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Louise Therese Pick Eileen Harkin‐Jones Maria Jovita Oliveira Maria Clara Cramez 《应用聚合物科学杂志》2006,101(3):1963-1971
This article examines changes to the morphology of rotationally molded metallocene catalyzed linear low density polyethylene brought about by varying the cooling rate during processing. These changes in morphology lead to variations in the impact performance, which is reflected in the dynamic mechanical characteristics of the materials. Various analytical techniques are used in an attempt to explain the differences in impact behavior. Slow cooling is shown to result in high crystallinity, and in the formation of large spherulites, which in turn is detrimental to the impact performance of the material, particularly at low temperatures. The high crystallinity corresponds with a shift in the β transition of the material to a higher temperature, and is shown to result in a higher brittle–ductile transition. A case study was also carried out on samples from a finished part provided by an industrial molder, one section of which failed in a brittle manner when impact tested while the other failed in a ductile manner. Microscopy results showed that the brittle material had large spherulites at the inside surface, while the ductile material showed incipient degradation at this surface, which has previously been shown to be of benefit to impact strength in rotationally molded parts. Dynamic mechanical studies again showed a β transition at a higher temperature in the brittle samples. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 1963–1971, 2006 相似文献
4.
Muñoz-Ramírez David-Octavio García-Salgado Beatriz-Paulina Ponomaryov Volodymyr Reyes-Reyes Rogelio Sadovnychiy Sergiy Cruz-Ramos Clara 《Multimedia Tools and Applications》2021,80(9):13707-13734
Multimedia Tools and Applications - The copyright protection of three-dimensional (3D) content is a matter of interest in artistic and creative works due to the rights of the holder for the... 相似文献
5.
Clara Silvia Roero 《Nexus Network Journal》2009,11(3):415-439
Guarini considered the mathematical studies to be of fundamental importance for all artists and scholars. His own knowledge
of mathematics was vast and profound. The aim of this present paper is to show, through an analysis of the most substantial
of his mathematical works, Euclides adauctus, along with the Appendix to this printed a few months later, the role that philosophical and mathematical studies had on his cultural formation, on
the new and original research that he conducted, and on his teaching activities, while looking for traces of the mathematical
sources that he consulted and cited that indicate which authors and works exerted the greatest influence on him. 相似文献
6.
Psychotherapy studies published in the Journal of Counseling Psychology (JCP) and the Journal of Consulting and Clinical Psychology (JCCP) between 1978 and 1992 were examined. Differences were found between the 2 journals. JCP published mostly process, outcome, and analog research, whereas JCCP published mostly outcome research. Most process and process-outcome studies across journals were of individual, brief therapy. Across the years, more diversity was evident in samples used in process research in terms of student status, gender, and race of clients and therapists. Three content areas were prominent in the process measures and classic studies: therapist techniques, therapist influence, and facilitative conditions. Lists are provided of the frequently used measures, most productive authors, and classic studies in process research. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
7.
Lei Cao Da-Wei Zhang Clara Mihaela Ionescu Guo-Ping Liu 《Asian journal of control》2023,25(5):3978-3991
In this paper, the formation consensus problem for a class of leader–follower networked multi-agent systems under communication constraints and switching topologies is investigated. A networked predictive control scheme is proposed to achieve stability and output formation consensus with the switching topology, capable of compensating for data loss and time delays in the network. By equating the whole closed-loop networked multi-agent system with the proposed control scheme to the corresponding switched system, the sufficient and necessary condition of output formation consensus and stability for agents is given. Finally, using three-degree-of-freedom air-bearing spacecraft simulators as the control objects, the proposed scheme is demonstrated to be able to actively compensate for the communication constraints through numerical simulations, and it is also verified to have a good control performance by further realizing the formation task of the simulators through practical experiments. 相似文献
8.
Clara Mata Ellen K. Longmire David H. McKenna Katie K. Glass Allison Hubel 《Microfluidics and nanofluidics》2008,5(4):529-540
A recently proposed application of microfluidics is the post-thaw processing of biological cells. Numerical simulations suggest
that diffusion-based extraction of the cryoprotective agent dimethyl sulfoxide (DMSO) from blood cells is viable and more
efficient than centrifugation, the conventional method of DMSO removal. In order to validate the theoretical model used in
these simulations, a prototype was built and the flow of two parallel streams, a suspension of Jurkat cells containing DMSO
and a wash stream that contained neither cells nor DMSO, was characterized experimentally. DMSO transport in a rectangular
channel (depth 500 μm, width 25 mm and overall length 125 mm) was studied as a function of three dimensionless parameters:
depth ratio of the streams, cell volume fraction in the cell solution, and the Peclet number (Pe) based on channel depth, average flow rate and the diffusion coefficient for DMSO in water. In our studies, values of Pe ranged from O(103) to O(104). Laminar flow was ensured by keeping the Reynolds number between O(1) and O(10). Experimental results based on visual and
quantitative data demonstrate conclusively that a microfluidic device can effectively remove DMSO from liquid and cell laden
streams without compromising cell recovery. Also, flow conditions in the microfluidic device appear to have no adverse effect
on cell viability at the outlet. Further, the results demonstrate that we can predict the amount of DMSO removed from a given
device with the theoretical model mentioned previously. 相似文献
9.
