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Electrical conduction in non-metallic rare-earth solids 总被引:1,自引:0,他引:1
Schematic energy band diagrams for the genesis of charge carriers in non-metallic rare-earth solids have been presented. It has been shown that positions of 4f bands have significant effect on the genesis and nature of charge carriers, their conduction mechanism and magnitude of electrical conductivity () and Seebeck coefficient (S) of the solid. Relevant relations have been given for both and S in different situations. Experimental data on rare-earth sesquioxides (R2O3), rare-earth tungstates [R2(WO4)3] and rare-earth molybdates [R2(MoO4)3] in the intrinsic range have been explained as examples for the validity of energy band diagrams. 相似文献
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The thermal degradation of cellulose and its phosphorylated products (phosphates, diethylphosphate, and diphenylphosphate) were studied in air and nitrogen by differential thermal analysis and dynamic thermogravimetry from ambient temperature to 750°C. From the resulting data various thermodynamic parameters were obtained following the methods of Broido and Freeman and Carroll. The values of Ea for decomposition for phosphorylated cellulose were found to be in the range 55–138 kJ mol?1 in air and 85–152 kJ mol?1 in nitrogen and depended upon the percent of phosphorus contents in the samples. The mass spectrum of cellobiose phosphate indicated the absence of the molecular ion, indicating that the compound was thermally unstable. The IR spectra of the pyrolysis residues of cellulose phosphate gave indication of formation of a compound having C?O and P?O groups. A fire retardancy mechanism for the thermal degradation of cellulose phosphate has been proposed. 相似文献
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Huifen Nie Minghai Li Rama Bansil estmír Kok Martin Helmstedt Jyotsana Lal 《Polymer》2004,45(26):8791-8799
We have examined solutions of a polystyrene-polybutadiene pentablock copolymer in n-heptane, a strongly selective solvent for polybutadiene. Small angle neutron scattering from 7 to 15% samples reveals domains about 10 nm in radius formed by the association of 200 polystyrene blocks. Dynamic light scattering measurements on 8 and 9% samples showed three modes: a fast diffusive mode related to the collective diffusion in semidilute solutions/gels; a relaxational mode related to the local dynamics of polystyrene domains trapped in the gel formed by bridging the domains with the polybutadiene chains; and a very slow diffusive mode. The relaxational dynamics persisted over the entire temperature range, becoming faster with increasing temperature, indicating a decreased microviscosity at higher temperatures. The slow dynamics seems to be connected with heterogeneities in the physical gel due to microsyneresis and almost disappeared above 50 °C. Macroscopic phase separation into two liquid phases was observed in a dilute solution of the un-associated copolymer, and into a liquid and gel phase at higher concentrations. The absence of flower-like micelles in dilute solutions and the macroscopic phase seperation suggest that the gels in the pentablock are formed by random association of multiplet domains and not by bridging of micellar domains. 相似文献
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IR absorption spectra of preoxidized PAN fibres have been studied in the spectral region 2–15 μ. Observed frequencies have been assigned to the different modes of vibration. The neighbouring frequencies appearing in the stretching mode region of the nitrile group has been interpreted in terms of Fermi-resonance and a basis for the correlation between their intensity ratio and the degree of oxidation has also been discussed. 相似文献