全文获取类型
收费全文 | 166篇 |
免费 | 22篇 |
专业分类
电工技术 | 18篇 |
化学工业 | 54篇 |
金属工艺 | 6篇 |
机械仪表 | 10篇 |
建筑科学 | 26篇 |
矿业工程 | 2篇 |
能源动力 | 2篇 |
轻工业 | 4篇 |
石油天然气 | 2篇 |
无线电 | 13篇 |
一般工业技术 | 15篇 |
冶金工业 | 14篇 |
原子能技术 | 1篇 |
自动化技术 | 21篇 |
出版年
2022年 | 2篇 |
2021年 | 4篇 |
2020年 | 2篇 |
2019年 | 22篇 |
2018年 | 4篇 |
2017年 | 5篇 |
2016年 | 3篇 |
2015年 | 3篇 |
2013年 | 12篇 |
2012年 | 2篇 |
2011年 | 4篇 |
2009年 | 2篇 |
2006年 | 6篇 |
2005年 | 2篇 |
2004年 | 4篇 |
2003年 | 5篇 |
2001年 | 5篇 |
2000年 | 3篇 |
1995年 | 2篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 6篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1978年 | 4篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1975年 | 4篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1968年 | 4篇 |
1967年 | 2篇 |
1957年 | 1篇 |
1955年 | 2篇 |
1945年 | 1篇 |
1931年 | 1篇 |
1930年 | 3篇 |
1926年 | 1篇 |
1925年 | 1篇 |
1924年 | 2篇 |
1921年 | 1篇 |
1920年 | 1篇 |
1919年 | 2篇 |
排序方式: 共有188条查询结果,搜索用时 10 毫秒
1.
Clarence Sterling 《Starch - St?rke》1973,25(4):115-118
Silver crystals were produced in native potato starch by reduction from silver nitrate solution. The size of crystals ranged from less than 0.5 nm to 75 nm, in two distinct types of distribution. Considerations of nucleation and growth support the possibility that crystal size is an index of pore size. A model of free space distribution in the swollen starch grain relates lamellation of the grain to variations in the density of the starch substance. 相似文献
2.
A thermodynamic study was conducted of water vapor adsorption on four hydrophilic polymers (agar, carboxymethyl cellulose, gelatin, and maize starch) at 12 and 25°C. Monolayer coverage amounted, after correction for crystallinity, respectively, to 0.93, 1.46, 0.51, and 0.77 mol water/mol monomer. Evidence is adduced from the Bradley equation and thermodynamic data to indicate that at least during coverage with the second layer of water, the energy of adsorption is greater than that due to condensation alone. Differences in the amount of sorption and in the trend of values of ΔS?° and ΔH?° with the amount of sorbed water are related with differences in the strength of intermolecular association as affected by steric hindrances. 相似文献
3.
Distinct hydrogen species are present in important inorganic solids such as zeolites, silicoaluminophosphates (SAPOs), mesoporous materials, amorphous silicas, and aluminas. These H species include hydrogens associated with acidic sites such as Al(OH)Si, non-framework aluminum sites, silanols, and surface functionalities. Direct and quantitative methodology to identify, measure, and monitor these hydrogen species are key to monitoring catalyst activity, optimizing synthesis conditions, tracking post-synthesis structural modifications, and in the preparation of novel catalytic materials. Many workers have developed several techniques to address these issues, including 1H MAS NMR (magic-angle spinning nuclear magnetic resonance). 1H MAS NMR offers many potential advantages over other techniques, but care is needed in recognizing experimental limitations and developing sample handling and NMR methodology to obtain quantitatively reliable data. A simplified approach is described that permits vacuum dehydration of multiple samples simultaneously and directly in the MAS rotor without the need for epoxy, flame sealing, or extensive glovebox use. We have found that careful optimization of important NMR conditions, such as magnetic field homogeneity and magic angle setting are necessary to acquire quantitative, high-resolution spectra that accurately measure the concentrations of the different hydrogen species present. Details of this 1H MAS NMR methodology with representative applications to zeolites, SAPOs, M41S, and silicas as a function of synthesis conditions and post-synthesis treatments (i.e., steaming, thermal dehydroxylation, and functionalization) are presented. 相似文献
4.
Optimization of the Second-Order Logarithmic Machining Economics Problem by Extended Geometric Programming Part II: Posynomial Constraints 总被引:2,自引:0,他引:2
An algorithm is presented for solution of the machining economics problem with a Quadratic Posylognomial (QPL) objective function and single term posynomial constraints, meeting certain sufficient conditions. The algorithm applies to minimum cost or maximum productivity when the tool-life equation is a single term QPL and the removal rate is a single-term posynomial. A peripheral end-milling example, using the same tool-life equation and cost parameters as Part I, with the addition of experimentally derived constraints, is solved to illustrate the computational aspects of the algorithm. The QPL and posynomial (Taylor) formulations of the constrained machining problem are compared using the same experimental tool-life data. The QPL formulation is based on a quadratic logarithmic model whereas the posynomial formulation is based on a linear logarithmic tool-life model. An optimum without active constraints is possible using the QPL formulation in several independent machining variables, such as feed, speed, and depth, whereas the posynomial optimum, by nature, requires active constraints for more than one independent variable. This is tantamount to having additional “degrees of freedom” for optimization, as illustrated by the example problem. 相似文献
5.
