Highly Efficient Quasi 2D Blue Perovskite Electroluminescence Leveraging a Dual Ligand Composition

Perovskite light-emitting diodes (PeLEDs) are advancing because of their superior external quantum efficiencies (EQEs) and color purity. Still, additional work is needed for blue PeLEDs to achieve the same benchmarks as the other visible colors. This study demonstrates an extremely efficient blue PeLED with a 488 nm peak emission, a maximum luminance of 8600 cd m⁻², and a maximum EQE of 12.2% by incorporating the double-sided ethane-1,2-diammonium bromide (EDBr₂) ligand salt along with the long-chain ligand methylphenylammonium chloride (MeCl). The EDBr₂ successfully improves the interaction between 2D perovskite layers by reducing the weak van der Waals interaction and creating a Dion–Jacobson (DJ) structure. Whereas the pristine sample (without EDBr₂) is inhibited by small stacking number (n) 2D phases with nonradiative recombination regions that diminish the PeLED performance, adding EDBr₂ successfully enables better energy transfer from small n phases to larger n phases. As evidenced by photoluminescence (PL), scanning electron microscopy (SEM), and atomic force microscopy (AFM) characterization, EDBr₂ improves the morphology by reduction of pinholes and passivation of defects, subsequently improving the efficiencies and operational lifetimes of quasi-2D blue PeLEDs.     

Internal electrical fault detection techniques in DFIG-based wind turbines: a review

The keys factor in making wind power one of the main power sources to meet the world’s growing energy demands is the reliability improvement of wind turbines (WTs). However, the eventuality of fault occurrence on WT com ponents cannot be avoided, especially for doubly-fed induction generator (DFIG) based WTs, which are operating in severe environments. The maintenance need increases due to unexpected faults, which in turn leads to higher operating cost and poor reliability. Extensive investigation into DFIG internal fault detection techniques has been carried out in the last decade. This paper presents a detailed review of these techniques. It discusses the methods that can be used to detect internal electrical faults in a DFIG stator, rotor, or both. A novel sorting technique is presented which takes into consideration different parameters such as fault location, detection technique, and DFIG modelling. The main mathematical representation used to detect these faults is presented to allow an easier and faster under standing of each method. In addition, a comparison is carried out in every section to illustrate the main differences, advantages, and disadvantages of every method and/or model. Some real monitoring systems available in the market are presented. Finally, recommendations for the challenges, future work, and main gaps in the field of internal faults in a DFIG are presented. This review is organized in a tutorial manner, to be an effective guide for future research for enhancing the reliability of DFIG-based WTs.     

Flow simulations in arbitrarily complex cardiovascular anatomies – An unstructured Cartesian grid approach

Image guided computational fluid dynamics is attracting increasing attention as a tool for refining in vivo flow measurements or predicting the outcome of different surgical scenarios. Sharp interface Cartesian/Immersed-Boundary methods constitute an attractive option for handling complex in vivo geometries but their capability to carry out fine-mesh simulations in the branching, multi-vessel configurations typically encountered in cardiovascular anatomies or pulmonary airways has yet to be demonstrated. A major computational challenge stems from the fact that when such a complex geometry is immersed in a rectangular Cartesian box the excessively large number of grid nodes in the exterior of the flow domain imposes an unnecessary burden on both memory and computational overhead of the Cartesian solver without enhancing the numerical resolution in the region of interest. For many anatomies, this added burden could be large enough to render comprehensive mesh refinement studies impossible. To remedy this situation, we recast the original structured Cartesian formulation of Gilmanov and Sotiropoulos [Gilmanov A, Sotiropoulos F. A hybrid Cartesian/immersed boundary method for simulating flows with 3D, geometrically complex, moving bodies. J Comput Phys 2005;207(2):457–92] into an unstructured Cartesian grid layout. This simple yet powerful approach retains the simplicity and computational efficiency of a Cartesian grid solver, while drastically reducing its memory footprint. The method is applied to carry out systematic mesh refinement studies for several internal flow problems ranging in complexity from flow in a 90° pipe bend to flow in an actual, patient-specific anatomy reconstructed from magnetic resonance images. Finally, we tackle the challenging clinical scenario of a single-ventricle patient with severe arterio-venous malformations, seeking to provide a fluid dynamics prospective on a clinical problem and suggestions for procedure improvements. Results from these simulations demonstrate very complex cardiovascular flow dynamics and underscore the need for high-resolution simulations prior to drawing any clinical recommendations.     

Roll bonding of AA5052 and polypropylene sheets: Bonding mechanisms,microstructure and mechanical properties

Structural, microstructural and mechanical properties in roll bonding of AA5052 and polypropylene sheets have been evaluated in this study. The surface roughness of the AA5052 sheets, rolling temperature and the surface energy of polymer were selected as the bonding variables. The findings indicated that an increase in the surface energy of polypropylene by grafting maleic anhydride would result in higher bonding strength due to chemical interaction between the AA5052 and the maleic anhydride grafted polypropylene (PP-g-MAH). In fact, this reaction caused the formation of an interphase layer at the polymer side of the interface and the diffusion of aluminum into the PP-g-MAH layer. It was also observed that an increase in the rolling temperature increases bonding strength because the polymer penetrates the AA5052 surface irregularities more easily, the PP-g-MAH molecules move more smoothly toward the AA5052 surface, and finally there are more chemical interactions among the layers. An Increase in the bonding strength through increasing the AA5052 surface roughness was attributed to an increase of the van der Waals force and more interaction surface among the layers along with higher mechanical interlocking in the shear tension test.     

