Mixed oxide supported hydrodesulfurization catalysts—a review

Support effects form important aspect of hydrodesulfurization (HDS) studies and mixed oxide supports received maximum attention in the last two decades. This review will focus attention on studies on mixed oxide supported Mo and W catalysts. For convenience of discussion, these are divided into Al₂O₃ containing mixed oxide supports, TiO₂ containing mixed oxide supports, ZrO₂ containing mixed oxide supports and other mixed oxide supports containing all the rest. TiO₂ containing mixed oxides received maximum attention, especially TiO₂–Al₂O₃ supported catalysts. A brief discussion about their prospects for application to ultradeep desulfurization is also included. An overview of the available literature with emphasis on research carried out in our laboratory form the contents of this publication.     

Low Cost Low Power Smart Helmet for Real-Time Remote Underground Mine Environment Monitoring

Underground mining production process is vulnerable and highly dynamic in nature. Among the various causes of accidents in underground mine, major one is presence of flammable and noxious gases. Though many existing safety gadgets are there but they could not work reliably because of the typical nature of mines structure and production variability. Wireless data and communication network is also not successful because wireless communication in underground mine is significantly more challenging than through air. This work introduces the application of mobile wireless sensor network in order to monitor a variety of parameters in underground mines which have life threatening effects towards them. Each node of the network placed over the safety gear (helmet wore statutorily by every miner) comprises of various sensors depending on the requirement with microcontroller unit and other low power accessories. The proposed work has a unique feature that it will make the personnel aware about the situation of the gases present and surrounding by automatically generating different alarms and different light indicators. Other function of this device will be to transmit the data sensed by the sensors in the device to the control room wirelessly so that the responsible person would be aware of the situation. This work is focused on the design of such a prototype model for the underground mines with the aforementioned specification.     

在双镶嵌铜互联中O.13微米器件生成用的基于PVD和ALD阻挡层的先进技术

1. Introduction The requirement of minimal bottom coverageand thick sidewall coverage for PVD-based films forlow via resistance and improved stress migration isnot easy to achieve with traditional depositionmethods. Modern I-PVD techniques give high bot-tom coverage, due to the ionized component of thedeposition flux. Sidewall coverage tends to be low,which is mainly due to off-normal deposition fluxand a less than unity sticking coefficient.     

Throughput analysis in censoring-based cooperative cognitive radio network with energy harvesting

An energy harvesting (EH) and cooperative cognitive radio (CR) network (CRN) is studied in this paper where CR users transmit data through a primary user (PU) channel if the channel remains idle, else an optimal number CRs helps in transmission of PU. To achieve the optimum number of CRs (ONCR) involved in cooperation, a novel scheme based on a combination of channel censoring and total error is proposed. The performance of the proposed scheme is investigated under RF harvesting scenario. The EH is dependent on sensing decision and a CR source harvests energy from PU's RF signal. The harvested energy (HE) is split into two parts: One part is used by the CR network (CRN) for its own transmission, and the other part is used for supporting PU. The effect of the energy allocation factor on total throughput is also investigated. New expressions for optimal number of CRs and throughput are developed. The effect of network parameters such as sensing time, censoring threshold, and energy allocation parameter (EAP) on throughput is investigated. Impact of distance between nodes is also studied.     

Binary liquid–liquid equilibria of aniline–paraffin and furfural–paraffin systems

Binary liquid-liquid-equilibria data for several aniline-paraffin and furfural-paraffin systems have been taken. These data along with data for other aniline-hydrocarbon and furfural-hydrocarbon systems from literature have been correlated using UNIFAC model. The UNIFAC group interaction parameters have been found to have a linear temperature dependence. The CH₂ groups in cyclo and non cyclo paraffins require different interaction parameters. It was also found that a scaling of the combinatorial term is necessary for higher molecular weight hydrocarbons.     

