Effect of the addition of Fe2O3 and heat treatment duration on the magnetic susceptibility of V2O5-P2O5-B2O3 glass system

The effect of the addition of Fe₂O₃ and heat treatment duration on the magnetic susceptibility of vanadium borophosphate glass were studied. The magnetic susceptibility of glass samples was found to increase with increasing Fe₂O₃ content, which may be explained by the formation of the FeO₆ group and the change of Fe²⁺ to Fe³⁺ which has higher paramagnetic properties. No detectable changes in the magnetic susceptibility with heat treatment for the samples containing 0.0, 0.5 and 1.0 mol% Fe₂O₃ was observed. The magnetic susceptibility for the heat treated samples containing 2.5, 5.0 and 7.5 mol% Fe₂O₃ decreases sharply with increasing duration of heat treatment up to 6 h and then remains almost constant. The sharp decrease in magnetic susceptibility of 2.5 mol% Fe₂O₃ is attributed to the increase in the number of ferrous ions. The sharp decrease for samples containing 5.0 and 7.5 mol% Fe₂O₃ is attributed to the increase in the number of Fe³⁺ in tetrahedral co-ordination. The rate of crystallization owing to the heat treatment was calculated and was found to increase with increasing iron oxide content. The geometry of crystallization was found to be in three-, two-and one-dimension(s) for samples containing 2.5, 5.0 and 7.5 mol% Fe₂O₃, respectively.     

The Use of Acoustic Emission Intensity Analysis for the Assessment of Cover Crack Growth in Corroded Concrete Structures

In this paper, acoustic emission (AE) intensity analysis was utilized to assess the concrete cover cracking due to steel corrosion in reinforced concrete structures. A total of 30 reinforced concrete prism samples were tested under an accelerated corrosion test coupled with continuous AE monitoring using attached AE sensors. The samples were cast with three concrete cover thicknesses (20, 30 and 40 mm) around steel bars and were exposed to five percentages of steel mass loss: 1, 2, 3, 4, and 5 %. The cover cracking was monitored daily by visual inspection to detect and measure crack widths. Different AE signal parameters were continuously recorded during the tests, including number of hits, signal strength, energy, and amplitude. The acquired AE events were subjected to an intensity analysis of signal strength to estimate historic index (H (t)) and severity (\(S_r)\). In addition, a b value analysis was conducted on all AE data and the results were compared to those obtained from the intensity analysis. The results showed that increasing the cover thickness had no significant impact on AE parameters (number of hits, cumulative signal strength, cumulative energy, amplitude, H (t), and \(S_{r})\) at similar values of crack growth. Nonetheless, varying the cover thickness from 20 to 40 mm resulted in lower crack widths and slightly higher b values at the same levels of steel mass loss. It was also found that both H (t) and \(S_r\) showed a more evident correlation with the values of crack growth than did b values, regardless of cover thickness or percentage of steel mass loss. Finally, an intensity classification chart was developed to quantify the cover crack growth based on the values of H (t) and \(S_{r}\).     

Assessing abrasion performance of self-consolidating concrete containing synthetic fibers using acoustic emission analysis

The key objective of this investigation was to evaluate the abrasion resistance of self-consolidating concrete (SCC) with and without synthetic fibers (SynFs). The abrasion resistance of normal concrete was also investigated in this study for comparison. The abrasion test was performed on concrete specimens according to the rotating-cutter method along with continuous monitoring of acoustic emission (AE) using attached AE sensors. The effects of changing concrete type and incorporating various types (flexible and semi-rigid) and lengths of SynFs on the abrasion behaviour were investigated with the aid of AE analysis. AE signal characteristics such as amplitude, signal strength, number of hits, and duration were gathered during testing. Furthermore, the collected AE data was used to complete b-value analysis as well as intensity analysis resulting in three additional parameters: b-value, severity (S_r), and historic index (H(t)). The results showed that the AE parameters were directly correlated with the abrasion damage in all tested mixtures. Adding SynFs to all SCC mixtures enhanced their abrasion resistance. The flexible fibers variety exhibited better abrasion performance on average than the semi-rigid fibers. Meanwhile, longer fibers showed lower abrasion resistance than the shorter ones with the same type. The results also indicated that AE intensity analysis was able to determine the ranges for H(t) and S_r that identify the extent of damage due to abrasion of SynF-reinforced SCC.     

Microfluidic inverse phase ELISA via manipulation of magnetic beads

We report a new technique for conducting immuno-diagnostics on a microfluidic platform. Rather than handling fluid reagents against a stationary solid phase, the platform manipulates analyte-coated magnetic beads through stationary plugs of fluid reagents to detect an antigenic analyte. These isolated but accessible plugs are pre-encapsulated in a microchannel by capillary force. We call this platform microfluidic inverse phase enzyme-linked immunosorbent assay (μIPELISA). μIPELISA has distinctive advantages in the family of microfluidic immunoassay. In particular, it avoids pumping and valving fluid reagents during assaying, thus leading to a lab-on-a-chip format that is free of instrumentation for fluid actuation and control. We use μIPELISA to detect digoxigenin-labeled DNA segments amplified from E. coli O157:H7 by polymerase chain reaction (PCR), and compare its detection capability with that of microplate ELISA. For 0.259 ng μl⁻¹ of digoxigenin-labeled amplicon, μIPELISA is as responsive as the microplate ELISA. Also, we simultaneously conduct μIPELISA in two parallel microchannels.     

