Conducting composites of polythiophene and polyfuran with acetylene black

Conducting composites of polythiophene (PTP) and polyfuran (PF) with acetylene black (AB) were prepared via chemical oxidative polymerization of thiophene and furan in a suspension of AB in CHCl₃ at room temperature using anhydrous FeCl₃ as the oxidant. Formation of PTP and PF and their subsequent incorporation in PTP–AB and PF–AB composite systems were confirmed by FTIR analysis. Scanning electron microscope analysis showed the presence of compact clusters of particles in both composites. Transmission electron micrographs of PTP–AB and PF–AB composites showed formation of globular polymer encapsulated AB particles with average diameters of the order of ～100 nm in both systems. Thermogravimetric analysis revealed that the overall thermal stability varied in the order: AB > PTP–AB > PTP and AB > PF–AB > PF. DC conductivity values for the PTP–AB and PF–AB composites were of the order of 10^?2 and 10^?3 S cm^?1, respectively. Copyright © 2004 Society of Chemical Industry     

Initiation of air core in a swirl nozzle using time-independent power-law fluids

Summary Theoretical and experimental analyses have been carried out for determining the injection condition below which the formation of air core does not take place in the course of flow of a time-independent power-law fluid through a swirl nozzle. Analytical solution lends one distinct value of generalized Reynolds number at the inlet to a nozzle below which the air core is not formed. Experiments reveal that there exist two limiting values of such generalized Reynolds number regarding the formation of air core in a nozzle. One value being the upper limit below which steady flow occurs without air core, the other one is the lower limit above which steady flow with fully developed air core persists. In between these two limiting values, there prevails a transition zone through which fully developed air core is set up within the nozzle. For all the nozzles, theoretical results are in fair agreement with the experimental values of upper limit of generalized Reynolds numbers with respect to steady flow without air core. Amongst all the pertinent independent geometrical parameters of a nozzle, the orifice-to-swirl chamber-diameter ratio has the remarkable influence on generalized Reynolds number describing the initiation of air core.Nomenclature D ₁ Swirl chamber diameter - D ₂ Orifice diameter - D _s Diameter of tangential entry ports - E A non-dimensional parameter defined by Eq. (9) - E _R A non-dimensional parameter defined by Eq. (25) - K Flow consistency index - L ₁ Length of the swirl chamber - n Flow behaviour index - P Static pressure inside the nozzle - P _b Back-pressure of the nozzle - Q Volume flow rate - R Radius vector or longitudinal coordinate with respect to spherical coordinate system (Fig. 3) - R ₁ Radius of the swirl chamber - R ₂ Radius of the orifice - Generalized Reynolds number at the inlet to the nozzle - Limiting value of generalized Reynolds number describing initiation of air core - R _z Radius at any section - r Radial distance from the nozzle axis - r _a Air core radius - u Longitudinal component of velocity with respect to spherical coordinate system (Fig. 3) - V _r Radial velocity component - V _z Axial velocity component - V Tangential velocity component - Tangential velocity at inlet to the nozzle - v Component of velocity in the axial plane perpendicular toR (Fig. 3) - w Component of velocity perpendicular to axial plane with respect to the spherical coordinate system (Fig. 3) - z Distance along the nozzle axis from its inlet plane - Half of the spin chamber angle - Boundary layer thickness measured perpendicularly from the nozzle wall - ₂ Boundary layer thickness at the orifice - Angle, which a radius vector makes with the nozzle axis, in spherical coordinate system (Fig. 3) - Density of the fluid - Running coordinate in the azimuthal direction with respect to the cylindrical polar coordinate system as shown in Fig. 3 - Circulation constant With 8 Figures     

Electrical properties of vanadium pentoxide doped with lithium and sodium in the α-phase range

The electrical conductivity and Seebeck coefficients have been measured from room temperature to 500° C for polycrystalline V₂O₅ and V₂O₅ doped with lithium and sodium in the -phase range. The conductivity increases with doping and the energy of activation decreases. The Seebeck coefficient indicates that electrons are the majority carriers. The results have been discussed in terms of the two-level hopping model.     

Characteristics of p-Ge/N-GaAs heterojunctions grown by molecular beam epitaxy

Reports the nearly ideal electrical characteristics of p-Ge/N-GaAs heterojunction diodes grown by molecular beam epitaxy. The temperature and device size dependencies of the current-voltage characteristics have been investigated. At room temperature, unity ideality factor has been demonstrated over almost six decades of current.<>     

The cluster scanning system

Users with severe physical impairment often use computers with one or two switches using a scanning system. Scanning is a technique of successively highlighting portions of screen. This paper presents a new scanning system that works through clustering screen objects. The system is initially calibrated through simulation and later validated through a user trial. Results show that it outperforms existing block scanning systems.     