Effect of phosphorus on activity of hydrotreating catalyst of Maya heavy crude

The effect of phosphorus on physical properties of the catalyst and on activity of hydrotreating of Maya crude was studied in this work. Catalysts were prepared by the co-impregnation method. Alumina-titania binary oxide was used as a support material. The presence of phosphorus in the catalyst decreases the percentage of micropores, and it results in a decrease of specific surface area. Temperature program reduction (TPR) shows that phosphates reduce metal support interaction. It leads to the formation of polymolybdate phases in expense of strongly bonded tetrahedral molybdates. At higher P loading, polymolybdates may be present with quasi crystalline MoO₃. However, the TPR experiment is not sufficiently sensitive to distinguish several phases present on the catalysts used by the authors. A slight increment of HDM activity is observed, but HDS activity is lower in the P containing catalyst compared with the P free catalyst. The changes of physical properties of the spent catalysts are mainly due to the coke formation on the catalyst. The presence of phosphorus on hydrotreating catalysts inhibits coke formation during the hydrotreating reaction.     

Maya crude hydrodemetallization and hydrodesulfurization catalysts: An effect of TiO2 incorporation in Al2O3

Hydrotreating of Maya heavy crude oil over high specific surface area CoMo/TiO₂–Al₂O₃ oxide supported catalysts was studied in an integral reactor close to industrial practice. Activity studies were carried out with Maya crude hydrodesulfurization (HDS), hydrodemetallization (HDM), hydrodenitrogenation (HDN), and hydrodeasphaltenization (HDAs) reactions. The effect of support composition, the method of TiO₂ incorporation, and the catalyst deactivation are examined. Supported catalysts are characterized by BET specific surface area (SSA), pore volume (PV), pore size distribution (PSD), and atomic absorption. It has been found that sulfided catalysts showed a wide range of activity variation with TiO₂ incorporation into the alumina, which confirmed that molybdenum sulfided active phases strongly depend on the nature of support. The pore diameter and nature of the active site for HDS, HDM, HDN, and HDAs account for the influence of the large reactant molecules restricted diffusion into the pore, and/or the decrease in the number of active sites due to the MoS₂ phases buried with time-on-stream. The textural properties and hysteresis loop area of supported and spent catalysts indicated that catalysts were deactivated at the pore mouth due to the metal and carbon depositions. The atomic absorption results agreed well regarding the textural properties of spent catalysts. Thus, incorporation of TiO₂ with γ-Al₂O₃ alters the nature of active metal interaction with support, which may facilitate the dispersion of active phases on the support surface. Therefore, the TiO₂ counterpart plays a promoting role to HDS activity due to the favorable morphology of MoS₂ phases and metal support interaction.     

Effect of Amine Additive for the Synthesis of Cadmium Selenide Quantum Dots in a Microreactor

The effect of octylamine flow rate on the structure and morphology of CdSe quantum dots synthesized in a microreactor was studied. The flow rate of octylamine was varied from 0.005 ml/min to 0.030 ml/min, and the optical properties of the synthesized particles were analyzed by UV–vis and photoluminescence spectroscopy. The particle size of the quantum dots was found to increase with an increasing octylamine flow rate. Further, UV–vis and photoluminescence bands were found to be red‐shifted with an increasing flow rate. We determined that, by controlling octylamine flow rate, the particle size of the quantum dots could be controlled. This method will help to determine the optimal octylamine flow conditions for synthesizing nanoparticles for use in a diverse range of applications.     

Comparative study on the structural make-up and mechanical behavior of silicon and silver doped amorphous carbon films

Silicon - Silicon (Si) and silver (Ag) doped amorphous carbon (a-C) thin film were deposited on chrome nitrided 316 LVM stainless steel using filtered cathodic vacuum arc (FCVA) deposition...     

Chatter and dynamic cutting force prediction in high-speed ball end milling

Machine tool chatter is a serious problem which deteriorates surface quality of machined parts and increases tool wear, noise, and even causes tool failure. In the present paper, machine tool chatter has been studied and a stability lobe diagram (SLD) has been developed for a two degrees of freedom system to identify stable and unstable zones using zeroth order approximation method. A dynamic cutting force model has been modeled in tangential and radial directions using regenerative uncut chip thickness. Uncut chip thickness has been modeled using trochoidal path traced by the cutting edge of the tool. Dynamic cutting force coefficients have been determined based on the average force method. Several experiments have been performed at different feed rates and axial depths of cut to determine the dynamic cutting force coefficients and have been used for predicting SLD. Several other experiments have been performed to validate the feasibility and effectiveness of the developed SLD. It is found that the proposed method is quite efficient in predicting the SLD. The cutting forces in stable and unstable cutting zone are in well agreement with the experimental cutting forces.