Quantitative and reliable in vitro method combining scanning electron microscopy and image analysis for the screening of osteotropic modulators

The increased generation and up-regulated activity of bone resorbing cells (osteoclasts) play a part in the impairment of bone remodeling in many bone diseases. Numerous drugs (bisphosphonates, calcitonin, selective estrogen receptor modulators) have been proposed to inhibit this increased osteoclastic activity. In this report, we describe a pit resorption assay quantified by scanning electron microscopy coupled with image analysis. Total rabbit bone cells with large numbers of osteoclasts were cultured on dentin slices. The whole surface of the dentin slice was scanned and both the number of resorption pits and the total resorbed surface area were measured. Resorption pits appeared at 48 h and increased gradually up to 96 h. Despite the observation of a strong correlation between the total resorption area and the number of pits, we suggest that area measurement is the most relevant marker for osteoclastic activity. Osteotropic factors stimulating or inhibiting osteoclastic activity were used to test the variations in resorption activity as measured with our method. This reproducible and sensitive quantitative method is a valuable tool for screening for osteoclastic inhibitors and, more generally, for investigating bone modulators.     

Preparation and properties of probiotic concentrated yoghurt (labneh) fortified with conjugated linoleic acid

Milk of high conjugated linoleic acid (CLA) level (1.25 g per 100 g milk fat) was produced by inclusion of fish oil and rousted soy bean in the ration of Holstein cows as compared to 0.55 g per 100 g milk fat in the milk of animals receiving control diet. Milk of normal (control) and high CLA content (treatment) was spray‐dried. Labneh was made from 20 g L^?1 reconstituted milk using 3 mL per 100 mL yoghurt starter and 2 mL per 100 mL of probiotic cultures of Lactobacillus casei or Lactobacillus acidophilus. The control (C) and high CLA (T) labneh were analysed chemically and microbiologically, and their viscosities were determined during cold storage for 15 days. The fat content of labneh of high CLA was less than that of the control, but the total solids (TS) were unaffected by the CLA level. Labneh made with Lb. acidophilus had lower TS and higher acidity, exopolysaccharides and acetaldehyde contents and viscosity than that made with the use of Lb. casei. Labneh from the different treatments retained high counts of the added probiotic (>10⁸ cfu g^?1) throughout the storage period. The storage period had significant effects on all parameters determined.     

Structure,magnetic, and electrical studies on vanadium phosphate glasses containing different oxides

Glass system with molar composition (60% P₂O₅–30%V₂O₅–10%X) where X is Li₂O, Na₂O, K₂O, and BaO was prepared. The density and molar volume indicate that the density decreases while the molar volume increases with increasing ionic radius of doped oxides. IR studies reveal the coexistence of V⁴⁺ and V⁵⁺ ions (act as glass modifier and glass former, respectively). The observed paramagnetic behavior of samples indicates that V⁴⁺ > V⁵⁺ (the ratio V⁴⁺/V⁴⁺ + V⁵⁺ > 0.52 as obtained from chemical titration analysis). Mott’s model of conduction was applied to discuss DC electrical conduction mechanism. The prepared glass exhibits semiconducting behavior. However, Ba ion is the only ion which did not contribute to the ionic conduction. The conductivity increases with decreasing ionic radius of doped oxides due to high mobility due to their small size. The effect of hopping distance on the electrical conduction and magnetic properties were discussed. An attempt was done to determine the expected temperature of Ba ionic conduction and its ionic activation energy.     

Optimized SVD-based robust watermarking in the fractional Fourier domain

Digital watermarking is one of the most effective methods for protecting multimedia from different kind of threats. It has been used for many purposes, like copyright protection, ownership identification, tamper detection, etc. Many watermarking applications require embedding techniques that provide robustness against common watermarking attacks, like compression, noise, filtering, etc. In this paper, an optimized robust watermarking method is proposed using Fractional Fourier Transform and Singular Value Decomposition. The approach provides a secure way for watermarking through the embedding parameters that are required for the watermark extraction. It is a block-based method, where each watermark bit is embedded in its corresponding image block. First, the transform is applied to each block, and then the singular values are evaluated through which the embedding modification is performed. The optimum fractional powers, of the transform, and the embedding strength factor are evaluated through a Meta-heuristic optimization to optimize the watermark imperceptibility and robustness. The Artificial Bee Colony is used as the Meta-heuristic optimization method. A fitness function is employed, at the optimization process, through which the maximum achievable robustness can be provided without degrading the watermarking quality below a predetermined quality threshold Qth. The effectiveness of the proposed method is demonstrated through a comparison with recent watermarking techniques in terms of the watermarking performance. The watermarking quality and robustness are evaluated for different quality threshold values. Experimental results show that the proposed approach achieves a better quality compared to that of other existing watermarking methods. On the other hand, the robustness is examined against the most common applied attacks. It is noticed that the proposed method can achieve a higher robustness degree when decreasing the quality threshold value.     

Effect of metakaolin and silica fume on the durability of self-consolidating concrete

Metakaolin (MK) is a valuable admixture for concrete/cement applications that can enhance the performance of cementitious composites through high pozzolanic reactivity, much like silica fume (SF). While SF concrete is characterized by superior mechanical and durability performance, concrete containing MK achieves comparable properties at a lower price and with better workability. The objective of this study is to investigate the effect of cement replacement by MK on the durability of self-consolidating concrete (SCC); the effect of SF at similar levels of MK replacement has also been included for comparison. The durability performance of SCC was evaluated based on the results of drying shrinkage, freezing and thawing, salt scaling, and rapid chloride permeability tests. The results of these tests indicate that highly durable SCC mixtures can be produced using a high MK content with an optimum percentage of around 20%. The results also show that the durability of SCC, especially with high MK content, is higher than that of SCC containing SF.