Preparation and electrochemical characterization of Ti-based amorphous metallic glass with high strength

Ti-based amorphous metallic glasses have excellent mechanical, physical, and chemical properties, which is an important development direction and research hotspot of metal composite reinforcement. As a stable, simple, efficient, and large-scale preparation technology of metallic powders, the gas atomization process provides an effective way of preparing amorphous metallic glasses. In this study, the controllable fabrication of a Ti-based amorphous powder, with high efficiency, has been realized by using gas atomization. The scanning electron microscope, energy-dispersive spectrometer, and X-ray diffraction are used to analyze surface morphology, element distribution, and phase structure, respectively. A microhardness tester is used to measure the mechanical property. An electrochemical workstation is used to characterize corrosion behavior. The results show that as-prepared microparticles are more uniform and exhibit good amorphous characteristics. The mechanical test shows that the hardness of amorphous powder is significantly increased as compared with that before preparation, which has the prospect of being an important part of engineering reinforced materials. Further electrochemical measurement shows that the corrosion resistance of the as-prepared sample is also significantly improved. This study has laid a solid foundation for expanding applications of Ti-based metallic glasses, especially in heavy-duty and corrosive domains.     

滚筒位置参数及摇臂厚度对装煤性能的影响研究

采煤机作为综采工作面的关键设备,其性能直接决定工作面的生产能力,为进一步提升工作面生产能力,在研究滚筒采煤机装煤理论的基础上,基于现有工作面采煤机的参数分别对滚筒位置参数和摇臂厚度对采煤机装煤性能的影响机理进行研究,为后续改进采煤机的结构参数和生产过程中位置参数奠定扎实的理论基础.     

In-Situ observation on microfracture behavior ahead of the crack tip in 63Sn37Pb solder alloy

in-situ transmission electron microscopy (TEM) tensile tests on as-cast and aged 63Sn37Pb solder alloys were conducted, and the fracture behavior in nanometer scale ahead of the crack tip was inspected and discussed. Results show that the fracture was completed by connecting the discontinuous cracks or voids. Dislocation behavior was concentrated along the grain boundaries for as-cast samples, and displayed mainly as dislocation climb. The crack was intergranular dominated under the lower strain rate. While remarkable mutual dislocation emission was detected in the aged solder. Transgranular cracks were dominant in the fractured area, and they propagated by linking up with the nanometer scale cracks ahead of the crack tips under the effective promotion of the inverse dislocation emission. At the same time, the partial interphase or intergranular cracks in the thinned area were also found. Under this condition, a new critical stress intensity factor K _c ^′ to define the mutual dislocation emission was proposed.     

激光光束质量因子M~2的物理概念与测试方法

激光光束传输质量因子Ｍ２是一种全新的描述激光光束质量的参数，它能定量表征单模、多模光束传播特性。本文介绍Ｍ２的物理概念、特点、测试方法及近年来国外的研究概况。     

济南市1972─2016年降水特性

运用线性滑动平均、Mann-Kendall非参数趋势检验、Sen′s坡度、小波分析及多元线性回归方法,选取济南市24个降水站点45年(1972—2016年)逐日降水资料,分析了济南市在年和季节尺度上的降水特征以及降水量的决定性影响因素。结果表明:年降水量以8.23mm/(10a)的速率增加,且呈现出丰枯交替的变化周期,最大主周期为10a;降水量主要集中在夏季,占全年降水量的64.5%,冬季降水占比最小,占全年降水量的3.4%,春、夏和冬季降水具有不显著增加趋势,秋季的降水量具有不显著下降趋势;降水量的年际、春夏季变化主要受降水强度变化的影响;秋冬季变化则主要受降水频率变化的影响。     

PVP-assisted Sn-Ti microspheres for the efficient B–V oxidation of cyclohexanone

Journal of Porous Materials - New Sn-Ti microspheres were first successfully synthesized by a PVP-assisted sol-gel method in this paper, and their performance in the B–V oxidation of...     

