A 0.2-W Heterostructure Barrier Varactor Frequency Tripler at 113 GHz

We present a high-power InAlAs/InGaAs/InP heterostructure barrier varactor (HBV) frequency tripler. The HBV device topology was designed for efficient thermal dissipation and high efficiency. To verify simulations, the device was flip-chip soldered onto embedding microstrip circuitry on an aluminum nitride substrate. This hybrid circuit was then mounted in a waveguide block without any movable tuners. From the resulting RF measurements, the maximum output power was 195 mW at 113 GHz, with a conversion efficiency of 15%. The measured 3-dB bandwidth was 1.5%     

Equilibrium,kinetic and thermodynamic study of removal of reactive orange 12 on platinum nanoparticle loaded on activated carbon as novel adsorbent

The proposed research describes the synthesis and characterization of platinum nanoparticles loaded on activated carbon (Pt-NP-AC) and its efficient application as novel adsorbent for efficient removal of reactive orange 12 (RO-12). The influences of effective parameters following the optimization of variables on removal percentages, their value was set as 0.015 g Pt-NP-AC, pH 1, contact time of 13 min. At optimum values of all variables at 25 and 50 mgL⁻¹ of RO-12 enthalpy (ΔH⁰) and entropy (ΔS⁰) changes was found to be 59.89 and 225.076, respectively, which negative value of ΔG⁰ shows a spontaneous nature, and the positive values of ΔH⁰ and ΔS⁰ indicate the endothermic nature and adsorption organized of dye molecule on the adsorbent surface. Experimental data was fitted to different kinetic models including first-order, pseudo-second-order, Elovich and intra-particle diffusion models, and it was seen that the adsorption process follows pseudo-second-order model in consideration to intra-particle diffusion mechanism. At optimum values of all variables, the adsorption process follows the second-order kinetic and Langmuir isotherm model with adsorption capacity 285.143 mg g⁻¹ at room temperature.     

Investigation of chitosan‐g‐PEG grafted nanoparticles as a half‐life enhancer carrier for tissue plasminogen activator delivery

Tissue plasminogen activator (tPA) a thrombolytic agent is commonly used for digesting the blood clot. tPA half‐life is low (4–6 min) and its administration needs a prolonged continuous infusion. Improving tPA half‐life could reduce enzyme dosage and enhance patient compliance. Nano‐carries could be used as delivery systems for the protection of enzymes physically, enhancing half‐life and increasing the stability of them. In this study, chitosan (CS) and polyethylene glycol (PEG) were used for the preparation of CS‐g‐PEG/tPA nanoparticles (NPs) via the ion gelation method. Particles’ size and loading capacity were optimised by central composite design. Then, NPs cytotoxicity, release profile, enzyme activity and in vivo half‐life and coagulation time were investigated. The results showed that NPs does not have significant cytotoxicity. Release study revealed that a burst effect happened in the first 5 min and resulted in releasing 30% of tPA. Loading tPA in NPs could decrease 25% of its activity but the half‐life of it increases in comparison to free tPA in vivo. Also, blood coagulation time has significantly affected (p ‐value = 0.041) by encapsulated tPA in comparison to free tPA. So, CS‐g‐PEG/tPA could increase enzyme half‐life during the time and could be used as a non‐toxic candidate delivery system for tPA.Inspec keywords: drug delivery systems, nanofabrication, drugs, nanomedicine, coagulation, biomedical materials, cellular biophysics, enzymes, biochemistry, toxicology, molecular biophysics, biological tissues, blood, nanoparticles, polymersOther keywords: chitosan‐g‐PEG grafted nanoparticles, half‐life enhancer carrier, tissue plasminogen activator delivery, tPA half‐life, prolonged continuous infusion, enzyme dosage, polyethylene glycol, cytotoxicity, enzyme activity, encapsulated tPA, enzyme half‐life, blood coagulation, time 5.0 min     

Seismic performance evaluation of steel moment resisting frames through incremental dynamic analysis

Earthquake hazards effect significant damage to structures and cause widespread failure throughout buildings. Moment resisting frames are widely used as lateral resisting systems when sufficient ductility is to be met. Generally three types of moment resisting frames are designed in practice namely Special, Intermediate and Ordinary Moment Frames, each of which has certain level of ductility. Comparative studies on the seismic performance of these three different types of structure are performed in this study. Analytical models of connections are employed including panel zone and beam to column joint model. Incremental dynamic analysis is then utilized to assess the structural dynamic behavior of the frames and to generate required data for performance based evaluations. Maximum annual probability of exceeding different limit states may reveal the superiority of a ductile structure in which a greater behavior factor is employed. Special moment resisting frames are expected to perform better once a certain level of ductility is to be met but the amount of superiority may be the subject of investigation especially from a performance based design standpoint.     

The effect of nano-size additives on the electrical conductivity of matrix suspension and properties of self-flowing low-cement high alumina refractory castables

Influence of two nano-size additives on electrical properties of suspension matrix of self-flowing low-cement high alumina refractory castable is investigated. For this purpose, castament FS 10 and FS 20 on the basis of polycarboxylate ether were considered. The self-flow value, workability and mechanical strength of the castable are evaluated and their relations with electrical conductivity are determined. Using these relations, the type and optimum amount of proper additive for these refractory castables are determined. It was shown that if the electrical conductivity of matrix suspension is less than 0.71 mS/cm, high alumina low-cement self-flowing refractory castable can be obtained. The best self-flow, sufficient working time and adequate mechanical strength in the castables are obtained with 0.08 wt.% FS 20.     

