Phase diagrams for oil/methanol/ether mixtures

One-phase transmethylations of vegetable oils with methanol to form methyl esters occur considerably faster than conventional two-phase reactions. Addition of simple ethers is an efficient method for producing a single phase. Ternary phase diagrams have been determined at 23°C for oil/methanol/ether mixtures; these are useful when applying the one-phase method across a wide range of conditions. Soybean, canola, palm, and coconut oils were used in combination with five ethers, namely, tetrahydrofuran (THF), 1,4-dioxane (DO), diethyl ether (DE), diisopropyl ether (DI), andtert-butyl methyl ether (TBM). All five ethers can produce miscibility for all methanol/oil compositions. The ether/methanol volumetric ratios required for miscibility at a methanol/soybean or canola oil volumetric ratio of 0.20 (5.4 molar ratio) at 23°C are: THF, 1.15; DO, 1.60; DE, 1.38 DI, 1.57; and TBM, 1.57. For THF, this results in one-phase mixtures that contain 65 vol% oil. Soybean and canola oil form identical diagrams. Palm oil requires slightly less ether at the lower methanol concentrations, but coconut oil requires considerably less across the whole concentration range. Acid-catalyzed reactions, when performed at the boiling point of the most volatile component, require less ether than predicted from the diagrams.     

The pseudo-single-phase,base-catalyzed transmethylation of soybean oil

The base-catalyzed transmethylation of soybean oil has been studied under conditions whereby the reaction starts as a single phase, but later becomes two phases as glycerol separates. Methanol/oil molar ratios of 6∶1 were used at 23°C. The catalysts were sodium hydroxide (0.5, 1.0, and 2.0 wt%), potassium hydroxide (1.0 and 1.4 wt%), and sodium methoxide (0.5, 1.0, and 1.35 wt%), all concentrations being with respect to the oil. Oxolane (tetrahydrofuran) was used to form a single reaction phase. The reactions deviated from homogeneous kinetics as glycerol separated, taking with it most of the catalyst. When 1.0 wt% sodium hydroxide was used, the methyl ester content reached 97.5 wt% after 4 h, compared with 85–90 wt% in the two-phase reaction. Sodium hydroxide (1.0 wt%), sodium methoxide (1.35 wt%), and potassium hydroxide (1.4 wt%) gave similar results, presumably because the same number of moles was used. The ASTM biodiesel specification for chemically bound glycerol was achieved after only 3 min when 2.0 wt% sodium hydroxide was used. However, the standard was not achieved after 4 h when 1.0 wt% sodium hydroxide was used, the MG content being 1.1–1.6 wt%. The use of 2.0 wt% catalyst is commercially impractical.     

Emotion Recognition From Facial Expressions and Its Control Using Fuzzy Logic

This paper presents a fuzzy relational approach to human emotion recognition from facial expressions and its control. The proposed scheme uses external stimulus to excite specific emotions in human subjects whose facial expressions are analyzed by segmenting and localizing the individual frames into regions of interest. Selected facial features such as eye opening, mouth opening, and the length of eyebrow constriction are extracted from the localized regions, fuzzified, and mapped onto an emotion space by employing Mamdani-type relational models. A scheme for the validation of the system parameters is also presented. This paper also provides a fuzzy scheme for controlling the transition of emotion dynamics toward a desired state. Experimental results and computer simulations indicate that the proposed scheme for emotion recognition and control is simple and robust, with good accuracy.     

Automatic Clustering Using an Improved Differential Evolution Algorithm

Differential evolution (DE) has emerged as one of the fast, robust, and efficient global search heuristics of current interest. This paper describes an application of DE to the automatic clustering of large unlabeled data sets. In contrast to most of the existing clustering techniques, the proposed algorithm requires no prior knowledge of the data to be classified. Rather, it determines the optimal number of partitions of the data "on the run." Superiority of the new method is demonstrated by comparing it with two recently developed partitional clustering techniques and one popular hierarchical clustering algorithm. The partitional clustering algorithms are based on two powerful well-known optimization algorithms, namely the genetic algorithm and the particle swarm optimization. An interesting real-world application of the proposed method to automatic segmentation of images is also reported.     

