Environment-friendly and cost-effective solution for flexible packaging printing process by advancement in engraving process

Clean Technologies and Environmental Policy - Organic solvents have been commonly used in the printing process for a long time in gravure printing applications. Using organic solvents in...     

The fine structure of bicomponent polyester fibers

The application of alkaline hydrolysis to study the change in the fine structure of bicomponent polyester fibers as their surface is removed progressively was explored. The samples were prepared with a poly(butylene terephthalate) (PBT) sheath and a poly(ethylene terephthalate) (PET) core. The reagent used to hydrolyze the PBT was 1M NaOH in 75/25 methanol to water since it appeared to react topochemically with the fiber. The solution reacted more rapidly with PET than with PBT. Thus, when necessary to retard the weight loss of the bicomponent fibers, after a 2‐h hydrolysis with this reagent to remove PBT, it was replaced with aqueous 1M NaOH solution containing 0.1% cetrimmonium bromide. Unlike homofil PET or PBT fibers, where alkaline attack appeared to be confined to the surface and left the residue relatively smooth, the bicomponent fiber was attacked unevenly, and penetration to the PET core occurred before all the PBT at the surface was removed. Nevertheless, most of the reaction was confined initially to the PBT sheath. The tenacity and extension at break of the PBT–PET fiber passed through a maximum as hydrolysis progressed. The fall in tenacity at high weight losses is ascribed to increasing surface defects in the fiber surface. After removal of the PBT by the hydrolysis, the birefringence of the residue became progressively higher. The synergistic effect of the PBT sheath on the properties of the PET core and the possible causes of the nonuniform hydrolysis at the PBT surface are discussed. An equation is proposed that includes an interaction parameter, which can be utilized to determine which property is affected most by the hydrolysis of a bicomponent fiber. In this instance, it appears from the parameters that the order is strength > extension at break ≈ birefringence. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 71: 1163–1173, 1999     

When simulated environments make the difference: the effectiveness of different types of training of car service procedures

An empirical analysis was performed to compare the effectiveness of different approaches to training a set of procedural skills to a sample of novice trainees. Sixty-five participants were randomly assigned to one of the following three training groups: (1) learning-by-doing in a 3D desktop virtual environment, (2) learning-by-observing a video (show-and-tell) explanation of the procedures, and (3) trial-and-error. In each group, participants were trained on two car service procedures. Participants were recalled to perform a procedure either 2 or 4 weeks after the training. The results showed that: (1) participants trained through the virtual approach of learning-by-doing performed both procedures significantly better (i.e. p < .05 in terms of errors and time) than people of non-virtual groups, (2) the virtual training group, after a period of non-use, were more effective than non-virtual training (i.e. p < .05) in their ability to recover their skills, (3) after a (simulated) long period from the training—i.e. up to 12 weeks—people who experienced 3D environments consistently performed better than people who received other kinds of training. The results also suggested that independently from the training group, trainees’ visuospatial abilities were a predictor of performance, at least for the complex service procedure, adj R ² = .460, and that post-training performances of people trained through virtual learning-by-doing are not affected by learning styles. Finally, a strong relationship (p < .001, R ² = .441) was identified between usability and trust in the use of the virtual training tool—i.e. the more the system was perceived as usable, the more it was perceived as trustable to acquire the competences.     

Propagation modes and regimes of intense laser beam in magnetized plasma

This paper presents an analytical and numerical investigation of a circularly polarized beam propagating along the static magnetic field parallel to oscillating magnetic field in plasma at relativistic intensities. In the high intensity regime, such a magnetic field is created by the pulse itself. The authors have identified three regimes of propagation taking into account the relativistic mass correction. Based on WKB and paraxial ray theory, an appropriate expression for a dielectric tensor has been evaluated in the presence of an externally applied magnetic field. The natural electromagnetic modes are circularly polarized. Consequently, extraordinary and ordinary modes propagate, which are significantly affected due to the relativistic mechanism. The regimes are characterized by dimensionless power and beamwidth, characterizing the nature of propagation as steady divergence, oscillatory divergence and self-focusing. Numerical computations are presented and discussed for typical parameters of laser plasma interaction; defined through critical parameters, namely cyclotron-to-beam frequency (Ω _c ), plasma-to-beam frequency (Ω _p ) and beam power for arbitrary large intensities.     

