investigations we have developed a suitable T-cycle optimized for NO _x detection and quantification in a mixture of typical exhaust gases (CO, C₂H₄, and NH₃). Significant features describing the shape of the sensor response have been extracted and evaluated with multivariate statistics (e.g. linear discriminant analysis) allowing quantification of NO _x . Additional cleaning-cycles every 30?min improve the stability of the sensor further. With this kind of advanced signal processing the influence of sensor drift and cross sensitivity to ambient gases can be reduced effectively. Measurements have proven that different concentrations of NO _x can be detected even in a changing mixture of other typical exhaust gases under dry and humid conditions. In addition to that, unknown concentrations of NO _x can be detected based on a small set of training data. It can be concluded that the performance of GasFETs for NO _x determination can be enhanced considerably with temperature cycling and appropriate signal processing.     

A constraint-based variability modeling framework

Constraint-based variability modeling is a flexible, declarative approach to managing solution-space variability. Product variants are defined in a top-down manner by successively restricting the admissible combinations of product artifacts until a specific product variant is determined. In this paper, we illustrate the range of constraint-based variability modeling by discussing two of its extreme flavors: constraint-guarded variability modeling and constraint-driven variability modeling. The former applies model checking to establish the global consistency of product variants which are built by manual specification of variations points, whereas the latter uses synthesis technology to fully automatically generate product variants that satisfy all given constraints. Each flavor is illustrated by means of a concrete case study.     

The effect of microencapsulated phase change materials on the rheology of geopolymer and Portland cement mortars

The effect of microencapsulated phase-change materials (MPCM) on the rheological properties of pre-set geopolymer and Portland cement mortars was examined. Microcapsules with hydrophilic and hydrophobic shells were compared. The shear rate dependency of the viscosities fitted well to a double Carreau model. The zero shear viscosities are higher for geopolymer mortar, illustrating poorer workability. The time evolution of the viscosities was explored at shear rates of 1 and 10 s⁻¹. New empirical equations were developed to quantify the time-dependent viscosity changes. The highest shear rate disrupted the buildup of the mortar structures much more than the lower shear rate. Microcapsules with a hydrophobic shell affect the rheological properties much less than the microcapsules with a hydrophilic shell, due to the higher water adsorption onto the hydrophilic microcapsules. Shear forces was found to break down the initial structures within geopolymer mortars more easily than for Portland cement mortars, while the geopolymer reaction products are able to withstand shear forces better than Portland cement hydration products. Initially, the viscosity of geopolymer mortars increases relatively slowly during due to formation of geopolymer precursors; at longer times, there is a steeper viscosity rise caused by the development of a 3D-geopolymer network. Disruption of agglomerates causes the viscosities of portland cement mortars to decrease during the first few minutes, after which the hydration process (increasing viscosities) competes with shear-induced disruption of the structures (decreasing viscosities), resulting in a complex viscosity behavior.     

Polychlorinated naphthalenes in Swedish background air

Polychlorinated naphthalenes (PCNs) with four to eight chlorines were studied in air collected at two background stations in Sweden, one southerly and one northerly. Air was sampled with a high-volume sampler, and gas-phase adsorbents and filters were analyzed separately. The sum of TeCNs to HxCNs in the gaseous phase ranged between 1 and 10 pg/m3 with significantly higher concentrations at the southern location Hoburgen. HpCNs and OCN were below the detection limit. The highest concentrations were found in two samples from Hoburgen with the air masses coming from SW and W and during warm weather (+11 degrees C). The lowest concentration was found in a sample from the northern location Ammarn?s at cold weather (-22 degrees C) when the air came from the east. A correlation was found between logP and 1/T indicating that temperature has a larger effect than location on the concentration in the gas phase. The TeCNs constituted 50-75% in the gaseous phase. In most filter samples TeCNs and PeCNs were below the limit of quantitation. PUF samples with air trajectories from W to NE had relatively higher concentrations of late eluting TeCNs and PeCNs, while in samples with winds from SE to S the early eluting congeners dominated. Samples with early eluting congeners were mainly collected at lower temperature. TriCNs constituted the dominant homologue group both in the gaseous and particulate phase of air samples as well as in bulk deposition from a rural monitoring station south of Stockholm. The octanol-air partition coefficient described the gas/particle interaction well for samples collected at temperatures down to -8 degrees C.     

Effect of surfactant concentration, pH, and shear rate on the rheological properties of aqueous systems of a hydrophobically modifed chitosan and its unmodified analogue

Oscillatory shear, shear relaxation and viscosity experiments have been carried out on semidilute solutions of chitosan and on a hydrophobically modified analogue (HM-chitosan) in 1% acetic acid. This was done in the presence of various amounts of cetyltrimethylammonium bromide (CTAB) and at different pH values. All the rheological measurements on the HM-chitosan solutions revealed significant polymer-surfactant interaction and pH effects. The observed rheological effects were least pronounced at pH ≈ 4, while a strong viscoelastic response was found at pH values of 1 and 5 in HM-chitosan solutions of low surfactant concentration. At these conditions, significant shear-thinning effects were observed. In semidilute solutions of unmodified chitosan, the influence of pH, surfactant concentration and shear rate on the rheological properties was moderate or insignificant. Received: 25 September 1996/Revised version: 30 October 1996/Accepted: 4 November 1996     

Evaluation of on-line flue gas measurements by MISiCFET and metal-oxide sensors in boilers

Metal insulator silicon carbide field-effect transistor sensors, metal-oxide sensors, and a linear Lambda sensor in an electronic nose was used to measure on-line in hot flue gases from a boiler. Flue gas from a 100-MW pellets-fuelled boiler has been used to feed the experimental setup. Several reference instruments, which measure the flue gases in parallel to the sensor array, are connected to the electronic nose. Data was collected during six weeks and then evaluated. Using principal component analysis as the data evaluation method, different operating modes for the boiler have been identified in the data set. The different modes could be described in terms of high or low O/sub 2/ and CO concentration. Furthermore, we have shown that it seems possible to use a sensor array to determine the operating mode of the boiler and, by partial least-squares models, measure the CO concentration when the boiler operates in its optimum mode.