Effect of dysprosia doping on structural and electrical property of stabilized zirconia for intermediate- temperature SOFCs

Present work deals with structural, micro-structural and electrical properties of dysprosia stabilized zirconia electrolyte, which have been evaluated by means of X-ray diffraction (XRD) and scanning (SEM), and complex impedance analysis respectively. The amount of dysprosia was varied from 2 to 12 mol% in zirconia. The addition of dysprosia (8-12 mol%) stabilized the cubic zirconia phase, which was analyzed from XRD analysis. SEM micrographs clearly showed the improvement in sinterability with increase in dysprosia concentration up to 6 mol% disprosia. Complex impedance analysis was performed in the temperature range from 250 to 600 °C. The results indicated a gradual decrease in impedance of both bulk and grain boundary and increase in conductivity with dysprosia doping up to 6 mol% and thereafter showing a reverse trend. The activation energies for oxygen ion migration were also found to decrease with increase in dysprosia doping which was in the range of 0.99 ? 1.28 eV. The average thermal expansion coefficient increases linearly.     

Multiple material domain‐based computational tools for ease assessment of modal parameter in photonic crystal fibers

We report here the development of two computational tools PCFPS (Photonic Crystal Fiber Parameter Study) and PCFPA (Photonic Crystal Fiber Parameter Analysis), equipped with graphical user interface (GUI) for modeling of photonic crystal fiber. The tools are based on different structural parameters, and they provide characteristic analysis of the modal parameters from the structural parameters. The main feature of PCFPS is that it enables the user to find out the values of each defining modal parameter that has an immense contribution towards the manufacture of photonic crystal fiber. Additionally, PCFPA allows the user to observe the variation in the modal parameters with respect to the changes in structural parameters (such as d, Λ, d/Λ, and λ/>Λ). Besides their ease of use, these two schemes have high computational precision and adaptability, giving a novel platform to optical engineers to modulate the microstructured fibers according to their requirement.     

Attribute Allocation and Retrieval Scheme for Large-Scale Sensor Networks

Wireless sensor network is an emerging technology that enables remote monitoring of large geographical regions. In this paper, we address the problem of distributing attributes over such a large-scale sensor network so that the cost of data retrieval is minimized. The proposed scheme is a data-centric storage scheme where the attributes are distributed over the network depending on the correlations between them. The problem addressed here is similar to the Allocation Problem of distributed databases. In this paper, we have defined the Allocation Problem in the context of sensor networks and have proposed a scheme for finding a good distribution of attributes to the sensor network. We also propose an architecture for query processing given such a distribution of attributes. We analytically determine the conditions under which the proposed architecture is beneficial and present simulation results to demonstrate the same. To the best of our knowledge, this is the first attempt to determine an allocation of attributes over a sensor network based on the correlations between attributes.     

In-Flight Synthesis of Core–Shell Mg/Si–SiOx Particles with Greatly Reduced Ignition Temperature

Magnesium is a promising candidate as a solid fuel for energetic applications, however, the diffusion-controlled oxidation mechanism impedes its reaction with an oxidizer, often resulting in diminished performance. In this study, non-thermal plasma processing is implemented to modify the surface of magnesium nanoparticles with silicon in-flight, in the gas-phase to enhance the rate of interfacial reactions and tune the ignition pathways. Allowing the silicon coating to partially oxidize provides direct contact between the fuel and oxidizer, resulting in a nanostructured thermite system at the single particle level. The proximal distance between oxidizer and fuel directly impacts the ignition temperature and, therefore, the combustion kinetics. An intermetallic reaction occurs within the magnesium/silicon system to supplement the heating of the magnesium fuel to initiate its reaction with the oxidizer, resulting in highly reduced ignition thresholds. The ignition temperature is lowered significantly from ≈740 °C for magnesium particles with a native oxide layer to ≈520 °C for particles coated via the in-flight plasma process.     

A novel DSP‐based PFC‐DPLL with fuzzy controlled acquisition aid to improve acquisition performance and noise immunity

This paper proposes a new digital signal processing (DSP)‐based phase frequency controlled digital phase locked loop. Here, a very simplistic form of fuzzy logic controller with the help of carrier phase and frequency error as input data is used to provide an acquisition aid. A frequency discriminator is employed to generate frequency error, and phase detector output is taken for phase error. This addition of an acquisition aid helps the loop to achieve the minimum acquisition time and maximum noise rejection simultaneously. An additional phase control in the digitally controlled oscillator makes the loop perform even better towards this goal. The implementation of the proposed loop is carried out on a reconfigurable logic platform using System Generator^®;, a tool from Xilinx^®; used to design real‐time DSP application. A significant improvement of time domain characteristics are observed as well as the performance in presence of additive white Gaussian noise is demonstrated in terms of the reduction in steady‐state phase jitter and enhancement in output signal to noise ratio in the proposed loop. Copyright © 2014 John Wiley & Sons, Ltd.