Relation between abrasion resistance and flexural strength of high volume fly ash concrete

In this paper, abrasion of high volume fly ash (HVFA) concretes made with 50% and 70% of cement replacement with fly ash was assessed in terms of its relation to flexural tensile strength. Comparisons were made between normal Portland cement (NPC) concrete and fly ash concrete. Comparisons were also made between fly ash concretes. Investigation results have shown that the abrasion resistance increased as flexural tensile strength increased. Analysis of the results showed that, for concrete with tensile strength of greater than 4–5 MPa, the abrasion resistance of HVFA concrete with 70% replacement with cement was found to be higher than that of counterpart control NPC concrete and concrete made with 50% fly ash. The comparison between the relation of abrasion to compressive strength and abrasion to flexural tensile strength made in terms of R² of the linear regression showed that a stronger relation existed between abrasion and flexural tensile strength than that of abrasion to compressive strength of the concrete studied.

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Résumé L'étude a pour but d'estimer la relation entre la résistance à l'usure avec la résistance à la traction en flexion des bétons contenant de 50% et 70% de cendres volantes. On a comparé le béton pur au béton contenant des cendres volantes. Des comparaisons ont été faites également entre les différents bétons contenant des cendres volantes. Les resultats de la recherche ont montré que la résistance à l'usure augmente à mesure que la résistance à la traction en flexion de 4∼5 MPa ont une résistance à l'usure plus grande s'ils contienneint 70% de cendres volantes que s'ils étaient purs ou contenaient 50% de cendres volantes. La comparaison entre les relation de la résistance à l'usure en compression et de la résistance à l'usure en traction a été établie en termes de R² de la régression linéaire. On a prouvé qu'une relation plus forte a été obtenue entre la résistance à l'usure et la résistance à la traction en flexion par rapport à la résistance à l'usure en compression du béton étudié.

     

Heat evolution of high-volume fly ash concrete

In this paper, the results of a laboratory investigation conducted with heat evolution of high-volume fly ash (HVFA) concrete are presented. Heat evolution of concrete was studied by measuring the temperature increase in concrete under adiabatic curing condition. Characteristic of heat evolution of fly ash concrete was found to be strongly dependent on the replacement level of fly ash and dosage of superplasticizer used to maintain workability. It was also found that using fly ash as cement replacement resulted in a reduction on the maximum temperature rise. Increasing the replacement level of fly ash caused lower temperature rise in concrete. Superplasticizer caused a delay in peak temperature rise time; this is taken as an indicator that high-dosage superplasticizer used in concrete caused retardation in hydration of cement. Concretes having similar ingredients showed similar peak temperature rise whether they are superplasticized or not.     

Carbon segregation and inclusions effects on surface fracture morphology of a 12% chromium stainless steel

Martensitic 12% chromium stainless steel is generally used for the manufacture of water vapour turbine blades. This material, under these environmental conditions, develops fatigue corrosion with failure as a result of the segregation of certain constituent elements such as phosphorus (P) and sulphur (S),^[1–3] or the presence of some types of inclusions.^[2–4] To be able to understand and explain these phenomena, in situ characterization of the fractured surfaces were performed for two types of samples: steel 1 as manufactured turbine material whose fracture mode is intergranular and steel 2 issued from last stage turbine blades after 100 000 h service at 40 °C whose fracture mode is transgranular. The techniques used for characterization were scanning electron microscopy (SEM) coupled with the x-ray analysis by energy dispersive spectroscopy (EDS), and auger electron spectroscopy (AES). The Auger results enabled the understanding of the brittle to ductile transition for the material by showing the simultaneous diffusion of carbon from grain boundaries (GB) to grains (G) and chromium from G to GB. Furthermore, the heavy segregation of phosphorus at the GBs could explain the intergranular crack rupture traces observed in steel 2. SEM observations coupled with EDS analysis showed the presence of different types of non-metallic inclusions such as silicon-based complex inclusions and manganese sulfides (MnS). The presence of silicon-based complex inclusions at GB could explain the intergranular fracture mode previously reported. The characterization of the fracture appearance suggests also that MnS inclusions can act as nucleation sites for secondary microcracks at the GB level that were observed after service.     