住房支出对我国城镇居民消费的影响研究——基于中、美、日3国数据分析

自1998年实行全面住房改革以来,我国房地产市场持续繁荣,居民住房支出在居民收入中所占比例不断提高,对居民消费影响显著.将住房支出区分为住房购置支出和居住性支出,以1992-2019年我国城镇居民的相关数据为依据构建回归模型,探究两类支出变动对居民消费的影响效应,同时构建美国、日本2个国家的时间序列模型进行对比研究.结果 表明:我国城镇居民住房购置支出、居住性支出对居民消费均具有一定程度的挤出效应;美日两国居民住房购置支出上升在一定程度上能够刺激消费,居住性支出上升对美国居民消费无显著影响,对日本居民消费起正向促进作用.基于以上结论,提出了引导居民住房消费理念、加强房地产市场监管、完善房地产金融市场的对策建议.     

Adjusting Pt Nanoparticle Size on SBA-15 by a Sol-Immobilisation Method Towards Naphthalene Hydrogenation

Regularly dispersed Pt particles on SBA-15 supported catalysts were synthesized with a Pt loading of 5 wt% by a sol-immobilisation method, wherein various Pt particle sizes within 1–5 nm were finely controlled via the adjustment of the addition amount of polyvinyl alcohol (PVA). A high PVA/Pt ratio of the initial solution tended to generate small Pt particles on the SBA-15 support due to intense protection against Pt particle aggregation. In addition, the effect of Pt particle size on naphthalene hydrogenation was investigated in terms of catalytic performance. Compared with the performance of other catalysts with Pt particle sizes greater or less than 3.5 nm, Pt nanoparticles with sizes centered at 3.5 nm exhibited excellent catalytic performance towards decalin. This excellent catalytic performance was mainly attributed to a suitable ratio of the edge sites to flat sites on these Pt nanoparticles, benefitting the rapid adsorption of naphthalene and dissociation of hydrogen.

Graphical Abstract

The Pt/SBA-15 catalysts were prepared by sol-immobilisation method. The highest performance was attributed to the Pt-nanoparticles with suitable flat/edge sites ratio.

     

少齿差行星齿轮传动轮齿载荷研究

在少齿差行星齿轮传动中,轮齿的弹性变形可能导致多对齿同时接触共同承载,啮合情况复杂,故建立数学模型对其啮合情况进行分析,并通过有限元仿真对同时啮合齿对数、载荷分配情况、相对误差等方面进行相应的分析,验证了模型的正确性.计算结果表明,处于啮合线上的齿对仅承担了部分载荷,故对齿根弯曲应力计算公式亦进行了适当修正.     

Properties of thermally conductive silicone rubbers filled with admicellar polymerized polypyrrole-coated Al2O3 particles

Polypyrrole (PPy) nanolayers were introduced on the surface of alumina (Al₂O₃) particles via admicellar polymerization. The properties of silicone rubbers (SRs) filled with PPy-coated Al₂O₃ and pristine Al₂O₃ as thermally conductive fillers were studied and compared. The results demonstrate that the addition of PPy-coated Al₂O₃ leads to a better interfacial compatibility but lower cross-linking density of the composites than pristine Al₂O₃. The improvement in the compatibility and the decrease in the cross-linking density are paradoxes in affecting mechanical properties. The improvement in the compatibility shows a slight predominance on the strength at low-filler contents. Lower cross-linking density of modified-Al₂O₃/SR composites led to a better processing performance and a higher maximum filler loading amount than the pristine Al₂O₃/SR composites, which is beneficial to increasing the thermal conductivity and maintaining a relatively good strength. The PPy-coated Al₂O₃/SR composite with 83 wt% filler content has a thermal conductivity of 1.98 W/(m K) and a tensile strength of 2.9 MPa, and the elongation at break was 63%. Functionalized fillers by admicellar polymerization used in the fabrication of filler/SR composites not only improve the interfacial compatibility but also optimize and expand the functions of the composites, which has great significance for the production and application of thermally conductive SR in some branches of industry (automotive, electrical engineering, etc.) in the future.