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排序方式: 共有68条查询结果,搜索用时 15 毫秒
1.
MXene Yarn Supercapacitors: High‐Performance Biscrolled MXene/Carbon Nanotube Yarn Supercapacitors (Small 37/2018)
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2.
Advanced Monte Carlo simulations of the adsorption of chiral alcohols in a homochiral metal‐organic framework
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Zhiwei Qiao Ariana Torres‐Knoop David Dubbeldam David Fairen‐Jimenez Jian Zhou Randall Q. Snurr 《American Institute of Chemical Engineers》2014,60(6):2324-2334
Grand canonical Monte Carlo (GCMC) simulations with configurational biasing were used to study the enantioselective adsorption of four alkanols in a homochiral metal‐organic framework, known as hybrid organic‐inorganic zeolite analogue HOIZA‐1. Conventional GCMC simulations are not able to converge satisfactorily for this system due to the tight fit of the chiral alcohols in the narrow pores. However, parallel tempering and parallel mole‐fraction GCMC simulations overcome this problem. The simulations show that the enantioselective adsorption of the different (R,S)‐alkanols is due to the specific geometry of the chiral molecules relative to the pore size and shape. © 2014 American Institute of Chemical Engineers AIChE J, 60: 2324–2334, 2014 相似文献
3.
Velichka Strijkova-Kenderova Svetla Todinova Tonya Andreeva Desislava Bogdanova Ariana Langari Avgustina Danailova Sashka Krumova Elena Zlatareva Nikolay Kalaydzhiev Ivan Milanov Stefka G. Taneva 《International journal of molecular sciences》2022,23(1)
Human red blood cells (RBCs) are unique cells with the remarkable ability to deform, which is crucial for their oxygen transport function, and which can be significantly altered under pathophysiological conditions. Here we performed ultrastructural analysis of RBCs as a peripheral cell model, looking for specific signatures of the neurodegenerative pathologies (NDDs)—Parkinson’s disease (PD), amyotrophic lateral sclerosis (ALS) and Alzheimer’s disease (AD), utilizing atomic force (AFM) and conventional optical (OM) microscopy. We found significant differences in the morphology and stiffness of RBCs isolated from patients with the selected NDDs and those from healthy individuals. Neurodegenerative pathologies’ RBCs are characterized by a reduced abundance of biconcave discoid shape, lower surface roughness and a higher Young’s modulus, compared to healthy cells. Although reduced, the biconcave is still the predominant shape in ALS and AD cells, while the morphology of PD is dominated by crenate cells. The features of RBCs underwent a marked aging-induced transformation, which followed different aging pathways for NDDs and normal healthy states. It was found that the diameter, height and volume of the different cell shape types have different values for NDDs and healthy cells. Common and specific morphological signatures of the NDDs were identified. 相似文献
4.
Jorge Berlanga-Acosta Maday Fernndez-Mayola Yssel Mendoza-Marí Ariana García-Ojalvo Indira Martinez-Jimenez Nadia Rodriguez-Rodriguez Raymond J. Playford Osvaldo Reyes-Acosta Laura Lopez-Marín Gerardo Guilln-Nieto 《International journal of molecular sciences》2022,23(3)
Lower-extremity arterial disease is a major health problem with increasing prevalence, often leading to non-traumatic amputation, disability and mortality. The molecular mechanisms underpinning abnormal vascular wall remodeling are not fully understood. We hypothesized on the existence of a vascular tissue memory that may be transmitted through soluble signaling messengers, transferred from humans to healthy recipient animals, and consequently drive the recapitulation of arterial wall thickening and other vascular pathologies. We examined the effects of the intralesional infiltration for 6 days of arteriosclerotic popliteal artery-derived homogenates (100 µg of protein) into rats’ full-thickness wounds granulation tissue. Animals infiltrated with normal saline solution or healthy brachial arterial tissue homogenate obtained from traumatic amputation served as controls. The significant thickening of arteriolar walls was the constant outcome in two independent experiments for animals receiving arteriosclerotic tissue homogenates. This material induced other vascular morphological changes including an endothelial cell phenotypic reprogramming that mirrored the donor’s vascular histopathology. The immunohistochemical expression pattern of relevant vascular markers appeared to match between the human tissue and the corresponding recipient rats. These changes occurred within days of administration, and with no cross-species limitation. The identification of these “vascular disease drivers” may pave novel research avenues for atherosclerosis pathobiology. 相似文献
5.
Ariana C. F. Santos Luís P. G. Monteiro Adriana C. C. Gomes Ftima Martel Teresa M. Santos Brbara J. M. Leite Ferreira 《International journal of molecular sciences》2022,23(5)
After the serendipitous discovery of cisplatin, a platinum-based drug with chemotherapeutic effects, an incredible amount of research in the area of coordination chemistry has been produced. Other transition metal compounds were studied, and several new relevant metallodrugs have been synthetized in the past few years. This review is focused on coordination compounds with first-row transition metals, namely, copper, cobalt, nickel or manganese, or with zinc, which have potential or effective pharmacological properties. It is known that metal complexes, once bound to organic drugs, can enhance the drugs’ biological activities, such as anticancer, antimicrobial or anti-inflammatory ones. NSAIDs are a class of compounds with anti-inflammatory properties used to treat pain or fever. NSAIDs’ properties can be strongly improved when included in complexes using their compositional N and O donor atoms, which facilitate their coordination to metal ions. This review focuses on the research on this topic and on the promising or effective results that complexes of first-row transition metals and NSAIDs can exhibit. 相似文献
6.