Study of microstructure, phases and microhardness of metallic coatings deposited by flame thermal spray

The recharging technique by thermal spraying offers the opportunity of renovating the worn surface parts of a machine element to give it again a new technical life despite its previous degradation in service. This process has consequently interesting economic impacts. In order to improve the adherence between 100Cr6 steel deposits and the substrate material (left worn crankshafts), company SNC ATRA of Béjaïa uses at present a composite formed by (100Cr6 steel/molybdenum bond coat of 0.2 mm thick/crankshaft substrate). As a matter of fact, it is shown in the present work that the molybdenum bond coat is not appropriate since, for the 0.2 mm thickness, lateral cracks are observed in the middle of the bond coat. On the other hand, our experiment is that a deposit of 100Cr6 steel projected directly on the substrate seems more promising since no gaps or cracks were detected at the “deposit/substrate” interface of this two-material composite. Lastly, phase analysis using X-ray diffraction confirmed that during spraying process, a stable -phase (bcc) of 100Cr6 wire was transformed to a new phase of γ-phase (fcc). The coatings exhibited the higher microhardness which would contribute to increase wear resistance.     

Influence of activator on the strength and drying shrinkage of alkali-activated slag mortar

The development of new binders, as an alternative to traditional cement, by the alkaline activation of industrial by-products (i.e. ground granulated slag and fly ash) is an ongoing research topic in the scientific community [Puertas F, Amat T, Jimenez AF, Vazquez T. Mechanical and durable behaviour of alkaline cement mortars reinforced with polypropylene fibres. Cem Concr Res 2003;33(12): 2031–6]. The aim of this study was to investigate the feasibility of using and alkaline activated ground Turkish slag to produce a mortar without Portland cement (PC).Following the characterization of the slag, mortar specimens made with alkali-activated slag were prepared. Three different activators were used: liquid sodium silicate (LSS), sodium hydroxide (SH) and sodium carbonate (SC) at different sodium concentrations. Compressive and flexural tensile strength of alkali-activated slag mortar was measured at 7-days, 28-days and 3-months. Drying shrinkage of the mortar was measured up to 6-months. Setting times of the alkali-activated slag paste and PC paste were also measured.Setting times of LSS and SH activated slag pastes were found to be much slower than the setting time of PC paste. However, slag paste activated with SC showed similar setting properties to PC paste.LSS, SH and SC activated slag mortar developed 81, 29, and 36 MPa maximum compressive strengths, and 6.8, 3.8, and 5.3 MPa maximum flexural tensile strengths at 28-days. PC mortar developed 33 MPa compressive strength and 5.2 MPa flexural tensile strength. LSS and SH activated slag mortars were found to be more brittle than SC activated slag and PC mortars.Slag mortar made with LSS had a high drying shrinkage, up to six times that of PC mortar. Similarly, slag mortar made with SH had a shrinkage up to three times that of PC mortar. However, SC activated slag mortar had a lower or comparable shrinkage to PC mortar. Therefore, the use of SC as an activator for slag mortar is recommended, since it results in adequate strength, similar setting times to PC mortar and comparable or lower shrinkage.     

CuII Pyrazolyl-Benzimidazole Dinuclear Complexes with Remarkable Antioxidant Activity