de Silva CW 《Philosophical transactions. Series A, Mathematical, physical, and engineering sciences》2003,361(1809):1749-1780
An intelligent machine relies on computational intelligence in generating its intelligent behaviour. This requires a knowledge system in which representation and processing of knowledge are central functions. Approximation is a 'soft' concept, and the capability to approximate for the purposes of comparison, pattern recognition, reasoning, and decision making is a manifestation of intelligence. This paper examines the use of soft computing in intelligent machines. Soft computing is an important branch of computational intelligence, where fuzzy logic, probability theory, neural networks, and genetic algorithms are synergistically used to mimic the reasoning and decision making of a human. This paper explores several important characteristics and capabilities of machines that exhibit intelligent behaviour. Approaches that are useful in the development of an intelligent machine are introduced. The paper presents a general structure for an intelligent machine, giving particular emphasis to its primary components, such as sensors, actuators, controllers, and the communication backbone, and their interaction. The role of soft computing within the overall system is discussed. Common techniques and approaches that will be useful in the development of an intelligent machine are introduced, and the main steps in the development of an intelligent machine for practical use are given. An industrial machine, which employs the concepts of soft computing in its operation, is presented, and one aspect of intelligent tuning, which is incorporated into the machine, is illustrated. 相似文献
6.
Jastreboff Pawel J.; Brennan James F.; Coleman John K.; Sasaki Clarence T. 《Canadian Metallurgical Quarterly》1988,102(6):811
To measure tinnitus induced by sodium salicylate injections, 84 rats were used in a conditioned suppression paradigm. In Exp 1, Ss were trained with a conditioned stimulus/stimuli (CS) consisting of the offset of a continuous background noise. One group began salicylate injections before Pavlovian training, a 2nd group started injections after training, and a control group received daily saline injections. Resistance to extinction was profound when injections started before training but minimal when initiated after training, suggesting that salicylate-induced effects acquired differential conditioned value. In Exp 2, salicylate treatments were mimicked by substituting a 7 kHz tone in place of respective injections, resulting in effects equivalent to salicylate-induced behavior. A 3rd experiment included a 3 kHz CS, and again replicated the salicylate findings. In Exp 4, we decreased the motivational level, and the sequential relation between salicylate-induced effects and suppression training was retained. Findings support the demonstration of phantom auditory sensations in animals. (PsycINFO Database Record (c) 2011 APA, all rights reserved) 相似文献
7.
Clarence J. Wolf 《应用聚合物科学杂志》2003,90(3):615-625
The solubility and transport of toluene and carbon disulfide into amorphous and crystalline polyphenylene sulfide (PPS) was investigated. The rates of sorption, desorption, and resorption of both fluids were measured as a function of temperature. The sorption of these fluids into amorphous PPS produces a semi‐crystalline material by solvent induced crystallinity (SIC). Although the rate of diffusion of carbon disulfide (CS2) into crystalline PPS, (produced either thermally or by SIC), is several orders of magnitude slower than that observed in amorphous PPS, the solubility is only slightly reduced, by approximately 10%. The PPS films exhibit highly stressed surface regions that rapidly sorb the penetrant. Thermal annealing at temperatures as high as 100°C (note Tg of PPS is 85°C) has little or no effect on the surface stress, the diffusion process or the solubility of toluene into PPS. In addition to SIC, PPS undergoes cold crystallization at 130°–140°C; however, the degree of crystallinity induced by cold crystallization is approximately 60% of that formed by cooling from the melt. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 615–625, 2003 相似文献
8.
Primary polyether polyamine oligomers containing preformed urea or amide moieties in their backbones were converted to the corresponding N-isopropyl polyether polyamine oligomers (secondary amines) by reaction with acetone and hydrogen in the presence of a catalyst. The best results were from reactions carried out at about 150°C using a supported platinium or palladium catalyst in a fixed bed. Reactants and products were monitored by quantitative carbon-13 NMR, size exclusion chromatography, and amine titration. Perchloric acid titration was used to quantify the number of urea moleties per molecule. Amide backbone materials gave very little backbone degradation. However, some backbone degradation was observed with urea backbone materials, leading to products with lower molecular weights. These polyether polyamine oligomers, containing urea or amide moieties in their backbones, are useful in urethane/urea polymer systems. The lower reactivity of these secondary amines (toward polyisocyanates) results in their utility in a broader range of polyurethane fabrication technologies. © 1992 John Wiley & Sons, Inc. 相似文献
9.
C. William Ibbs Clarence K. Wong Young Hoon Kwak 《Canadian Metallurgical Quarterly》2001,17(3):159-165
Changes in projects are common and may be deleterious or beneficial—whether you see a change as a conflict or a valuable lesson depends only on your prospective. Project changes affect the cost, the scheduling, and the duration of projects, both directly and indirectly. Despite many articles and much discussion in practice and academic literature, there is a lack of information about systematic approaches to manage project change. This paper introduces a comprehensive project change management system that is founded on five principles: (1) promote a balanced change culture; (2) recognize change; (3) evaluate change; (4) implement change; and (5) continuously improve from lessons learned. By applying this project change management system, project participants can minimize deleterious change and promote beneficial change. 相似文献
10.
Clarence F. Eddy 《Journal of the American Oil Chemists' Society》1931,8(1):11-13
Summary Extraction efficiency clearly points to counter-current extraction and with the other requirements indicates continuous operation.
So our investigations and plant experience together with consideration of modern production methods have led us to the firm
conclusion that the future of large scale solvent extraction of vegetable oils lies in continuous counter-current extraction.
Presented at Fourth Annual Fall Meeting of the American Oil Chemsits' Society, Chicago, Nov. 13, 1930.
Prosco Oils Corporation. 相似文献