Techniques to develop and characterize nanosized formulation for salbutamol sulfate

The present study relates to enhancing the dosing efficiency of pharmaceutical dry powder formulations administered by pulmonary inhalation. In particular, the study relates to the provision of dry powder inhalers (DPI) by forming nanosized particles of salbutamol sulfate (SBM) in order to augment the drug penetrability and deposition in the lungs. SBM, an antiasthmatic was selected to be developed into a nanosized formulation by different techniques like solvation, high-pressure homogenization, and spray drying, which were then compared on the basis of particle shape, particle size, and particle size distribution. In case of solvation method the nanosuspension was prepared by dispersing SBM into a nonsolvent and adding Tween-80 as a surfactant to prevent the agglomeration, the particles obtained therein were in the range of 2-10 mu. The second attempt was made by passing the suspension of SBM through high-pressure homogenizer at 10,000-15,000 psi. A treatment of six cycles of homogenization in presence of a Tween-80 as surfactant was found to give a nanosuspension within a size range 50-100 nm. The only drawback seemed with this technique was the low-product yield and high-processing time (3-4 h). In order to overcome this drawback spray-drying technique was further explored; the solution of SBM containing Tween-80 was stirred on magnetic stirrer at 1,200 rpm and finally dried by using spray dryer at an inlet and outlet temperature of 75 degrees C and 56 degrees C, respectively. The feed rate for spray dryer was kept to be 91 ml/h. The sample was collected and analyzed for particle size distribution which was found to be in the range of 50-100 nm. Keeping in view the positive outcomes in terms of higher yield and lower processing time, the spray-drying technique was taken to give the optimized formulation. Nanosized particles, thus obtained were evaluated for particle size, surface topology and particles size distribution, by Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM), and Quasi-elastic light scattering (QELS) technique, respectively. The nanosized particles were subjected to investigate changes on the physical stability of the powder, for this different analytical method was used as: Fourier transform infrared spectroscopy (FT-IR), Differential Scanning Calorimetry (DSC) and X-ray diffraction (XRD) analysis and thus the result indicates that there was no physical disparity when compared with the commercial SBM sample.     

A SIMPLE AND RAPID METHOD FOR DETERMINATION OF METAL IONS IN DEVELOPING BARLEY SEEDS

A simple, rapid and accurate procedure involving flame—and flameless—atomic absorption spectroscopy was devised for the extraction and assay of major and trace metal ions in developing embryos and endosperms of barley seeds. Both embryo (maximum dry weight 20 mg) and endosperm (maximum dry weight 300 mg) samples were decomposed by digestion with nitric acid to yield a clear solution from which all the elements were analysed. Potassium, magnesium, calcium, iron, manganese and copper were determined from the embryo digests. Similarly, potassium, magnesium, calcium and manganese were determined from the endosperm digests. The validity of the procedure was confirmed by high recoveries of added metal ions. The sensitivity of analysis was such that sample size was in the range 1–12 mg.     

Effects of flavonoid-rich extract from seeds of Eugenia jambolana (L.) on carbohydrate and lipid metabolism in diabetic mice

Eugenia jambolana (EJ) is long known for its antidiabetic activities in traditional medicines. The aim of this study was to determine the probable mechanism of action of a flavonoid-rich extract from seeds of EJ on streptozotocin-induced diabetic mice. Various biochemical parameters, e.g. glucose tolerance, lipid profile, glycogen biosynthesis, glucose uptake and insulin release in vivo and in vitro, were significantly improved in the extract-treated diabetic mice. Similarly, differential regulation and expression of glucose homeostatic enzymes, e.g. glucose-6-phosphatase and hexokinase, were also changed significantly in response to the flavonoid-rich extract, which clearly demonstrated the hypoglycemic and hypolipidemic effects in treated animals. Further, analysis of the extract using HPLC, demonstrated the presence of different flavonoids and their derivatives which are known for their antidiabetic and antioxidant potential. The data showed that this flavonoid-rich seed extract has a remarkable dual hypoglycemic and hypolipidemic effect.