Application of mesoporous magnetic carbon composite for reactive dyes removal: Process optimization using response surface methodology

Discharging the effluents of textile wastewaters into potable water resources can endanger the ecosystem, due to their reactivity, toxicity, and chemical stability. In this research, the application of powder activated carbon modified with magnetite nanoparticles (PAC-MNPs) as an adsorbent for removal of reactive dyes (Reactive black 5 (RB5) and reactive red 120 (RR120)) was studied in a batch system. The adsorption performance was evaluated as a function of temperature, contact time and different adsorbent and adsorbate concentrations. The levels of factors were statistically optimized using Box-Behnken Design (BBD) from the response surface methodology (RSM) to maximize the efficiency of the system. The adsorption process of both dyes was fit with the pseudo-second order kinetic and Langmuir isotherm models. The identified optimum conditions of adsorption were 38.7 °C, 46.3 min, 0.8 g/L and 102 mg/L for temperature, contact time, adsorbent dose, and initial dyes concentration, respectively. According to the Langmuir isotherm, the maximum sorption capacities of 175.4 and 172.4 mg/g were obtained for RB5 and RR120, respectively. Thermodynamics studies indicated that the adsorption process of the reactive dyes was spontaneous, feasible, and endothermic. After five cycles, the adsorption efficiency was around 84 and 83% for RB5 and RR120, respectively. A high value of desorption was achieved, suggesting that the PAC-MNPs have a good potential in regeneration and reusability, and also can be effectively utilized in industrial applications. PAC-MNPs also show a good anti-interference potential for removal of reactive dyes in dye-industry wastewaters.     

Multi-Objective Optimization Model for the Allocation of Water Resources in Arid Regions Based on the Maximization of Socioeconomic Efficiency

The escalating world population has led to a drastic increase in water demand in the municipal and drinking water, agriculture and industry sectors. This situation necessitates application of effective measures for the optimal and efficient management of water resources. With this respect, a two-objective socioeconomic model (aimed at job creation) has been presented in this study for the optimum allocation of water resources to industry, agriculture and municipal water sectors. In the agriculture sector, the production function of each product has been determined and then, based on the production functions, areas under cultivation, product yield and the income obtained from each product, the combined objective function has been specified. In the industry sector, since water demand is a function of the amount of produced products, price of supplied water and the price of other supplies, the demand function of this sector was determined regionally. Also, considering the existing necessity in meeting the municipal water requirement, the total amount of water needed by this sector was fully allocated. Then by using two meta-heuristic algorithms, i.e. genetic algorithm (GA) and particle swarm optimization (PSO), the objective functions were maximized and the water resources were optimally allocated between agriculture and industry sectors and the results were compared. Ultimately, comparing the results gained by PSO and GA algorithms, PSO with an economic and profit growth of 54 % and a 13 % rise in employment relative to the base condition, turned out to be more efficient in this application.     

Analytical solutions for one-phase seepage flows impeded by wellbore seals

Steady, one-phase, plane and axisymmetric, Darcian seepage in a homogeneous rock adjacent to a partly isolated wellbore with annular seals is analytically studied. Water flows from an isobaric feeding contour and a fracture, which is kept at the same pressure as the feeding contour, to a wellbore. Partial isolation of the wellbore makes its wall a composition of intermittently arrayed no-flow boundaries, which model the wellbore seals, and isobaric surfaces, which model the annular compartments between the seals and a wellbore tubular on which the seals are mounted. Pressure drops from the aquifer (fracture) to the compartments and further to the borehole that generates a hierarchy of flows mathematically equivalent to the Toth [Freeze, R.A., Cherry, J.A., 1979. Groundwater. Prentice Hall, Englewood Cliffs] hydrogeological patterns of regional, intermediate and local groundwater flows on the scale of catchments. Conformal mappings of complex potential domains onto physical planes, where water seepage takes place, are used to tackle the fragments of the full feeding contour-fracture–sealed wellbore system. Explicit rigorous solutions for the flow characteristics (pressure and stream function) enable calculating optimal wellbore isolation with a criterion of minimal water flow rate from the fracture.     

The role of electrolyte concentration on crevice corrosion of pure nickel

In this work an artificial crevice electrode was used in conjunction with a fine microprobe assembly to measure the potential inside the crevice. Using this setup crevice corrosion of commercially pure nickel was investigated in sulfuric acid with concentrations: 0.5, 1 and 2N. The outer surface of the Ni was held at a passive potential of 530 mV(SCE) while the experiment was running. The results showed a steep potential decay observed in all concentrations. For 0.5, 1 and 2N H₂SO₄, the total potential drop inside the crevice was: 681, 619 and 593 mV, respectively. This indicates the higher the acid concentration is the lower the potential drop will be. On the other hand, the measured current was highest (4.09 mA) for 2N and lowest (1 mA) for 0.5N. On the crevice wall a boundary was found to exist between the passive and the active regions. These findings point toward the IR voltage drop mechanism operating for this system.