Meticulous analysis and consequences of microstructure changes on melt rheology and dynamic viscoelasticity of thermoplastic vulcanizates upon reprocessing

Thermoplastic vulcanizates (TPVs), which are a special class of elastomer alloy, prepared by dynamic vulcanization possess unique morphology of finely dispersed micron‐size cross‐linked elastomeric particles in a continuous thermoplastic matrix. The present study investigates the microstructure formation of elastomeric phase and its associated morphological changes during reprocessing of TPVs based on poly[styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene] triblock co‐polymer (S‐EB‐S) and solution polymerized styrene butadiene elastomer (S‐SBR) by scanning electron microscopy and atomic force microscopy. Semi‐efficient and efficient sulfur‐based curing systems have been adopted to cure the elastomeric phase and a comparative study has been made to demonstrate and explain the effect of reprocessing on the melt rheology and dynamic viscoelasticity of the TPVs. The present work also provides a better insight and guidance to control the microstructure of the cross‐linked elastomeric phase to prepare selectively co‐continuous or dispersed phase morphology. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41182.     

Reduction of hexavalent chromium by Bacillus sp. isolated from chromite mine soils and characterization of reduced product

BACKGROUND: The reduction of highly mobile and toxic hexavalent chromium by bacterial strains is considered to be a viable alternative to reduce Cr(VI) contamination, in soils and water bodies, emanating from the overburden dumps of chromite ores and mine drainage. The present study reports the isolation of Cr(VI) resistant bacterial strains from an Indian chromite mine soil and their potential use in reduction of hexavalent chromium. RESULTS: Among the isolates, a bacterial strain (CSB‐4) was identified as Bacillus sp. based on standard biochemical tests and partial 16SrRNA gene sequencing, which was tolerant to as high as 2000 mg L^?1 Cr(VI) concentration. The strain was capable of reducing Cr(VI) to Cr(III) in different growth media. Under the optimized conditions pH ～7.0, 100 mg L^?1 Cr(VI), 35 °C temperature and stirring speed 100 rpm, CSB‐4 reduced more than 90% of Cr(VI) in 144 h. The time course reduction data fitted well an exponential rate equation yielding rate constants in the range 3.22 × 10^?2 to 6.5 × 10^?3 h^?1 for Cr(VI) concentration of 10–500 mg L^?1. The activation energy derived from temperature dependence rate constants between 25 and 35 °C was found to be 99 kJ mol^?1. The characterization of reduced product associated with bacterial cells by SEM‐EDS, FT‐IR and XRD was also reported. CONCLUSION: Reasonably high tolerance and reduction ability of indigenous Bacillus sp. (CSB‐4) for Cr(VI) under a wide range of experimental conditions show promise for its possible use in reclamation of chromite ore mine areas including soils and water bodies. Copyright © 2010 Society of Chemical Industry     

Majorisations for the eigenvectors of graph-adjacency matrices

We develop majorisation results that characterise changes in eigenvector components of a graph's adjacency matrix when its topology is changed. Specifically, for general (weighted, directed) graphs, we characterise changes in dominant eigenvector components for single- and multi-row incrementations. We also show that topology changes can be tailored to set ratios between the components of the dominant eigenvector. For more limited graph classes (specifically, undirected, and reversibly-structured ones), majorisations for components of the subdominant and other eigenvectors upon graph modifications are also obtained.     

Influence of pentavalent dopant addition to polarization and bioactivity of hydroxyapatite

Influence of pentavalent tantalum doping in bulk hydroxyapatite (HAp) ceramics has been investigated for polarizability and bioactivity. Phase analysis from X-ray diffraction measurement indicates that increasing dopant concentration decreased the amount of HAp phase and increased β-TCP and/or α-TCP phases during sintering at 1250 °C in a muffle furnace. Results from thermally stimulated depolarization current (TSDC) measurements showed that doping hindered charge storage ability in HAp ceramics, and doped samples stored fewer charge compared to pure HAp. However, doping enhanced wettability of HAp samples, which was improved further due to polarization. In vitro human osteoblast cell–material interaction study revealed an increase in bioactivity due to dopant addition and polarization compared to pure HAp. This increase in bioactivity was attributed to the increase in wettability due to surface charge and dopant addition.     

Simultaneous abatement of diesel soot and NOX emissions by effective catalysts at low temperature: An overview

The diesel engine generally achieves the highest fuel, energy, and thermal efficiency due to its very high compression/expansion ratio (14:1 to 25:1). Diesel engines can have a thermal efficiency that exceeds 50%. The main problem is that they emit more pollution like fine black soot particulates (C₈H to C₁₀H) and nitrogen oxides (NO_X). These pollutants have been causing serious problems for human health and the global environment and also impacts on the engine. There are many types of catalysts investigated for simultaneous control of these two pollutants, i.e., platinum group metals (PGM; Pt, Pd, Rh, and Ir) based, spinel-type oxides, hydrotalcite, rare earth metal oxides, mixed transient metal oxides, etc. The high raw material cost of PGM catalysts has become a significant issue, so developing non-PGM catalysts are one of the promising challenges. There are no extra reductants required because soot catalytically oxidizes itself in the presence of NO_X at a faster rate than molecular oxygen and simultaneously NO_X is reduced to nitrogen. The order of oxidation potential of NO_X to oxidized soot in comparison to molecular oxygen is as follows: NO₂ > NO > O₂. To meet the very strict EPA US 2010 and Euro VI regulations of particulate matter (PM) and NO_X for heavy-duty and light-duty vehicular stringent emission, it is very important to apply the integrated catalytic systems to significantly remove PM and NO_X simultaneously. Many papers related to simultaneous control of soot and NO_X over different catalysts have been published but till now some of effective catalysts showing high conversion at low temperatures (possibly within the range typical of diesel exhaust: 150–450°C) have not been reviewed. Thus, this article provides a summary of published information regarding the effective catalysts, their preparation methods, properties, and application for simultaneous control of diesel soot and NO_X.     

Al and Al-TiB2 Foams Produced by Melt Injection Technique

Transactions of the Indian Institute of Metals - Aluminium and Al-TiB2 closed-cell foams were produced by a recently developed foaming method called melt injection technique where bubbles are...     

Biological fixation of subtrochanteric fractures by external fixation

Fifty-one subtrochanteric fractures have been stabilized by external fixation over the last 9 years. Union occurred in all types of fractures, usually within 6 months. Soft tissue interposition led to non-union in three patients. Refracture in one patient and significant limb-length discrepancy in two patients was seen. The technique is versatile, easily reproducible and 'biological'. Protected weight-bearing is not necessary after removal.     

Local open‐ and closed‐loop manipulation of multiagent networks

The manipulation of networked cyberphysical devices via local external actuation or feedback control is explored, in the context of a canonical multiagent dynamical system that is engaged in a consensus or synchronization task. One main focus is to understand whether or not, and how easily, a stakeholder can manipulate the full network's dynamics by hijacking only one agent's actuation signal. Explicit spectral characterizations are given of the energy (effort) required to manipulate the dynamics. These characterizations are used to (1) gain structural insights into ease of manipulation, (2) show that manipulation along the consensus manifold is easy, and (3) address network design to enable or prevent manipulation. Additionally, it is shown that the multiagent system can be manipulated effectively along the consensus manifold using local feedback controls, which do not require model knowledge or wide‐area measurements.     

Cauchy with whale optimizer based eagle strategy for multi-level color hematology image segmentation

Neural Computing and Applications - Pathological color image segmentation is an exigent procedure due to the existence of imperceptibly correlated, and indistinct multiple regions of concern....