Three dinuclear coordination complexes generated from 1-n-butyl-2-((5-methyl-1H-pyrazole-3-yl)methyl)-1H-benzimidazole ( L ), have been synthesized and characterized spectroscopically and structurally by single crystal X-ray diffraction analysis. Reaction with iron(II) chloride and then copper(II) nitrate led to a co-crystal containing 78 % of [Cu(NO₃)(μ-Cl)( L’ )]₂ ( C₁ ) and 22 % of [Cu(NO₃)(μ-NO₃)( L’ )]₂ ( C₂ ), where L was oxidized to a new ligand L^’ . A mechanism is provided. Reaction with copper chloride led to the dinuclear complex [Cu(Cl)(μ-Cl)( L) ]₂ ( C₃ ). The presence of N−H⋅⋅⋅O and C−H⋅⋅⋅O intermolecular interactions in the crystal structure of C₁ and C₂ , and C−H⋅⋅⋅N and C−H⋅⋅⋅Cl hydrogen bonding in the crystal structure of C₃ led to supramolecular structures that were confirmed by Hirshfeld surface analysis. The ligands and their complexes were tested for free radical scavenging activity and ferric reducing antioxidant power. The complex C₁ / C₂ shows remarkable antioxidant activities as compared to the ligand L and reference compounds.     

The durability properties of polypropylene fiber reinforced fly ash concrete

This paper reports of a comprehensive study on the durability properties of concrete containing polypropylene fiber and fly ash. Properties studied include unit weight and workability of fresh concrete, and compressive strength, modulus of elasticity, porosity, water absorption, sorptivity coefficient, drying shrinkage and freeze–thaw resistance of hardened concrete. Fly ash content used in concrete mixture was 0%, 15% and 30% in mass basis, and fiber volume fraction was 0%, 0.05%, 0.10% and 0.20% in volume basis.     

Analytic Hierarchy Process for Evaluating Flipped Classroom Learning

In reality, the flipped classroom has gained popularity as a modern way of structuring teaching, where lectures move from in-class procedures to digitally-based assignments, freeing up the debate, and practice exercises class time. Therefore, it is essential to implement and analyze a way of teaching that will improve student performance. The paper aims to develop a model of the method of teaching science in Iraqi schools, and to assess whether teaching flipped classroom affects the achievement, motivation, and creative thinking of students by using the methodology of Multi-Criteria Decision Making (MCDM) in the Analytic Hierarchy Process (AHP). The AHP approach includes several steps, including setting assessment criteria and their weights, and by assessing the methodology of the flipped classroom as compared to the conventional cognitive learning process. An experiment was carried out in Iraqi secondary schools to examine the attitude of the students towards the subject of Chemistry. The findings have indicated that the students and teachers favored flipped classroom learning more than conventional cognitive learning. The study took the following parameters compared to the traditional approach: teaching techniques, learning flexibility, teaching aids effectiveness, student participation and working environment. This paper indicates that the teachers in Iraqi schools will be able to improve and do more preparation to shift towards flipped learning in the classroom.     

Wet and dry cured compressive strength of concrete containing ground granulated blast-furnace slag

This paper reports a part of an ongoing laboratory investigation in which the compressive strength of ground granulated blast-furnace slag (GGBFS) concrete studied under dry and wet curing conditions. In the study, a total of 45 concretes, including control normal Portland cement (NPC) concrete and GGBFS concrete, were produced with three different water-cement ratios (0.3, 0.4, 0.5), three different cement dosages (350, 400, 450 kg/m³) and four partial GGBFS replacement ratios (20%, 40%, 60%, 80%). A hyperplasticizer was used in concrete at various quantities to provide and keep a constant workability. Twelve cubic samples produced from fresh concrete were de-moulded after a day, then, six cubic samples were cured at 22±2 °C with 65% relative humidity (RH), and the remaining six cubic samples were cured at 22±2 °C with 100%RH until the samples were used for compressive strength measurement at 28 days and three months. Three cubic samples were used for each age and curing conditions. The comparison was made on the basis of compressive strength between GGBFS concrete and NPC concrete. GGBFS concretes were also compared within themselves. The comparisons showed that compressive strength of GGBFS concrete cured at 65%RH was influenced more than that of NPC concrete. It was found that the compressive strength of GGBFS concrete cured at 65%RH was, at average, 15% lower than that of GGBFS concrete cured at 100%RH. The increase in the water-cementitious materials ratios makes the concrete more sensitive to dry curing condition. The influence of dry curing conditions on GGBFS concrete was marked as the replacement ratio of GGBFS increased.