Leonel Pekarek Basilio De la Torre-Escuredo Oscar Fraile-Martinez Cielo García-Montero Miguel A. Saez David Cobo-Prieto Luis G. Guijarro Jose V. Saz Patricia De Castro-Martinez Diego Torres-Carranza Tatiana Pekarek Ana Clara Carrera Melchor Alvarez-Mon Miguel A. Ortega 《International journal of molecular sciences》2022,23(23)
Osteosarcoma represents a rare cause of cancer in the general population, accounting for <1% of malignant neoplasms globally. Nonetheless, it represents the main cause of malignant bone neoplasm in children, adolescents and young adults under 20 years of age. It also presents another peak of incidence in people over 50 years of age and is associated with rheumatic diseases. Numerous environmental risk factors, such as bone diseases, genetics and a history of previous neoplasms, have been widely described in the literature, which allows monitoring a certain group of patients. Diagnosis requires numerous imaging tests that make it possible to stratify both the local involvement of the disease and its distant spread, which ominously determines the prognosis. Thanks to various clinical trials, the usefulness of different chemotherapy regimens, radiotherapy and surgical techniques with radical intent has now been demonstrated; these represent improvements in both prognosis and therapeutic approaches. Osteosarcoma patients should be evaluated in reference centres by multidisciplinary committees with extensive experience in proper management. Although numerous genetic and rheumatological diseases and risk factors have been described, the use of serological, genetic or other biomarkers has been limited in clinical practice compared to other neoplasms. This limits both the initial follow-up of these patients and screening in populations at risk. In addition, we cannot forget that the diagnosis is mainly based on the direct biopsy of the lesion and imaging tests, which illustrates the need to study new diagnostic alternatives. Therefore, the purpose of this study is to review the natural history of the disease and describe the main biomarkers, explaining their clinical uses, prognosis and limitations. 相似文献
10.
Ana Filipa Fernandes Luís Gafeira Gonalves Maria Bento Sandra I. Anjo Bruno Manadas Clara Barroso Miguel Villar Rita Macedo Maria Joo Simes Ana Varela Coelho 《International journal of molecular sciences》2022,23(22)
Tuberculosis (TB) is a transmissible disease listed as one of the 10 leading causes of death worldwide (10 million infected in 2019). A swift and precise diagnosis is essential to forestall its transmission, for which the discovery of effective diagnostic biomarkers is crucial. In this study, we aimed to discover molecular biomarkers for the early diagnosis of tuberculosis. Two independent cohorts comprising 29 and 34 subjects were assayed by proteomics, and 49 were included for metabolomic analysis. All subjects were arranged into three experimental groups—healthy controls (controls), latent TB infection (LTBI), and TB patients. LC-MS/MS blood serum protein and metabolite levels were submitted to univariate, multivariate, and ROC analysis. From the 149 proteins quantified in the discovery set, 25 were found to be differentially abundant between controls and TB patients. The AUC, specificity, and sensitivity, determined by ROC statistical analysis of the model composed of four of these proteins considering both proteomic sets, were 0.96, 93%, and 91%, respectively. The five metabolites (9-methyluric acid, indole-3-lactic acid, trans-3-indoleacrylic acid, hexanoylglycine, and N-acetyl-L-leucine) that better discriminate the control and TB patient groups (VIP > 1.75) from a total of 92 metabolites quantified in both ionization modes were submitted to ROC analysis. An AUC = 1 was determined, with all samples being correctly assigned to the respective experimental group. An integrated ROC analysis enrolling one protein and four metabolites was also performed for the common control and TB patients in the proteomic and metabolomic groups. This combined signature correctly assigned the 12 controls and 12 patients used only for prediction (AUC = 1, specificity = 100%, and sensitivity = 100%). This multiomics approach revealed a biomarker signature for tuberculosis diagnosis that could be potentially used for developing a point-of-care diagnosis clinical test. 相似文献