Thin microwire with negative magnetostriction in a zero magnetic field

The effect of residual mechanical stresses on the distribution of magnetization in thin metal microwires with negative magnetostriction has been studied in a zero magnetic field. It is established that the microwire has a nonzero residual magnetization in the absence of twisting and bulging rotational modes.     

Atmospheric corrosion of reference metals in Antarctic sites

This paper presents the results obtained at three Antarctic test sites participating in the “Ibero-American Map of Atmospheric Corrosiveness” (MICAT), a project on atmospheric corrosion carried out during the period 1988–1994 at some 70 sites distributed across 12 countries of the Latin-American region, Spain and Portugal. The three Antarctic sites are located near the coastline.The singular climatic characteristics of Antarctic regions are related with the purity of the air, the absence of rainfall and the formation of ice on the metallic surface during an important part of the exposure time. However, electrochemical activity is possible below ice layers. This situation affects the structure and morphology of corrosion product films and the resulting corrosion rates of metallic surfaces.     

Dynamics and linear stability of charged jets in dielectric liquids

The physical system to be considered is a blade-plane configuration in a dielectric liquid. For high electric fields, injection from the blade takes place with ions of the same polarity. The Coulomb force acting upon the injected charges originates an electrohydrodynamic (EHD) flow, referred in what follows as the charged jet. A laminar solution of this EHD jet is obtained using similarity analysis. If transport of charge is dominated by convection, i.e., neglecting molecular diffusion and ion drift, and the electric field is assumed constant, the problem is mathematically equivalent to the bidimensional thermal plume in the limit of large Prandtl numbers. The authors examine the stability of this EHD jet using linear theory and parallel-flow approximations. Neutral stability curves are computed numerically in terms of a nondimensional parameter which is the electrical analogous to the Grashof number. Finally, some experimental observations are presented, followed by a short discussion. The role played by the viscosity correlates reasonable well with the theoretical analysis     

Use of 3D modelling and several ultrasound sensors to assess overflow rate.

A new instrumentation mode has been put in place in order to determine the overflow rate of five complex CSOs of the system in Sélestat (French), which are subject to self monitoring. 3D and 1D models have made it possible to predict the shapes of the water lines and suggest a location for the ultrasound sensors. In order to validate the instrumentation principle, three overhead sensors were placed on a weir. The overflow laws suggested are of the type Q(overflow) = a1h1b1 + a2h2b2 + a3h3b3. Early results of the overflow rate that have been obtained by applying the law are close to 10 % of the flow measured in the physical test bench. On the actual site, the ultrasound sensors were assembled on a rail covering the entire weir in order to be able to change their position in future after models calibration.     

Graft copolymerization of different mixtures of acrylic monomers on amylopectin. Swelling behavior

Hydroxylic and nonhydroxylic acrylates—methyl acrylate (MA), ethyl acrylate (EA), butylacrylate (BA), hydroxypropyl methacrylate (HPMA), ethylenglycol dimethacrylate (EGDMA), and mixtures of HPMA–MA, HPMA–EA, HPMA–BA in a 50/50 feed composition—were grafted onto amylopectin with different amounts of crosslinking agent, EGDMA. Percent of total conversion, percent crude grafting, and influence of pH in water content were studied. In this sense it was only at pH 10 when a real variation in the water content could be seen. It was also proved that the highest values were obtained when one of the comonomers was EGDMA with a 34 mol% of the initial feed composition. © 1994 John Wiley & Sons, Inc.     

Mechanical properties and thermal stability of rice husk ash filled epoxy foams

Mechanical properties and thermal stability of epoxy foams filled with white and black rice husk ash were studied. Epoxy foams were prepared from a commercial system and filled with different amounts of both the ashes (0, 6.8, 12.8, 18.0, and 22.7 wt %). The incorporation of both the ashes modified the final morphology of the foam, decreasing the average cell size and increasing the number of cells per volume unit. For all filler percentages used, the specific modulus and strength results showed that the white ash is more effective as reinforcing agent than the black ash. The initial degradation temperature was not affected by the content and type of ash used as the filler. The integral procedure decomposition temperature, weight loss, and char residue results were related to the ash type and atmosphere used in the thermogravimetric analysis. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci, 2006     

Electrochemical,FTIR and morphological study of polypyrrole—Polystyrenesulphonate conducting films

The electrochemical behaviour, FTIR spectrum and the morphology of polypyrrole-polystyrenesulphonate (PPy-PSS) films obtained potentiostatically at 0.6 V in a 0.05m Py + 1.7 × 10^?2m NaPSS medium have been analysed. Different electrochemical parameters have been modified in order to establish the first polaron formation, the reversibility of the redox process and the doping mechanism. The FTIR spectrum confirms the existence of C?O groups in the film structure and two possible explanations are suggested. SEM reveals a higher homogeneity in these films than in PPy films doped with smaller counterions.     

Study of the impedance of a platinum electrode in the system Br2/Br (HClO4, aq.)—II. Mechanism of the electrode reaction

The Randles circuit well represents impedance measurements carried out with activated Pt electrodes. This enables us to study the variation of j_o for redox reactions with concentration of the reactants, at constant potential, and also the variation of j_o with potential, keeping constant the concentration of one of the reactants. The results thus obtained indicate that the step Br₂ + e Br₂⁻ is rate-determining; it is followed or preceded by the rapid equilibria Br₂⁻ Br⁻ + Br 2Br Br₂. The mechanisms proposed hitherto for the electrochemical behaviour of the halogen/halide systems at inert electrodes are discussed, and it is reasoned that the ‘reversibility’ of these systems increases in the order Cl₂/Cl⁻ < Br₂/Br⁻ < I₂/I.     

Control of 1-D parabolic PDEs with Volterra nonlinearities, Part I: Design

Boundary control of nonlinear parabolic PDEs is an open problem with applications that include fluids, thermal, chemically-reacting, and plasma systems. In this paper we present stabilizing control designs for a broad class of nonlinear parabolic PDEs in 1-D. Our approach is a direct infinite dimensional extension of the finite-dimensional feedback linearization/backstepping approaches and employs spatial Volterra series nonlinear operators both in the transformation to a stable linear PDE and in the feedback law. The control law design consists of solving a recursive sequence of linear hyperbolic PDEs for the gain kernels of the spatial Volterra nonlinear control operator. These PDEs evolve on domains T_n of increasing dimensions n+1 and with a domain shape in the form of a “hyper-pyramid”, 0≤ξ_n≤ξ_n−1?≤ξ₁≤x≤1. We illustrate our design method with several examples. One of the examples is analytical, while in the remaining two examples the controller is numerically approximated. For all the examples we include simulations, showing blow up in open loop, and stabilization for large initial conditions in closed loop. In a companion paper we give a theoretical study of the properties of the transformation, showing global convergence of the transformation and of the control law nonlinear Volterra operators, and explicitly constructing the inverse of the feedback linearizing Volterra transformation; this, in turn, allows us to prove L² and H¹ local exponential stability (with an estimate of the region of attraction where possible) and explicitly construct the exponentially decaying closed loop solutions.