Investigating the effect of production process of ball mill refiner on some physical quality parameters of compound chocolate: response surface methodology approach

Chocolate compound was produced using ball mill refiner, and the effect of agitator shaft speed and refining time on the physical quality parameters (particle size, colour and steady‐state rheology) of compound chocolate was determined using response surface methodology. The shaft speed and refining time range were selected between 40–60 r.p.m. and 10–30 min, respectively. Determination coefficient of the models established for particle size, Newtonian viscosity and colour parameters (brightness, chroma and hue angle) were found to be very close to unity. Increasing shaft speed and time induced a reduction in particle size and an increase in viscosity of the samples. Temperature sweep test was also performed, and the obtained data were successfully fitted to Arrhenius equation to calculate the corresponding parameters representing temperature dependency of the compounds. The results highlighted that the establishment of such models can provide essential information in terms of optimisation of production processes regarding usage purpose of the compound chocolate.     

Horizontal collaboration in semiconductor manufacturing industry supply chain: An evaluation of collaboration intensity index

This paper aims to provide a generic quantitative model to comprehensively assess the degree of collaboration with individual horizontal collaboration initiatives with a view to check feasibility for satisfying the customer requirements. The analytic hierarchy process–fuzzy logic model (AHP–FLM) approach is chosen for developing the model, a method that is often used to tackle complex strategic decision making that calls for subjective judgment based on well-established logical reasoning, rather than on simple feeling and intuition. In the process, the complex and unstructured problem for ‘compatibility test’ is broken down into elements, and then a customized hierarchy structure is set up to demonstrate the relationship between different hierarchy levels and among these elements. Each element may have a different level of importance for the horizontal collaboration. A fuzzy rule based collaboration intensity index (CII) is developed to build up the relationships among these evaluation attributes. Synthesizing the generic relative importance and the forecasted degree of collaboration, the proposed approach can determine the success of the collaboration initiative. An illustrative example of a semiconductor industry supply chain (SSC) member that intends to partner with a potential and competing candidate enterprise is developed to demonstrate the applicability of the proposed fuzzy strategic alliance selection framework and to measure the effectiveness of a horizontal collaboration initiative.     

Bio-fabrication of gold nanoparticles using aqueous extract of red tomato and its use as a colorimetric sensor

In this work, we report a green method for the synthesis of gold nanoparticles (GNP) using the aqueous extract of red tomato (Lycopersicon esculentum). We believe that citric acid and ascorbic acid present in tomato juice are responsible for the reduction of gold ions. This biosynthesized GNP in the presence of sodium dodecyl sulfate has been used as a colorimetric sensor to detect and estimate the pesticide, methyl parathion. The GNP in the presence of methyl parathion shows a new peak at 400 nm due to the formation of 4-nitrophenolate ion by catalytic hydrolysis of methyl parathion in alkaline medium. A calibration curve between the absorption coefficients of the 400-nm peak versus the concentration of the pesticide allows the quantitative estimation of the 4-nitrophenolate ion, thereby enabling indirect estimation of methyl parathion present in the system.     

TCP Over Optical Burst Switching: To Split or Not to Split?

TCP-based applications account for a majority of data traffic in the Internet; thus, understanding and improving the performance of TCP over optical burst switching (OBS) network is critical. In this paper, we identify the ill effects of implementing TCP over a hybrid network (IP-access and OBS-core). We propose a Split-TCP framework for the hybrid IP-OBS network to improve TCP performance. We propose two Split-TCP approaches, namely, 1:1:1 and N:1:N. We evaluate the performance of the proposed approaches over an IP-OBS hybrid network. Based on the simulation results, N:1:N Split-TCP approach outperforms all other approaches. We also develop an analytical model for end-to-end Split-TCP throughput and verify it with simulations.