Wideband radar cross section reduction using a novel design of artificial magnetic conductor structure with a triple‐layer chessboard configuration

A novel wideband three‐layer chessboard‐like structure is proposed to reduce the radar cross section (RCS) of the radar target. This configuration is composed of two artificial magnetic conductor (AMC) cells formed by two crossed ellipses with different sizes in two cells. A desired 180° ± 37° phase difference is achieved by combining these unit cells and the measured 10 dB RCS‐reduction bandwidth is extensively broadened to more than 96% (from 8.11 to 23.32 GHz, covering X, Ku, and K bands for different radars) in comparison with the other works. This characteristic is obtained by carefully adjusting the positions of all resonances using the proper sizes for the ellipses and the proper dielectric constants and thicknesses for the three layers. Although, the proposed design has three layers with the overall thickness of 2 mm, it is still thinner than most of the recent related works. This low‐profile structure is also cost‐effective due to the fact that 60% of the overall thickness is formed by an air substrate. The proposed cells are designed, simulated, and fabricated in a chessboard‐like configuration for both monostatic and bistatic RCSs. Simulations and measurements are in a good agreement, which shows the capabilities of the design.     

Fabrication and characterization of novel nanofibers from cress seed mucilage for food applications

Cress seed mucilage (CSM) as a new source of biomacromolecule has gained attraction in food science due to its biodegradability and biocompatibility. In this research CSM–poly(vinyl alcohol) (PVA) nanofibers were produced under different conditions by electrospinning technique. Viscosity and electrical conductivity of the produced biopolymers were analyzed. The effect of CSM to PVA volume ratio and applied electrical field were evaluated on nanofiber morphology by scanning electron spectroscopy. The optimum nanofibers showed smooth and uniform surfaces with diameter size range of 95–278 nm. The results of Fourier transform infrared spectroscopy of CSM–PVA nanofiber with volume ratio of 60:40 showed characteristic peaks of CSM and PVA. X‐ray diffractometer data clearly revealed the amorphous structure of the electrospun nanofibers. Thermogravimetric and derivative thermogravimetric analysis indicated that thermal stability of electrospun nanofibers increased in comparison to CSM and PVA. The results of this study indicated that CSM can be applied as a new source of biopolymer for production of nanofibers that could be used for different applications such as delivery systems and packaging film fabrication. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45811.     

Prediction of limiting drawing ratio considering the effective parameters of die arc region

In this paper an improved analytical method for estimating the limiting drawing ratio (LDR) for the first drawing stage is presented. In this method, the effects of parameters such as the geometry and the material properties of die arc region are taken into account for a more accurate determination of LDR. The results are compared to experiments and some other analytical methods reported in the literature. It is shown that the presented method is in good agreement with the experimental results and more accurate compared with other analytical methods. Using the presented method, the effect of some process parameters such as, coefficient of friction, strain hardening exponent, normal plastic anisotropy ratio, ratio of die arc radius to blank thickness and ratio of blank thickness to diameter on LDR is investigated.     

Tool path accuracy enhancement through geometrical error compensation

Kinematic and geometric errors of CNC machine tools, introduce large deviations in the real path traveled by the cutting tool. Tool path deviation reduces geometrical and dimensional accuracy of the machined features of the component. Tool path modification is an effective strategy to increase accuracy of the machined features. An improved error estimation model based on kinematic transformation concepts has been developed and used to calculate the volumetric overall error. These calculations are applicable for each arbitrary target positions of the machine's work space. Also a NC Program editor software has been developed in order to manage the calculations, modifications and to generate the new compensated NC program. The compensation procedure includes: fragmentation of nominal tool path to small linear elements, translating nominal position of elements to real positions using the Kinematics error model, finding compensated positions using the error compensation algorithm, converting newly generated elements to new tool paths using the packing algorithms and finally editing old NC program using NC code generator algorithm. Experimental tests showed 4-8 times accuracy improvement for linear, and S-pline tool paths deviations.     

Atomically Precise Prediction of 2D Self‐Assembly of Weakly Bonded Nanostructures: STM Insight into Concentration‐Dependent Architectures

A joint experimental and computational study is reported on the concentration‐dependant self‐assembly of a flat C₃‐symmetric molecule on a graphite surface. As a model system a tripodal molecule, 1,3,5‐tris(pyridin‐3‐ylethynyl)benzene, has been chosen, which can adopt either C_3h or C_s symmetry when planar, as a result of pyridyl rotation along the alkynyl spacers. Density functional theory (DFT) simulations of 2D nanopatterns with different surface coverage reveal that the molecule can generate different types of self‐assembled motifs. The stability of fourteen 2D patterns and the influence of concentration are analyzed. It is found that ordered, densely packed monolayers and 2D porous networks are obtained at high and low concentrations, respectively. A concentration‐dependent scanning tunneling microscopy (STM) investigation of this molecular self‐assembly system at a solution/graphite interface reveals four supramolecular motifs, which are in perfect agreement with those predicted by simulations. Therefore, this DFT method represents a key step forward toward the atomically precise prediction of molecular self‐assembly on surfaces and at interfaces.