Inorganic–organic hybrid materials are attracting a strong scientific interest mainly for their outstanding inherent mechanical and thermal properties, which can be traced back to the intimate coupling of both inorganic and organic components. By carefully choosing the experimental parameters used for their synthesis, chemically and thermally stable acrylate-based hybrid material embedding the zirconium oxocluster Zr4O4(OMc)12, where OMcCH2C(CH3)C(O)O, can be deposited as UV-cured films on aluminium alloys.
In particular, the molar ratios between the oxocluster and the monomer, the polymerisation time, the amount of photo-initiator and the deposition conditions, by using an home-made spray-coating equipment, were optimised in order to obtain the best performing layers in terms of transparency and hardness to coat aluminium alloy (AA1050, AA6060 and AA2024) sheets. Furthermore, it was also evaluated whether the hybrid coatings behave as barrier to corrosion.
Several coated samples were prepared and characterised. Environmental scanning electronic microscopy (ESEM) and scratch test were used to investigate the morphology of the films and to evaluate their scratch resistance, respectively. Electrochemical impedance spectroscopy (EIS) was performed in order to evaluate if the coatings actually protect the metallic substrate from corrosion.
In order to measure shear storage modulus (G′) and loss modulus (G″) of the materials used for coatings, bulk samples were also obtained by UV-curing of the precursors solution. Dynamical mechanical thermal analysis (DMTA) was performed in shear mode on cured disks of both the hybrid materials and pristine polymer for comparison. The values of Tg were read off as the temperatures of peak of loss modulus. The length and mass of all the samples were measured before and after the DMTA analysis, so that the shrinkage of the materials in that temperature range was exactly evaluated. 相似文献
Manual responses can be defined by differing response parameters. Any of them may generate a Simon effect. For all those response parameters, the same implementation of the Simon effect (in terms of subserving mechanism) is assumed. In 3 experiments, subjects had to respond with either fingers or sticks. Temporal properties of the Simon effect changed with response parameters relevant in a task. The Simon effect for manual responses decayed. For stick responses, in which the action goal differed from the anatomical mapping of the acting hand, a sustained Simon effect was observed. However, if the action goal for stick responses was not instrumental for selecting the correct response, the Simon effect decayed. The findings are consistent with the notion of different mechanisms involved in generating a Simon effect. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
A cook has to prepare n cakes using an oven with two racks. According to the recipe, the i-th cake has to be baked for exactly ai minutes. Cakes to be cooked are taken from a table and carried to the oven, and once cooked are carried back to the table by means of a trolley that can carry two cakes at a time. What is the minimum number q* of round trips required of the cook? This problem has application to the operation scheduling of transportation systems and to material cutting. A different problem arises according to whether the cook accepts or not to stay near the oven for awhile with the trolley. If the trolley cannot be idle at the oven, an optimum schedule with no oven idle-time always exists: consequently, the trolley schedule is trivial, and the problem is transformed into a set packing. For this case, we propose and test a heuristic method which generates all of the promising columns of the set packing, and solves the resulting problem by branch-and-bound. Instead, if the trolley can be idle at the oven for a limited amount of time, a problem arises to find an optimal schedule of the trolley: in this case we show how to use a scaling technique in order to obtain a very good feasible solution by the method above. 相似文献
We have used two dimensional drift diffusion simulations to calculate the electrical properties of bottom contact pentacene based organic thin film transistor, taking into account field-dependent mobility and interface or bulk trap states. In order to derive from basic principles the transport properties of the organic semiconductor we have developed a Monte Carlo simulator to calculate the field dependent mobility. We analyzed the presence of trap states at the interface between organic material and gate insulator and we show the influence of trap states combined with the effect of field-dependent mobility on the transfer characteristic. Numerical calculations are also reported for the output characteristics of the device showing a very good agreement with the available experimental results. 相似文献
The previous on-line LC-GC method for the direct analysis of the minor components in oils and fats (without cleavage of esters) was modified: The free alcohols/sterols were silylated instead of acylated, and the LC fraction transferred to GC is widened to range from the beginning of the LC chromatogram up to the sterol esters. Silylation eliminated the problem that acylation may esterify some free alcohols with free fatty acids from the oil if the oil or fat is of high acidity. Widening of the LC fraction to include squalene and the tocopherols added information to that previously obtained. 相似文献
The computational method for large deformation plasticity called differential equations on a manifold (DEM) has previously been shown to be effective for axisymmetric and plane strain sheet metal forming problems. The method has now been formulated for in-plane stretching problems, incorporated into a computer code, and applied to several problems. The code's performance is robust and accurate, as evidenced by a comparison with other published results. Incorporation of an automatic mesh generator significantly reduces data preparation time. 相似文献