Enhanced Photoelectrochemistry in CdS/Au Nanoparticle Bilayers

Three different configurations of Au‐nanoparticle/CdS‐nanoparticle arrays are organized on Au/quartz electrodes for enhanced photocurrent generation. In one configuration, Au‐nanoparticles are covalently linked to the electrode and the CdS‐nanoparticles are covalently linked to the bare Au‐nanoparticle assembly. The resulting photocurrent, φ = 7.5 %, is ca. 9‐fold higher than the photocurrent originating from a CdS‐nanoparticle layer that lacks the Au‐nanoparticles, φ = 0.8 %. The enhanced photocurrent in the Au/CdS nanoparticle array is attributed to effective charge separation of the electron–hole pair by the injection of conduction‐band electrons from the CdS‐ to the Au‐nanoparticles. Two other configurations involving electrostatically stabilized bipyridinium‐crosslinked Au/CdS or CdS/Au nanoparticle arrays were assembled on the Au/quartz crystal. The photocurrent quantum yields in the two systems are φ = 10 % and φ = 5 %, respectively. The photocurrents in control systems that include electrostatically bridged Au/CdS or CdS/Au nanoparticles by oligocationic units that lack electron‐acceptor units are substantially lower than the values observed in the analogous bipyridinium‐bridged systems. The enhanced photocurrents in the bipyridinium‐crosslinked systems is attributed to the stepwise electron transfer of conduction‐band electrons to the Au‐nanoparticles by the bipyridinium relay bridge, a process that stabilizes the electron–hole pair against recombination and leads to effective charge separation.     

Programmable group-delay module using binary polarization switching

We demonstrate the first programmable group-delay module based on polarization switching. With a unique binary tuning mechanism, the device can generate any differential group delay value from -45 to +45 ps with a resolution of 1.40 ps, or any true-time-delay value from 0 to 45 ps with a resolution of 0.7 ps. The delay varying speeds for both applications are under 1 ms and can be as fast as 0.1 ms. We evaluate both the dynamic and static performances of the device while paying special attention to its dynamic figures of merit for polarization-mode dispersion emulation and compensation applications. Our experiment shows that the device exhibits a negligible transient-effect induced power penalty (<0.2 dB) in a 10-Gb/s nonreturn-to-zero system.     

SNR analysis of crosstalk and filtering effects in an amplifiedmultichannel direct-detection dense-WDM system

An SNR analysis is presented for multichannel dense-WDM (wavelength-division-multiplexed) networks using optical amplifiers and optical filters. By using Lorentzian approximations for the amplified spontaneous emission and the optical and electrical bandwidths, simple expressions are derived for the relevant noise sources and crosstalk and filtering effects. Guidelines are stated for choosing appropriate optical filter widths and channel spacings to reduce power penalties. For any experimental system easily measurable quantities can be inserted into the analytical solutions to obtain close approximations for minimizing SNR degradation due to filtering and crosstalk     

Simple autocorrelation technique based on degree-of-polarization measurement

We demonstrate a simple optical-fiber-based autocorrelator for picosecond short pulses based on degree-of-polarization measurement while tuning the relative delay of the two orthogonal polarization states of the pulse. The pulsewidths of 20-, 40-, and 80-GHz pulse trains and 2-ps pulses generated by a mode-locked laser are measured. The <-10-dBm optical powers are used in the experiment. The measurement results agree well with the measurements using conventional techniques. Compared with conventional autocorrelators, this technique has the advantages of 1) wavelength independent, 2) significant less alignment, and 3) no high power required.     

A Preliminary Study of the Toxicological Properties of Selected Polymer–Ferrocene Conjugates

Prompted by early observations of the cytotoxic and antineoplastic properties of certain ferrocene and ferricenium derivatives, efforts in this laboratory were focused on the synthesis of carrier-bound ferrocene compounds. Subsequent cell culture tests carried out with selected conjugates obtained in that program showed these polymers to be highly active antiproliferative agents. In the present project toxicological work has been performed in vivo on several ferrocene conjugates in an effort to assess their toxic effects in experimental animals (CD-1 mice). The conjugates, all based on an ,-DL-polyaspartamide backbone structure, comprise the ferrocene drug model as a terminal on short side chains containing biofissionable amide or ester links for intracellular drug release. The polymers, dissolved in phosphate-buffered saline, have been injected in predetermined concentrations into the vein of the mice, and the maximum tolerated dose (MTD) levels have been determined, the latter referring to the highest dose levels administered that would allow long-term survival of the test animals. For the five conjugates tested, MTD levels range from about 3 to 30 mg Fe/kg or 0.05–0.66 mmol Fe/kg. Compared on a molar metal-to-metal basis with similarly structured platinum conjugates tested previously (MTD, 0.14–2.66 mmol Pt/kg), these values are indicative of comparatively high toxicity of the ferrocene polymers. Some implications of these findings are discussed.     

Independent and Simultaneous Monitoring of Chromatic and Polarization-Mode Dispersion in OOK and DPSK Transmission

We propose and demonstrate a novel technique for a simultaneous chromatic and first-order polarization-mode-dispersion (PMD) monitoring method using a partial bit delay Mach-Zehnder interferometer (MZI) with radio-frequency (RF) clock tone monitoring. RF clock tones at the output of the two branches of the MZI behave oppositely with increasing chromatic dispersion (CD) which improves the sensitivity of the measurement. The technique increases CD monitoring sensitivity over standard clock tone methods by a factor of two for a nonreturn-to-zero intensity modulation format and a factor of five for a differential-phase-shift-keying modulation format. The accuracy of PMD monitoring is also enhanced. Moreover, the partial bit delay allows the signal to pass through the constructive branch of the MZI with no observable degradation of the signal quality, allowing it to be normally detected by a receiver     

Lanthanide oxide-doped titanium dioxide: Effective photocatalysts for the degradation of organic pollutants

A series of lanthanide oxide-doped titanium dioxide photocatalysts Ln₂O₃/TiO₂ (Ln³⁺ = Eu³⁺, Pr³⁺, Yb³⁺) were prepared. The photocatalysts reveal a substantially enhanced activity for the degradation of organic pollutants, as compared to undoped TiO₂. The photodegradation processes of p-nitrobenzoic acid, (1), p-chlorophenoxyacetic acid, (2), aniline, (3), salicylic acid, (4), and trans-cinnamic acid, (5), with the different photocatalysts was examined. The photodegradation of (1)–(5) is significantly faster with Ln₂O₃/TiO₂ photocatalysts and leads to complete mineralization of the organic compounds. The high activity of the Ln₂O₃/TiO₂ photocatalysts is attributed to the enhanced association of the functionalized organic pollutants to lanthanide-ion surface sites.