Comparison of vacuum impregnation and soaking techniques for addition of the probiotic Lactobacillus acidophilus to minimally processed melon
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Patrícia Martins de Oliveira Afonso Mota Ramos Eliane Maurício Furtado Martins Érica Nascif Rufino Vieira Ariana de Souza Soares Marcel Cardoso de Noronha 《International Journal of Food Science & Technology》2017,52(12):2547-2554
This study aimed to evaluate the vacuum impregnation (VI) and soaking methods in the addition of Lactobacillus acidophilusLA‐3 to minimally processed melon (MPM). The melons were washed, sanitised in chlorine solution (200 mg L?1), peeled and cutted into cubes. Lactobacillus acidophilusLA‐3 (1.4 × 1010 CFU g?1) were added to the MPM through both techniques. The L. acidophilusLA‐3 count in MPM was similar to those commonly found in dairy products having probiotic claim, but VI was more efficient than soaking in maintaining the viability (8.61 and 7.98 Log CFU g?1, respectively). The pH, acidity and soluble solids were not affected by probiotic culture and the incorporation technique; however, the VI affected the firmness of fruit. The MPM was within Brazilian standards for their microbiological characteristics. MPM may be used as a carrier of probiotic bacteria, being one more alternative for individuals who consume probiotic products. 相似文献
7.
A combination of step potential electrochemical spectroscopy (SPECS) and electrochemical impedance spectroscopy (EIS) has been used to examine the electrochemical cycling behaviour of a well-characterized birnessite-phase manganese dioxide sample for use in electrochemical capacitors. The resistance and interfacial properties of the macroscopic electrode were found to be irreversible with cycling. However, the corresponding properties for the individual particles were more reversible, although they did show substantial hysteresis in their behaviour during cycling. This behaviour was discussed in terms of the structural, conductivity and morphological characteristics of the birnessite at different depths of discharge. 相似文献
8.
Vítor J.P. Vilar Lívia X. Pinho Ariana M.A. Pintor Rui A.R. Boaventura 《Solar Energy》2011,85(9):1927-1934
Heterogeneous (TiO2/UV, TiO2/H2O2/UV) and homogenous (H2O2/UV, Fe2+/H2O2/UV) solar advanced oxidation processes (AOPs) are proposed for the treatment of recalcitrant textile wastewater at pilot-plant scale with compound parabolic collectors (CPCs). The textile wastewater presents a lilac colour, with a maximum absorbance peak at 516 nm, high pH (pH = 11), moderate organic content (DOC = 382 mg C L−1, COD = 1020 mg O2 L−1) and high conductivity (13.6 mS cm−1), associated with a high concentration of chloride (4.7 g Cl− L−1). The DOC abatement is similar for the H2O2/UV and TiO2/UV processes, corresponding only to 30% and 36% mineralization after 190 kJUV L−1. The addition of H2O2 to TiO2/UV system increased the initial degradation rate more than seven times, leading to 90% mineralization after exposure to 100 kJUV L−1. All the processes using H2O2 contributed to an effective decolourisation, but the most efficient process for decolourisation and mineralization was the solar-photo-Fenton with an optimum catalyst concentration of 100 mg Fe2+ L−1, leading to 98% decolourisation and 89% mineralization after 7.2 and 49.1 kJUV L−1, respectively. According to the Zahn-Wellens test, the energy dose necessary to achieve a biodegradable effluent after the solar-photo-Fenton process with 100 mg Fe2+ L−1 is 12 kJUV L−1. 相似文献
9.
Jahamunna A. A. Barbosa Ariana Zoppi Mario A. Quevedo Polyanne N. de Melo Arthur S. A. de Medeiros Letícia Streck Alice R. de Oliveira Matheus F. Fernandes-Pedrosa Marcela R. Longhi Arnóbio A. da Silva-Júnior 《International journal of molecular sciences》2014,15(9):17077-17099
The interaction of methotrexate (MTX) with beta-cyclodextrin (β-CD) in the presence of triethanolamine (TEA) was investigated with the aim to elucidate the mechanism whereby self-assembly cyclodextrin systems work in association with this third component. Solubility diagram studies showed synergic increment of the MTX solubility to be about thirty-fold. Experiments using 2D ROESY and molecular modeling studies revealed the inclusion of aromatic ring III of the drug into β-CD cavity, in which TEA contributes by intensifying MTX interaction with β-CD and stabilizes MTX:β-CD:TEA ternary complex by electrostatic interaction. The maintenance of these interactions in solid phase was also studied in ternary MTX:β-CD:TEA and comparisons were made with freeze dried binary MTX:β-CD and physical mixtures. FTIR studies evidenced that MTX–β-CD interaction remained in solid ternary complexes, which was also supported by thermal (differential scanning calorimetry (DSC), thermogravimetric analysis (TG)/first derivative of TG analysis (DTG) and C,N,H elementary analysis) and structural (X-ray diffraction analysis, (XRD)) studies, mainly regarding the increment of drug stability. The efficient in vitro drug dissolution studies successfully demonstrated the contribution of ternary complexes, which highlights the importance of this possible new raw material for further applications in drug delivery systems. 相似文献
10.
2‐Dimensional Transition Metal Dichalcogenides with Tunable Direct Band Gaps: MoS2(1–x)Se2x Monolayers
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John Mann Quan Ma Patrick M. Odenthal Miguel Isarraraz Duy Le Edwin Preciado David Barroso Koichi Yamaguchi Gretel von Son Palacio Andrew Nguyen Tai Tran Michelle Wurch Ariana Nguyen Velveth Klee Sarah Bobek Dezheng Sun Tony. F. Heinz Talat S. Rahman Roland Kawakami Ludwig Bartels 《Advanced materials (Deerfield Beach, Fla.)》2014,26(9):1399-1404